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The Effect of UV Irradiation on the Formation of Silver Molecular Clusters and Their Stabilization in Solutions and Composite and Oxide Coatings

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Abstract

The influence of UV irradiation on the formation of molecular silver clusters in aqueous solutions containing silver, zinc, magnesium nitrates, and polyvinylpyrrolidone has been studied. Solutions and coatings have been investigated using optical and luminescent spectroscopy methods, the morphology of coatings has been analyzed by electron microscopy. It has been shown that irradiation significantly accelerates the processes of reduction of silver ions and of formation of molecular clusters and silver nanoparticles stabilized by polyvinylpyrrolidone.

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Funding

This work was partially financially supported (S.K. Evstrop’ev) by the Russian Science Foundation, grant no. 19-19-00596.

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Authors and Affiliations

  1. St. Petersburg State Technological Institute (Technical University), 190013, St. Petersburg, Russia

    S. K. Evstrop’ev & D. P. Danilovich

  2. ITMO University, 197101, St. Petersburg, Russia

    N. V. Nikonorov & A. S. Saratovskii

Authors
  1. S. K. Evstrop’ev
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  2. N. V. Nikonorov
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  3. A. S. Saratovskii
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  4. D. P. Danilovich
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Corresponding author

Correspondence to S. K. Evstrop’ev.

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Translated by V. Rogovoi

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Evstrop’ev, S.K., Nikonorov, N.V., Saratovskii, A.S. et al. The Effect of UV Irradiation on the Formation of Silver Molecular Clusters and Their Stabilization in Solutions and Composite and Oxide Coatings. Opt. Spectrosc. 128, 707–712 (2020). https://doi.org/10.1134/S0030400X20060053

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