Abstract
The MoS2 quantum dots less than 10 nm were in situ prepared in green ILs for the first time. The MoS2 quantum dots can be easily obtained by simple one-step synthesis within the preparation of ILs themselves. The physico-chemical and tribological properties of the acquired the MoS2 QDs in ILs were systematically studied. Compared with pure ILs, the MoS2 QDs in ILs exhibiting long-term dispersion stabilities have superior lubricating properties under harsh conditions. Thin films formed according to the XPS results were attributed to be the main account for the preferable tribological properties of the MoS2 QDs in ILs than pure ILs.
Similar content being viewed by others
References
Ye, C.F., Liu, W.M., Chen, Y.X., Yu, L.G.: Room-temperature ionic liquids: a novel versatile lubricant. Chem. Commun. 21, 2244–2245 (2001)
Palacio, M., Bhushan, B.: A review of ionic liquids for green molecular lubrication in nanotechnology. Tribol. Lett. 40, 247–268 (2010)
Zhou, F., Liang, Y.M., Liu, W.M.: Ionic liquid lubricants: designed chemistry for engineering applications. Chem. Soc. Rev. 38, 2590–2599 (2009)
Qu, J., Bansal, D.G., Yu, B., Howe, J.Y., Luo, H., Dai, S., Li, H., Blau, P.J., Bunting, B.G., Mordukhovich, G., Smolenski, D.J.: Antiwear performance and mechanism of an oilmiscible ionic liquid as a lubricant additive. ACS Appl. Mater. Interfaces 4, 997–1002 (2012)
Zhou, Y., Qu, J.: Ionic liquids as lubricant additives: a review. ACS Appl. Mater. Interfaces 9, 3209–3222 (2017)
Kondo, H., Seto, J., Ozawa, K., Haga, S.: Novel lubricant for magnetic thin film media. J. Magn. Soc. Jpn. 13(Suppl S1), 213–218 (1989)
Kondo, H., Seki, A., Watanabe, H., Seto, J.: Frictional properties of novel lubricants for magnetic thin film media. IEEE Trans. Magn. 26, 2691–2693 (1990)
Kondo, H., Seki, A., Kita, A.: Comparison of an amide and amine salt as friction modifiers for a magnetic thin film medium. Tribol. Trans. 37, 99–105 (1994)
Kondo, H.: Protic ionic liquids with ammonium salts as lubricants for magnetic thin film media. Tribol. Lett. 31, 211–218 (2008)
Espinosa, T., Sanes, J., Jimenez, A.E., Bermudez, M.D.: Protic ammonium carboxylate ionic liquid lubricants of OFHC copper. Wear 303, 495–509 (2013)
Espinosa, T., Jimenez, M., Sanes, J., Jimenez, A.E., Iglesias, M., Bermudez, M.D.: Ultra-low friction with a protic ionic liquid boundary film at the water-lubricated sapphirestainless steel interface. Tribol. Lett. 53, 1–9 (2014)
Aviles, M.D., Carrion, F.J., Sanes, J., Bermudez, M.D.: Effects of protic ionic liquid crystal additives on the water-lubricated sliding wear and friction of sapphire against stainless steel. Wear 408, 56–64 (2018)
Zhao, Q., Zhao, G.Q., Zhang, M., Wang, X.B., Liu, W.M.: Tribological behavior of protic ionic liquids with dodecylamine salts of dialkyldithiocarbamate as additives in lithium complex grease. Tribol. Lett. 48, 133–144 (2012)
Shi, Y.J., Larsson, R.: Non-corrosive and biomaterials protic ionic liquids with high lubricating performance. Tribol. Lett. 63, 1 (2016)
Patel, A., Guo, H., Iglesias, P.: Study of the lubricating ability of protic ionic liquid on an aluminum-steel contact. Lubricants 6, 66 (2018)
Aviles, M.D., Carrion, F.J., Sanes, J., Bermudez, M.D.: Diprotic ammonium succinate ionic liquid in thin film aqueous lubrication and in graphene nanolubricant. Tribol. Lett. 67, 26 (2019)
Zheng, D.D., Wang, X.B., Zhang, M., Ju, C.: Synergistic effects between the two choline-based ionic liquids as lubricant additives in glycerol aqueous solution. Tribol. Lett. 67, 47 (2019)
Zheng, D.D., Wang, X.B., Zhang, M., Liu, Z.G., Ju, C.: Anticorrosion and lubricating properties of a fully green lubricant. Tribol. Int. 130, 324–333 (2019)
Zheng, D.D., Wang, X.B., Liu, Z.G., Ju, C., Xu, Z., Xu, J.J., Yang, C.: Synergy between two protic ionic liquids for improving the antiwear property of glycerol aqueous solution. Tribol. Int. 141, 105731 (2020)
Zheng, D.D., Zhao, Q., Ju, C., Wang, X.B.: The interaction of two anticorrosive ionic liquid additives on the friction properties of water lubricants. Tribol. Int. 141, 105948 (2020)
Dai, W., Kheireddin, B., Gao, H., Liang, H.: Roles of nanoparticles in oil lubrication. Tribol. Int. 102, 88–98 (2016)
