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A Keggin-Type Tungstovanadate-Based Hybrid Compound: Synthesis, Crystal Structure, and Electrocatalytic Oxidation of Ascorbic Acid

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Abstract

A new V-centered Keggin polyoxometalate-based inorganic-organic hybrid (HPpz)3[VW12O40] (I) (Ppz = piperazine) has been hydrothermal synthesized and characterized by IR spectroscopy, UV−Vis spectroscopy, elemental analysis and single-crystal X-ray diffraction (CIF file CCDC no. 1835683). Compound I belongs to the rhombohedral space group \(R\bar {3}c\) and displays a three-dimensional supramolecular structure. The band gap energy value calculated for compound I was observed to be 1.30 eV using UV−Vis-NIR absorption spectrum. Furthermore, electrocatalytic performance of I has also been investigated in details.

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Funding

This work was supported by the National Natural Science Foundation of China (no. 21571049), the Natural Science Foundation of Henan Province of China (nos. 162300410027, 162300410013), the Foundation of the Education Department of Henan Province of China (no. 14A150022) and Open Research Funds of Henan Key Laboratory of Polyoxometalate Chemistry (HNPOMKF1607, HNPOMKF1701).

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Authors and Affiliations

  1. Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, 475004, Kaifeng, P.R. China

    S. K. Shi, R. Q. Kang, J. L. Li, Y. Bai & D. B. Dang

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  1. S. K. Shi
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  2. R. Q. Kang
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  3. J. L. Li
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  4. Y. Bai
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  5. D. B. Dang
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Correspondence to Y. Bai or D. B. Dang.

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Shi, S.K., Kang, R.Q., Li, J.L. et al. A Keggin-Type Tungstovanadate-Based Hybrid Compound: Synthesis, Crystal Structure, and Electrocatalytic Oxidation of Ascorbic Acid. Russ J Coord Chem 46, 513–520 (2020). https://doi.org/10.1134/S1070328420070064

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