Abstract
The copolymers of aniline (ANI) and 2-aminophenethyl alcohol (APA) were synthesized on a poly (2-acrylamido-2-methyl-1-propanesulfonic) acid (PAMPS) template with the fungal laccase Trametes hirsuta, which has a high redox potential, as the catalyst. Atmospheric oxygen was the oxidizing agent. The copolymer/PAMPS complexes were pseudo-soluble and were characterized by various physicochemical methods. The electrical conductivity of the copolymers depended on the initial molar ratio of the monomers. The copolymer synthesized at an APA : ANI ratio of 2 : 8 possessed the best characteristics. It is shown that the laccase/mediator system can be to oxidize the primary alcohol groups of the copolymer to reactive aldehyde groups.
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ACKNOWLEDGMENTS
The equipment of the Collective Use Center Industrial Biotechnologies of the Research Center of Biotechnology of the Russian Academy of Sciences was used in the work.
Funding
The study was carried out as part of the state task of the Bach Institute of Biochemistry of the Research Center of Biotechnology of the Russian Academy of Sciences.
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Khlupova, M.E., Shumakovich, G.P., Vasil’eva, I.S. et al. Enzymatic Synthesis of a Conducting Aniline and 2-aminophenethyl Alcohol Copolymer with Functional Groups. Appl Biochem Microbiol 56, 441–445 (2020). https://doi.org/10.1134/S0003683820040080
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DOI: https://doi.org/10.1134/S0003683820040080