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Liquid-Phase Oxidation of n-Propyl Mercaptan with Molecular Oxygen in the Presence of an Ammoniac Solution of Cobalt Phthalocyanine

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Abstract

The main kinetic features of the oxidation of n-propyl mercaptan with molecular oxygen in a model mixture with diesel fuel in the presence of an ammoniac solution of cobalt phthalocyanine have been studied. The rate equation of the reaction has been derived based on the experimental data, and optimum conditions of a waste-free process for removing hydrogen sulfide and mercaptans from crude petroleum have been selected.

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Authors and Affiliations

  1. AO Volga Research Institute of Hydrocarbon Feedstocks, 420061, Kazan, Tatarstan, Russia

    O. M. Kornetova, A. M. Mazgarov, A. F. Vil’danov & I. K. Khrushcheva

Authors
  1. O. M. Kornetova
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  2. A. M. Mazgarov
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  3. A. F. Vil’danov
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  4. I. K. Khrushcheva
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Correspondence to O. M. Kornetova.

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CONFLICT OF INTEREST

The authors declare that they have no conflict of interest.

AUTHOR INFORMATION

O.M. Kornetova, Researcher; ORCID: https://orcid.org/0000-0001-7898-7499

A.M. Mazgarov, General Director, Prof., Dr. Sci. (Tech.); ORCID: https://orcid.org/0000-0003-1531-497X

A.F. Vil’danov, Deputy General Director of Research, Prof., Dr. Sci. (Tech.); ORCID: https://orcid.org/0000-0003-3796-8165

I.K. Khrushcheva, Senior Researcher, Cand. Sci. (Tech.); ORCID: https://orcid.org/0000-0002-1608-8911

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Translated by E. Boltukhina

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Kornetova, O.M., Mazgarov, A.M., Vil’danov, A.F. et al. Liquid-Phase Oxidation of n-Propyl Mercaptan with Molecular Oxygen in the Presence of an Ammoniac Solution of Cobalt Phthalocyanine. Pet. Chem. 60, 768–772 (2020). https://doi.org/10.1134/S0965544120070075

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  • DOI: https://doi.org/10.1134/S0965544120070075

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