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Synthesis and Crystal and Molecular Structure of the Solvated Complex [MoO2(L) · C5H5N], Where L2– Is the 2-[N-(2-Hydroxynaphthalidene)amino]propane-1,2,3-Triol Anion

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Abstract

A new dioxomolybdenum(VI) compound [MoO2(L) · C5H5N], where L2– is 2-[N-(2-hydroxynaphthalidene)amino]propane-1,2,3-triol, was synthesized and its structure was determined by IR spectroscopy and X-ray diffraction. The Mo atom is in an octahedral coordination environment formed by two oxo ligands in cis positions to each other, two O atoms and the N(2) atom of the tridentate bis(chelate) ligand L, and the N(1) atom of the pyridine (Py) molecule. The N(2)(L) and N(1)(Py) atoms are in trans positions to the O(oxo) ligands at distances that are elongated due to the structural trans effect of the multiply bonded oxo ligands (Mo–N(1), 2.476 Å; Mo–N(2), 2.272 Å).

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ACKNOWLEDGMENTS

The X-ray diffraction study was performed in the Shared Facility Center of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

Funding

The work was performed within the state assignment to the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences in the field of basic research.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    V. S. Sergienko & M. D. Surazhskaya

  2. All-Russian Institute for Scientific and Technical Information (VINITI), Russian Academy of Sciences, 125190, Moscow, Russia

    V. S. Sergienko

  3. Luhansk Taras Shevchenko National University, 92700, Lugansk, Ukraine

    V. L. Abramenko

Authors
  1. V. S. Sergienko
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  2. V. L. Abramenko
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  3. M. D. Surazhskaya
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Correspondence to V. S. Sergienko.

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Translated by T. Safonova

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Sergienko, V.S., Abramenko, V.L. & Surazhskaya, M.D. Synthesis and Crystal and Molecular Structure of the Solvated Complex [MoO2(L) · C5H5N], Where L2– Is the 2-[N-(2-Hydroxynaphthalidene)amino]propane-1,2,3-Triol Anion. Crystallogr. Rep. 65, 582–585 (2020). https://doi.org/10.1134/S106377452003030X

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  • DOI: https://doi.org/10.1134/S106377452003030X

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