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Shock-Wave Initiation of a Thermite Mixture of Al + CuO

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Combustion, Explosion, and Shock Waves Aims and scope

Abstract

The shock-wave initiation of chemical reaction in pressed pellets of a stoichiometric mixture of Al and CuO powders in a steel tube was studied. The dynamics of the chemical transformations in the heterogeneous flow of reaction products of the mixture with dispersion of the pressed pellet material in the unloading wave was investigated. From the results of pyrometric measurements, the maximum brightness temperature of chemical reaction products was \(\approx\)3500 K.

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REFERENCES

  1. A. F. Belyaev, Combustion, Detonation, and Work of Explosion of Condensed Systems (Nauka, Moscow, 1968) [in Russian].

  2. S. P. Smirnov, E. V. Kolganov, V. P. Il’in, Ya. S. Kulakevich, A. S. Smirnov, and F. T. Khvorov, “Development of Explosive Compositions of Increased Efficiency with Satisfactory Performance," in V Khariton Scientific Readings: Proc. Int. Conf. (RFNC-VNIIEF, Sarov, 2003), pp. 231, 232.

  3. A. A. Kotomin, “Elastic Explosive Materials," Ross. Khim. Zh.41 (4), 89–101 (1997).

  4. V. K. Bobolev, I. A. Karpukhin, and V. A. Teselkin, “Mechanism of Initiation of an Explosion by Impact in Mixtures of Ammonium Perchlorate with Combustible Additives," Fiz. Goreniya Vzryva7 (2), 261–264 (1971) [Combust., Expl., Sock Waves7 (2), 221–223 (1971)].

  5. M. F. Gogulya and M. A. Brazhnikov, “On the Characteristic Times of Chemical Reactions in Heterogeneous Systems under Dynamic Loading," Khim. Fiz. 13 (11), 88–101 (1994).

  6. S. I. Gerasimov, Yu. I. Faikov, and S. A. Kholin,Cumulative Light Sources (RFNC-VNIIEF, Sarov, 2011).

  7. A. A. Kotomin, V. V. Efanov, S. A. Dushenok, A. S. Kozlov, M. A. Trapeznikov, E. N. Breshev, and V. V. Gorovtsov, “Controlling the Detonability of Explosive Materials Used in Spacecraft Separation Systems," Vestn. NPO Lavochkina 13 (2), 12–18 (2012).

  8. A. I. Aniskin, “Detonation of Explosive Mixtures with Aluminum," Detonation and Shock Waves (Inst. of Chem. Phys., USSR Acad. of Sci., Chernogolovka, 1986), pp. 26–31.

  9. I. M. Voskoboinikov, “Oxidation of Aluminum in Shock and Detonation Waves," Khim. Fiz. 28 (12), 40–44 (2009).

  10. A. A. Borisov, A. A. Sulimov, M. K. Sukoyan, P. V. Komissarov, I. O. Shamshin, R. Kh. Ibragimov, and Yu. M. Mikhailov, “Blast Waves in Open Space upon Non-Ideal Detonation of High-Density Mixed Compositions Enriched in Aluminum," Khim. Fiz. 28(11), 59–68 (2009).

  11. Fan Yang, Xiaoli Kang, Jiangshan Luo, Zao Yi, and Yongjian Tang, “Preparation of Core-Shell Structure KClO4@Al/CuO. Nanoenergetic Material and Enhancement of Thermal Behavior," Sci. Report No. 7 (2017), Article number 3730; DOI: 10.1038/s41598-017-03683-z.

  12. A. Yu. Dolgoborodov, A. N. Streletskii, M. N. Makhov, I. V. Kolbanev, and V. E. Fortov, “Explosive Compositions Based on Mechanically Activated Metal–Oxidizer Mixtures," Khim. Fiz.25 (12), 40–45 (2007).

  13. A. N. Dremin, S. D. Savrov, V. S. Trofimov, and K. K. Shvedov,Detonation Waves in Condensed Media (Nauka, Moscow, 1970) [in Russian].

  14. B. G. Loboiko and S. N. Lyubyatinskii, “Reaction Zones of Detonating Solid Explosives," Fiz. Goreniya Vzryva36 (6), 45–64 (2000) [Combust., Expl., Sock Waves36 (6), 716–732 (2000)].

  15. A. Yu. Dolgoborodov, V. G. Kirilenko, A. N. Streletskii, I. V. Kolbanev, A. A. Shevchenko, B. D. Yankovskii, S. Yu. Anan’ev, and G. E. Val’yano, “Mechanically Activated Al/CuO Thermite Composition," Gorenie Vzryv 11 (3), 103–113 (2018).

  16. V. A. Golubev, V. V. Vakhrushev, E. V. Panturov, B. E. Grinevich, A. V. Strikanov, A. A. Uskov, V. A. Laktyushkin, V. A. Kozlov, O. S. Demidov, A. L. Ulanova, and V. V. Yaroshenko, “The Behavior of AlCuO Pyrotechnic Composition under Shock-Wave Loading," inIII Khariton Scientific Readings, Proc. Int. Conf.(RFNC-VNIIEF, Sarov, 2002), pp. 75–80.

  17. V. S. Solov’ev, “Some Specific Features of Shock-Wave Initiation of Explosives," Fiz. Goreniya Vzryva 36 (6), 65–76 (2000) [Combust., Expl., Sock Waves 36 (6), 734–744 (2000)].

  18. M. A. Dmitrieva, “Model of a Shock-Loaded Reactive Powdered Body with Structure," Abstracts of Doct. Dissertation (Tomsk State University, Tomsk, 2009).

  19. S. Y. Ananev, A. Y. Dolgoborodov, A. A. Shiray, B. D. Yankovsky, “Shock Initiation of Exothermic Reactions in Mechanically Activated Mixtures," J. Phys.: Conf. Ser. 774 (1), 1–8 (2016); DOI:10.1088/1742-6596/774/1/012069.

  20. P. V. Pikhtovnikov and V. I. Zav’yalov, Forming of Sheet Metal by Explosion (Mashinostroenie, Moscow, 1964) [in Russian].

  21. S. Y. Ananev, B. D. Yankovsky, and A. Y. Dolgoborodov, “The Combustion of Al–CuO Powder Mixture under Shock Wave Initiation of the Reaction," J. Phys.: Conf. Ser. 946 (1), 1–7 (2018).

  22. S. Yu. Anan’ev, A. Yu. Dolgoborodov, and B. D. Yankovskii, “Dynamics of Expansion of Combustion Products of a Mechanically Activated Mixture of Aluminum with Copper Oxide," Gorenie Vzryv10 (4), 81–85 (2017).

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Correspondence to A. Yu. Dolgoborodov.

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Ananev, S.Y., Grishin, L.I., Dolgoborodov, A.Y. et al. Shock-Wave Initiation of a Thermite Mixture of Al + CuO. Combust Explos Shock Waves 56, 220–230 (2020). https://doi.org/10.1134/S0010508220020136

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  • DOI: https://doi.org/10.1134/S0010508220020136

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