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Chitin-based magnetic composite for the removal of contaminating substances from aqueous media

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Abstract

A method of obtaining multipurpose magnetic chitin, which combines the magnetic properties of magnetite and the adsorption properties of polysaccharide, was proposed. The possibility of using chitin-(CT) and chitosan (CS)-containing magnetic composites for the adsorption of inorganic ions CoII and CrVI and organic substances (2- and 4-nitrophenols) from aqueous media was analyzed. It was shown that the adsorption capacity of magnetic chitin with respect to CoII and CrVI ions reached 41 mg g−1 and 15 mg g−1, respectively. The maximum adsorption capacity for 4-nitrophenol (19 mg g−1 per CT-containing magnetic composite or 56 mg g−1 per chitin component) was about three times higher than for 2-nitrophenol. The obtained adsorbent Fe3O4/CT is environmentally friendly and reusable.

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    N. A. Samoilova & M. A. Krayukhina

Authors
  1. N. A. Samoilova
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  2. M. A. Krayukhina
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Corresponding author

Correspondence to N. A. Samoilova.

Additional information

The authors are grateful to V. E. Tikhonov for valuable advice and comments on the work, and Z. S. Klemenkova for recording the IR spectra.

This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation and carried out using the equipment of the Center for molecule composition studies of the A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

On the occasion of the 65th anniversary of the foundation of A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences.

Based on the materials of the International Conference “Chemistry of Organoelement Compounds and Polymers 2019” (November 18–22, 2019, Moscow, Russia).

Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 6, pp. 1157–1164, June, 2020.

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Samoilova, N.A., Krayukhina, M.A. Chitin-based magnetic composite for the removal of contaminating substances from aqueous media. Russ Chem Bull 69, 1157–1164 (2020). https://doi.org/10.1007/s11172-020-2883-7

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  • DOI: https://doi.org/10.1007/s11172-020-2883-7

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