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Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

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Abstract

Reactivity of pymS‒SnPh3 (pymS = pyrimidine-2-thiolate) towards two unsaturated triosmium clusters [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] are investigated. Reaction of pymS‒SnPh3 with [Os3(CO)10(μ-H)2] affords [Os3(CO)10(µ-pymS)(µ-H)] (1) and [Os3(CO)9(µ3-pymS)(µ-H)] (2), while with [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] leads to the isolation of only [Os3(CO)8(μ-pymS)(μ-H)(μ-dppm)] (3). In both reactions, the products are formed via incorporation of the thiolate part (pymS) of pymS‒SnPh3 into the parent clusters through Sn‒S bond cleavage. Clusters 1–3 have been characterized by a combination of analytical and spectroscopic data together with single crystal X-ray diffraction analysis.

Graphic Abstract

Reactions of pymS‒SnPh3 with two unsaturated triosmium clusters have been investigated which resulted in the isolation and characterization of three triosmium clusters containing a pymS ligand.

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Acknowledgements

Financial support from the Ministry of Science and Technology, the Government of the People’s Republic of Bangladesh (SG and SEK) is acknowledged. We also thank the Wazed Miah Science Research Center, Jahangirnagar University, Bangladesh for providing some technical facilities required for this work.

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  1. Department of Chemistry, Jahangirnagar University, Savar, Dhaka, 1342, Bangladesh

    Md Tuhinur R. Joy, Shishir Ghosh & Shariff E. Kabir

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  1. Md Tuhinur R. Joy
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  3. Shariff E. Kabir
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Correspondence to Shishir Ghosh or Shariff E. Kabir.

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Joy, M.T.R., Ghosh, S. & Kabir, S.E. Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand. J Chem Crystallogr 51, 257–264 (2021). https://doi.org/10.1007/s10870-020-00849-y

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