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Thermal Aging of Perovskite Based Natural Gas Vehicle Catalysts: Dependency of the Mode of Pd Incorporation

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Abstract

Catalytic performance of fresh and aged impregnated Pd/LaFeO3 and sol gel LaFe1−xPdxO3 Natural Gas Vehicle Three-Way Catalysts, in powder form and wash-coated on ceramic monolith, have been investigated. Aging at 980 °C in wet atmosphere has no detrimental effect on the structural properties with the preservation of the orthorhombic structure of the perovskite. On the other hand, a loss of specific surface area is accompanied with surface Pd enrichment on LaFe1−xPdxO3 through ex solution process. It was found that the mode of Pd incorporation and subsequent aging has a limited impact on the catalytic performance at low temperature for the NO/H2 reaction. On the other hand, sharp rate enhancement in NO and methane conversion occurs at high temperature related to change in the reaction pathway from methane combustion to reforming reactions producing more efficient reducing agents to reduce NO. Such behaviour has been explained by the coexistence of palladium stabilized at different oxidation state at the surface and inside the perovskite structure.

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Acknowledgements

The authors would like to thank the Region Nord-Pas-de-Calais and ADEME for supporting this work through a Ph.D grant (Y. Renème). We greatly acknowledge Mrs Martine Trentesaux and Olivier Gardoll who conducted XPS measurements and thermal analysis.

Funding

This work has been done in the frame of the ANR project ANR-07-PDIT-001 « Caravelle».

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Authors and Affiliations

  1. Univ. Lille, CNRS, Centrale Lille, Univ. Artois, UMR 8181 - UCCS - Unité de Catalyse et Chimie du Solide, 59000, Lille, France

    P. Granger, Y. Renème & F. Dhainaut

  2. Institut Régional des Matériaux Avancés (IRMA), 2, allée Copernic, Parc technologique de Soye, 56270, Ploemeur, France

    A. Lahougue & C. Hamon

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  1. P. Granger
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  2. Y. Renème
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  3. A. Lahougue
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  5. F. Dhainaut
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Correspondence to P. Granger.

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Granger, P., Renème, Y., Lahougue, A. et al. Thermal Aging of Perovskite Based Natural Gas Vehicle Catalysts: Dependency of the Mode of Pd Incorporation. Top Catal 63, 1474–1484 (2020). https://doi.org/10.1007/s11244-020-01331-x

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