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Synthesis of Organic-Inorganic Derivatives of Perovskite-Like Layered HCa2Nb3O10 Oxide with Monoethanolamine and Glycine

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Abstract

Novel hybrid organic-inorganic HCa2Nb3O10 × ОМ (OM = MEA, Gly) derivatives are synthesized through the intercalation of monoethanolamine and glycine into the interplanar space of protonated layered HCa2Nb3O10 · yH2O niobate. The compounds are characterized using X-ray phase, thermogravimetric, and elemental analysis and 13С NMR spectroscopy.

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REFERENCES

  1. Dion, M., Ganne, M., and Tournoux, M., Nouvelles familles de phases MIMII2Nb3O10 a feuillets perovskites, Mater. Res. Bull., 1981, vol. 16, no. 11, pp. 1429–1435.

    Article  CAS  Google Scholar 

  2. Fukuoka, H., Isami, T., and Yamanaka, S., Crystal structure of a layered perovskite niobate KCa2Nb3O10, J. Solid State Chem., 2000, vol. 151, pp. 40–45.

    Article  CAS  Google Scholar 

  3. Jacobson, A.J., Lewandowski, J.T., and Johnson, J.W., Ion exchange of the layered perovskite KCa2Nb3O10 by protons, J. Less-Common Met., 1986, vol. 116, no. 1, pp. 137–146.

    Article  CAS  Google Scholar 

  4. Jacobson, A.J., Johnson, J.W., and Lewandowski, J.T., Intercalation of the layered solid acid HCa2Nb3O10 by organic amines, Mater. Res. Bull., 1987, vol. 22, no. 1, pp. 45–51.

    Article  CAS  Google Scholar 

  5. Jacobson, A.J., Johnson, J.W., and Lewandowski, J.T., Interlayer chemistry between thick transition-metal oxide layers: Synthesis and intercalation reactions of KCa2Nan – 3NbnO3n + 1 (3< n < 7), Inorg. Chem., 1985, vol. 24, no. 23, pp. 3727–3729.

    Article  CAS  Google Scholar 

  6. Schaak, R.E. and Mallouk, T.E., Prying apart Ruddlesden-Popper phases: Exfoliation into sheets and nanotubes for assembly of perovskite thin films, Chem. Mater., 2000, vol. 12, no. 11, pp. 3427–3434.

    Article  CAS  Google Scholar 

  7. Nicolosi, V., Chhowalla, M., Kanatzidis, M.G., Strano, M.S., and Coleman, J.N., Liquid exfoliation of layered materials, Science (Washington, DC, U. S.), 2013, vol. 340, no. 6139, pp. 1226419–1226419.

    Article  Google Scholar 

  8. Tahara, S., Ichikawa, T., Kajiwara, G., and Sugahara, Y., Reactivity of the Ruddlesden–Popper phase H2La2Ti3O10 with organic compounds: Intercalation and grafting reactions, Chem. Mater., 2007, vol. 19, no. 9, pp. 2352–2358.

    Article  CAS  Google Scholar 

  9. Tahara, S., Preparation of inorganic-organic hybrids via intercalation and grafting reactions of protonated forms of ion-exchangeable layered perovskites, Thesis, Waseda Univ. Seiichi Tahara, 2007.

  10. Tahara, S. and Sugahara, Y., Interlayer surface modification of the protonated triple-layered perovskite HCa2Nb3O10 · xH2O with n-alcohols, Langmuir, 2003, vol. 19, no. 22, pp. 9473–9478.

    Article  CAS  Google Scholar 

  11. Han, Y.-S., Park, I., and Choy, J.-H., Exfoliation of layered perovskite, KCa2Nb3O10, into colloidal nanosheets by a novel chemical process, J. Mater. Chem., 2001, vol. 11, no. 4, pp. 1277–1282.

    Article  CAS  Google Scholar 

  12. Wang, Y., Nikolopoulou, M., Delahaye, E., Leuvrey, C., Leroux, F., Rabu, P., and Rogez, G., Microwave-assisted functionalization of the aurivillius phase Bi2SrTa2O9: Diol grafting and amine insertion vs. alcohol grafting, Chem. Sci., 2018, vol. 9, no. 35, pp. 7104–7114.

    Article  CAS  Google Scholar 

  13. Cattaneo, A.S., Ferrara, C., Marculescu, A.M., Giannici, F., Martorana, A., Mustarelli, P., and Tealdi, C., Solid-state NMR characterization of the structure and thermal stability of hybrid organic-inorganic compounds based on a HLaNb2O7 Dion–Jacobson layered perovskite, Phys. Chem. Chem. Phys., 2016, vol. 18, no. 31, pp. 21 903–21 912.

    Article  Google Scholar 

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ACKNOWLEDGMENTS

The studies were carried out using the equipment of the Research Park of St. Petersburg State University. The authors thank the Resource Center “X-ray Diffraction Methods of Study,” “Thermogravimetric and Calorimetric Methods of Study,” “Methods of the Analysis of the Composition of a Substance,” and “Magnetic-Resonance Methods of Study.”

Funding

The work was supported by the Russian Foundation for Basic Research (project no. 18-03-00915).

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Correspondence to O. I. Silyukov.

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Translated by A. Muravev

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Silyukov, O.I., Khramova, A.D. & Zvereva, I.A. Synthesis of Organic-Inorganic Derivatives of Perovskite-Like Layered HCa2Nb3O10 Oxide with Monoethanolamine and Glycine. Glass Phys Chem 46, 256–259 (2020). https://doi.org/10.1134/S1087659620030128

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  • DOI: https://doi.org/10.1134/S1087659620030128

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