Abstract
Catalytic recombination of hydrogen and oxygen as radiolysis gases was studied using ceramic blocks of cellular structure as a catalyst support. The characteristics of the catalyst samples obtained were compared to those of the presently used granulated catalyst RK-102-12 (OPK-2). The possibility of preventing the transition of the catalytic recombination of hydrogen and oxygen to the flame combustion mode by making a catalyst with “gradient” activity was examined. The results obtained confirm good prospects for using the cellular ceramic as a catalyst support for passive hydrogen recombiners to ensure hydrogen safety at nuclear power plants.
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REFERENCES
Kirillov, I.A., Kharitonova, N.L., Sharafutdinov, R.B., and Khrennikov, N.N., Yadern. Radiats. Bezopasn., 2017, vol. 84, no. 2, pp. 26–37.
Solovev, S.A. and Orlik, S.N., Kinet. Catal., 2009, vol. 50, no. 5, pp. 705–714. https://doi.org/10.1134/S0023158409050127
Govender, S. and Friedrich, H.B., Catalysts, 2017, vol. 7, no. 2, pp. 62–67. https://doi.org/10.3390/catal7020062
Su, J., Liu, Q., Liu, Z., and Huang, Z., Ind. Eng. Chem. Res., 2008, vol. 47, no. 13, pp. 4295–4301. https://doi.org/10.1021/ie800105p
Trueba, M. and Trasatti, S.P., Eur. J. Inorg. Chem., 2005, no. 17, pp. 3393–3403 https://doi.org/10.1002/ejic.200500348
Pakhomov, N.A., Nauchnye osnovy prigotovleniya katalizatorov. Vvedenie v teoriyu i praktiku (Scientific Principles of Catalyst Preparation. Introduction to Theory and Practice), Novosibirsk: Sib. Otdel. Ross. Akad. Nauk, 2011.
RF Patent 2222060, Publ. 2004.
RF Patent 2461900, Publ. 2012.
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Yasnev, I.M., Mel’nichenko, A.N. & Gurskii, V.S. A Cellular Ceramic as a Catalyst Support for Radiolytic Gas Recombination Devices. Russ J Appl Chem 93, 927–932 (2020). https://doi.org/10.1134/S107042722006021X
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DOI: https://doi.org/10.1134/S107042722006021X