Abstract
Using X-ray diffraction study of the solid phases formed in an alkaline titanosilicate system with an invariable concentration of components upon process temperature variation in the 180–210°C range and time variation from 1 to 7 days, structural genesis of the solid phases was established. This allowed predicting the final result, consisting in the formation of an ion exchange material as a powder or granules with a high sorption capacity for Cs+ and Sr2+ cations. The formation of granules of the titanosilicate sorbent with a colloidal silicon binder induced agglomeration of particles with partial isolation of their pore system, which decreased the sorption capacity for Cs+ by a factor of 1.5. Simultaneously, the uptake of Sr2+ increased by 10–15% due to the formation of insoluble Sr2+ silicate or hydroxide on the surface with pH of 8.5–9.5.
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REFERENCES
Myasoedova, G.V. and Nikashina, V.A., Ross. Khim. Zh. (Zh. Ross. Khim. O-va im. D.I. Mendeleeva), 2006, vol. 50, no. 5, pp. 55–63.
US Patent 3329481, 1967; appl. filed Oct. 18, 1963; publ. Jul. 4, 1967. no. 318829.
Al-Attar, L., Dyer, A., and Harjulab, R., J. Mater. Chem., 2003, vol. 13, pp. 2963–2968.
Nikolaev, A.I., Ivanyuk, G.Yu., Krivovichev, S.V., Yakovenchuk, V.N., Pakhomovskii, Ya.A., Gerasimova, L.G., et al., Vestn. Kol’sk. Nauchn. Tsentra Ross. Akad. Nauk, 2010, no. 3, pp. 51–62.
Wang, X. and Jacobson, A.J., Chem. Commun., 1999, no. 11, pp. 973–974.
Cruciani, G., De Luca, P., Nastro, A., and Pattison, P., Micropor. Mesopor. Mater., 1998, vol. 21 nos. 1–3, pp. 143–153.
Perovskii, I.A. and Burtsev, I.N., Vestn. Komi Nauchn. Tsentra Ross. Akad. Nauk, 2013, no. 3, pp. 16–19.
Ji, Z., Yilmaz, B., Warzywoda, J., and Sacco, A., Jr., Micropor. Mesopor. Mater., 2005, vol. 81, nos. 1–3, pp. 1–10.
Spiridonova, D.V., Krivovichev, S.V., Yakovenchuk, V.N., and Pakhomovskii, Ya.A., Ross. Khim. Zh. (Zh. Ross. Khim. O-va im. D.I. Mendeleeva), 2010, no. 5, pp. 79–88.
Nguyen, H.K.D., Sankar, G., and Catlow, R.A., J. Porous Mater., 2017, vol. 24, no. 2, pp. 421–428.
Gerasimova, L.G., Nikolaev, A.I., Shchukina, E.S., and Maslova, M.V., Dokl. Earth Sci., 2019. vol. 487, pp. 831–834.
Gerasimova, L.G., Maslova, M.V., and Shchukina, E.S., Khim. Tekhnol., 2008, no. 6, pp. 241–244.
Gerasimova, L.G, Maslova, M.V., and Shchukina, E.S., Mezhd. Zh. Prikl. Fundam. Issl., 2019, no. 7, pp. 112–117.
Du, H.B., Zhou, F.Q., Pang, W.Q., and Yue, Y., Micropor. Mater., 1996, vol. 7, no. 2/3, pp. 73–80.
RF Patent 2699614, appl. Dec. 12, 2018; publ. Sep. 6, 2019. Byul. No. 25.
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Gerasimova, L.G., Nikolaev, A.I., Shchukina, E.S. et al. Phase Transformations in an Alkaline Titanosilicate System upon Variation of the Temperature and Time Parameters. Dokl Chem 491, 49–53 (2020). https://doi.org/10.1134/S0012500820030039
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DOI: https://doi.org/10.1134/S0012500820030039