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Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane

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Abstract

The reaction of perfluorinated three-mercury anticrown (o-C6F4Hg)3 (1) with 1,2-dichloroethane (DCE) affords the complex {[(o-C6F4Hg)3]2(ClCH2CH2Cl)}(2) containing two anticrown molecules per DCE molecule. According to the X-ray diffraction data, the DCE molecule in complex 2 acts as a bridge between molecules 1, each DCE chlorine atom being coordinated to a single mercury center of the neighboring anticrown molecules.

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References

  1. V. B. Shur, I. A. Tikhonova, in Encyclopedia of Supramolecular Chemistry, Eds J. L. Atwood, J. W. Steed, Marcel Dekker, Inc., New York, 2004, p. 68.

  2. T. J. Wedge, M. F. Hawthorne, Coord. Chem. Rev., 2003, 240, 111.

    Article  CAS  Google Scholar 

  3. V. B. Shur, I. A. Tikhonova, Russ. Chem. Bull., 2003, 52, 2539.

    Article  CAS  Google Scholar 

  4. M. R. Haneline, R. E. Taylor, F. P. Gabbaï, Chem. Eur. J., 2003, 21, 5188.

    Article  Google Scholar 

  5. T. J. Taylor, C. N. Burress, F. P. Gabbaï, Organometallics, 2007, 26, 5252.

    Article  CAS  Google Scholar 

  6. J. D. Wuest, Acc. Chem. Res., 1999, 32, 81.

    Article  CAS  Google Scholar 

  7. M. F. Hawthorne, Z. Zheng, Acc. Chem. Res., 1997, 30, 267.

    Article  CAS  Google Scholar 

  8. I. A. Tikhonova, D. A. Gribanyov, K. I. Tugashov, F. M. Dolgushin, A. S. Peregudov, D. Yu. Antonov, V. I. Rosenberg, V. B. Shur, J. Organomet. Chem., 2010, 695, 1949.

    Article  CAS  Google Scholar 

  9. I. A. Tikhonova, D. A. Gribanyov, K. I. Tugashov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, Z. S. Klemenkova, V. B. Shur, ARKIVOC, 2011, No. 8, 172.

    Google Scholar 

  10. A. S. Filatov, A. K. Greene, E. A. Jackson, L. T. Scott, M. A. Petrukhina, J. Organomet. Chem., 2011, 696, 2877.

    Article  CAS  Google Scholar 

  11. M. Fleischmann, C. Heindl, M. Seidl, G. Balázs, A. V. Virovets, E. V. Peresypkina, M. Tsunoda, F. P. Gabbaï, M. Scheer, Angew. Chem., Int. Ed., 2012, 51, 9918.

    Article  CAS  Google Scholar 

  12. K. I. Tugashov, D. A. Gribanyov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, M. Kh. Minacheva, B. N. Strunin, I. A. Tikhonova, V. B. Shur, J. Organomet. Chem., 2013, 747, 167.

    Article  CAS  Google Scholar 

  13. S. P. Fischer, E. W. Reinheimer, J. Chem. Crystallogr., 2013, 43, 478.

    Article  Google Scholar 

  14. S. P. Fischer, E. W. Reinheimer, J. Chem. Crystallogr., 2014, 44, 123.

    Article  Google Scholar 

  15. R. Castañeda, S. Draguta, A. Yakovenko, M. Fonari, T. Timofeeva, Acta Cryst., Sect. E, 2014, 70, m164.

    Article  Google Scholar 

  16. A. Muñoz-Castro, Phys. Chem. Chem. Phys., 2014, 16, 7578.

    Article  Google Scholar 

  17. M. Ponce-Vargas, A. Muñoz-Castro, J. Phys. Chem. C, 2014, 118, 28244.

    Article  CAS  Google Scholar 

  18. H. Schmidbaur, A. Schier, Organometallics, 2015, 34, 2048.

    Article  CAS  Google Scholar 

  19. S. P. Fisher, R. H. Groeneman, E. W. Reinheimer, J. Coord. Chem., 2015, 68, 3589.

    Article  CAS  Google Scholar 

  20. K. I. Tugashov, D. A. Gribanyov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, I. A. Tikhonova, V. B. Shur, Organometallics, 2015, 34, 1530.

    Article  CAS  Google Scholar 

  21. K. I. Tugashov, D. A. Gribanyov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, M. Kh. Minacheva, I. A. Tikhonova, V. B. Shur, Organometallics, 2016, 35, 2197.

    Article  CAS  Google Scholar 

  22. M. Tsunoda, M. Fleischmann, J. S. Jones, N. Bhuvanesh, M. Scheer, F. P. Gabbaï, Dalton Trans., 2016, 45, 5045.

    Article  CAS  Google Scholar 

  23. T. Lasanta, J. M. López-de-Luzuriaga, M. Monge, M. E. Olmos, D. Pascual, Dalton Trans., 2016, 45, 6334.

    Article  CAS  Google Scholar 

  24. K. I. Tugashov, D. A. Gribanyov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, Z. S. Klemenkova, O. V. Matvienko, I. A. Tikhonova, V. B. Shur, Organometallics, 2017, 36, 2437.