Zheng, X.J., Xu, Y.F., Geng, J., Peng, Y.B., Olson, D., Hu, X.G.: Tribological behavior of Fe3O4/MoS2, nanocomposites additives in aqueous and oil phase media. Tribol. Int. 102, 79–87 (2016)
Xie, H.M., Jiang, B., He, J.J., Xia, X.S., Pan, F.S.: Lubrication performance of MoS2, and SiO2, nanoparticles as lubricant additives in magnesium alloy-steel contacts. Tribol. Int. 93, 63–70 (2016)
Xu, Z.Y., Hu, K.H., Han, C.L., Hu, X.G., Xu, Y.F.: Morphological influence of molybdenum disulfide on the tribological properties of rapeseed oil. Tribol. Lett. 49, 513–524 (2013)
Liu, L., Huang, Z.B., Huang, P.: Fabrication of coral-like MoS2, and its application in improving the tribological performance of liquid paraffin. Tribol. Int. 104, 303–308 (2016)
Kalin, M., Kogovšek, J., Remškar, M.: Mechanisms and improvements in the friction and wear behavior using MoS2 nanotubes as potential oil additives. Wear 280, 36–45 (2012)
Xu, Y.F., Peng, Y.B., Dearn, K.D., Zheng, X.J., Yao, L.L., Hu, X.G.: Synergistic lubricating behaviors of graphene and MoS2 dispersed in esterified bio-oil for steel/steel contact. Wear 342–343, 297–309 (2015)
Gong, K.L., Wu, X.H., Zhao, G.Q., Wang, X.B.: Nanosized MoS2 deposited on graphene as lubricant additive in polyalkylene glycol for steel/steel contact at elevated temperature. Tribol. Int. 110, 1–7 (2017)
Xu, Z., Lou, W.J., Wu, X.H., Wang, X.B., Hao, J.Y.: Investigating the tribological behavior of PEGylated MoS2 nanocomposites as additives in polyalkylene glycol at elevated temperature. RSC Adv. 7, 53346–53354 (2017)
Wu, X.H., Zhao, G.Q., Zhao, Q., Gong, K.L., Wang, X.B., Liu, W.M., Liu, W.S.: Investigating the tribological performance of nanosized MoS2 on graphene dispersion in perfluoropolyether under high vacuum. RSC Adv. 6, 98606–98610 (2016)
Wu, X.H., Gong, K.L., Zhao, G.Q., Lou, W.J., Wang, X.B., Liu, W.M.: Surface modification of MoS2 nanosheets as effective lubricant additives for reducing friction and wear in poly-α-olefin. Ind. Eng. Chem. Res. 57, 8105–8114 (2018)
Wu, X.H., Gong, K.L., Zhao, G.Q., Lou, W.J., Wang, X.B., Liu, W.M.: MoS2/WS2 quantum dots as high-performance lubricant additive in polyalkylene glycol for steel/steel contact at elevated temperature. Adv. Mater. Interfaces. 5, 1700859 (2017)
Gong, K.L., Lou, W.J., Zhao, G.Q., Wu, X.H., Wang, X.B.: Investigation on tribological behaviors of MoS2 and WS2 quantum dots as lubricant additives in ionic liquids under severe conditions. Friction (2019). https://doi.org/10.1007/s40544-019-0290-6
Zhong, Y.P., Xue, F.F., Wei, P., Li, R.H., Cao, C.Y., Tao, Y.: Water-soluble MoS2 quantum dots for facile and sensitive fluorescence sensing of alkaline phosphatase activity in serum and live cells based on the inner filter effect. Nanoscale 10, 21298 (2018)
Zhou, K.G., Mao, N.N., Wang, H.X., Peng, Y., Zhang, H.L.: A mixed-solvent strategy for efficient exfoliation of inorganic graphene analogues. Angew. Chem. Int. Ed. 50, 10839–10842 (2011)
Zeng, X.Q., Shao, H.Y., Rao, W.Q., He, Z.Y., Ren, T.H.: Tribological study of trioctylthiotriazine derivative as lubricating oil additive. Wear 258, 800–805 (2005)
Naumkin, A.V., Kraut-Vass, A., Gaarenstroom, S.W., Powell, C.J.: NIST X-ray photoelectron spectroscopy database. https://www.srdatanistgov/xps/Default.aspx
Sun, Y.B., Hu, L.T., Xue, Q.J.: Tribological properties and action mechanism of N, N-dialkyl dithiocarbamate-derived S-hydroxyethyl borate esters as additives in rapeseed oil. Wear 266, 917–924 (2009)
Zheng, D.D., Ju, C., Zhao, Q., Wang, X.B.: Ammonium tetrathiomolybdate enhancing the lubricity of choline ricinoleate ionic liquid in water-glycerol mixture. Tribol. Lett. 67, 122 (2019)
Acknowledgements
The authors are grateful for financial support of this work by National Key Research and Development Program of China (2018YFB0703802) and National Natural Science Foundation of China (NSFC 51875553).
Author information
Authors and Affiliations
Corresponding authors
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ju, C., Zheng, D., Zhao, Q. et al. Tribological Properties of Green ILs Containing MoS2 Quantum Dots with One-Step Preparation. Tribol Lett 68, 79 (2020). https://doi.org/10.1007/s11249-020-01314-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s11249-020-01314-9