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Reaction of N-(4,4-Diethoxybutyl)phosphamides with Chloro(diphenyl)phosphine. Synthesis of 2-(Diphenylphosphoryl)pyrrolidines

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Abstract

The reaction of N-(4,4-diethoxybutyl)phosphamides with chloro(diphenyl)phosphine in chloroform in the presence of acetic acid gave previously unknown 2-(diphenylphosphoryl)pyrrolidines, and hydrolysis of the latter afforded 2-(diphenylphosphoryl)pyrrolidine.

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Funding

This study was performed under financial support by the President of the Russian Federation (program for state support of young Russian doctors of science, project no. MD-585.2019.3).

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Authors and Affiliations

  1. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, 420088, Kazan, Russia

    A. V. Smolobochkin, A. S. Gazizov, A. R. Burilov & M. A. Pudovik

  2. Kazan National Research Technological University, 420015, Kazan, Russia

    R. A. Turmanov

  3. Butlerov Institute of Chemistry, Kazan (Volga Region) Federal University, 420008, Kazan, Russia

    E. A. Kuznetsova

Authors
  1. A. V. Smolobochkin
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  2. R. A. Turmanov
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  3. A. S. Gazizov
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  4. E. A. Kuznetsova
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  5. A. R. Burilov
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  6. M. A. Pudovik
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Corresponding author

Correspondence to A. V. Smolobochkin.

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The authors declare no conflict of interest.

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Dedicated to M.A. Pudovik on his 80th anniversary

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Smolobochkin, A.V., Turmanov, R.A., Gazizov, A.S. et al. Reaction of N-(4,4-Diethoxybutyl)phosphamides with Chloro(diphenyl)phosphine. Synthesis of 2-(Diphenylphosphoryl)pyrrolidines. Russ J Org Chem 56, 1119–1121 (2020). https://doi.org/10.1134/S107042802006024X

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  • DOI: https://doi.org/10.1134/S107042802006024X

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