    Article  CAS  Google Scholar 

  25. K. I. Tugashov, S. M. Yunusov, E. S. Kalyuzhnaya, F. M. Dolgushin, A. A. Yakovenko, I. A. Tikhonova, V. B. Shur, Russ. Chem. Bull., 2018, 67, 45.

    Article  CAS  Google Scholar 

  26. N. A. Semenov, D. E. Gorbunov, M. V. Shakhova, G. E. Salnikov, I. Y. Bagryanskaya, V. V. Korolev, J. Beckmann, N. P. Gritsan, A. V. Zibarev, Chem. Eur. J., 2018, 24, 12983.

    Article  CAS  Google Scholar 

  27. K. I. Tugashov, D. A. Gribanyov, F. M. Dolgushin, A. F. Smol’yakov, A. S. Peregudov, Z. S. Klemenkova, I. G. Barakovskaya, I. A. Tikhonova, V. B. Shur, Organometallics, 2019, 38, 2910.

    Article  CAS  Google Scholar 

  28. P. Sartory, A. Golloch, Chem. Ber., 1968, 101, 2004.

    Article  Google Scholar 

  29. M. C. Ball, D. S. Brown, A. G. Massey, D. A. Wickens, J. Organomet. Chem., 1981, 206, 265.

    Article  CAS  Google Scholar 

  30. K. I. Tugashov, I. A. Tikhonova, F. M. Dolgushin, A. Yu. Volkonskii, I. G. Barakovskaya, A. G. Buyanovskaya, V. B. Shur, Tez. dokl. Vseross. konf “Khimiya ftora” posvyashchennoi 100-letiyu so dnya rozhdeniya akademika I. L. Knunyantsa [All-Russian Conference “Fluorine Chemistry” devoted to the 100th Anniversary of Academician I. L. Knunyants], (June 5–9, 2006, Moscow), Moscow, 2006, P-75 (in Russian).

  31. M. Fleischmann, J. S. Jones, F. P. Gabbaï, M. Scheer, Chem. Sci., 2015, 6, 132.

    Article  CAS  Google Scholar 

  32. O. Elbjeirami, C. N. Burress, F. P. Gabbaï, M. A. Omary, J. Phys. Chem. C, 2007, 111, 9522.

    Article  CAS  Google Scholar 

  33. A. J. Canty, G. B. Deacon, Inorg. Chim. Acta, 1980, 45, L 225.

    Article  CAS  Google Scholar 

  34. P. Pyykkö, M. Straka, Phys. Chem. Chem. Phys., 2000, 2, 2489.

    Article  Google Scholar 

  35. S. S. Batsanov, Russ. J. Inorg. Chem., 1991, 36, 1694.

    Google Scholar 

  36. Yu. K. Grishin, Yu. A. Strelenko, L. A. Margulis, Yu. A. Ustynyuk, L. S. Golovchenko, A. S. Peregudov, D. N. Kravtsov, Dokl. Chem., 1979, 249, 1008.

    Google Scholar 

  37. APEX II software package; Bruker AXS, Inc.: 5465, East Cheryl Parkway, Madison, WI 5317, 2005.

  38. G. M. Sheldrick, Acta Crystallogr., Sect. C, 2015, C71, 3.

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    K. I. Tugashov, S. M. Yunusov, E. S. Kalyuzhnaya, F. M. Dolgushin, I. A. Tikhonova & V. B. Shur

Authors
  1. K. I. Tugashov
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  2. S. M. Yunusov
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  3. E. S. Kalyuzhnaya
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  4. F. M. Dolgushin
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  5. I. A. Tikhonova
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  6. V. B. Shur
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Corresponding author

Correspondence to V. B. Shur.

Additional information

Dedicated to Academician of the Russian Academy of Sciences I. L. Eremenko on the occasion of his 70th birthday.

This work was financially supported by the Russian Foundation for Basic Research (Project No. 19-03-00875). The X-ray diffraction studies, spectroscopic measurements, and elemental analyses were performed with the financial support from the Ministry of Science and Higher Education of the Russian Federation using equipment of the Center for Molecular Composition Studies of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1092–1095, June, 2020.

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Tugashov, K.I., Yunusov, S.M., Kalyuzhnaya, E.S. et al. Coordination chemistry of anticrowns. Synthesis and structure of the binuclear complex of perfluorinated three-mercury anticrown (o-F6Hg)3 with 1,2-dichloroethane. Russ Chem Bull 69, 1092–1095 (2020). https://doi.org/10.1007/s11172-020-2872-x

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  • DOI: https://doi.org/10.1007/s11172-020-2872-x

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