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Fluorescent Probe Derived from 1,8-Naphthalimide-Schiff Base for Copper(Ii) Ion: Synthesis, Characterization, and Application

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Journal of Applied Spectroscopy Aims and scope

A novel fluorescent probe, 2-allyl-6-((2-((2-hydroxy-5-nitrobenzylidene)amino)ethyl)amino)-1H-benzo[de]isoquinoline- 1,3(2H)-dione (ABID), based on naphthalimide-Schiff base, has been designed and synthesized for the monitoring of Cu2+ ions. In solution (DMSO/HEPES, 1:1, v/v, pH 7.4), ABID displayed fluorescence quenching towards Cu2+ ions over other important metal ions. A good linearity with a correlation coefficient (R2) of 0.99 validated that the ABID probe could be used to detect Cu2+ ions in 0.5–5.0 μM concentrations. The limit of detection of ABID for Cu2+ could reach at 3.4 × 10–7 M level, and the quenching constant (KSV) of ABID towards Cu2+ was calculated to be 3.4 × 104 M–1. The 2:1 stoichiometry and the binding mode between ABID and Cu2+ were studied by a Job plot and UV-Vis and fluorescence titration. Additionally, ABID was successfully employed to monitor Cu2+ in the Yellow River and tap water samples.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou, 730070, Gansu, China

    Y. Qu, C. Wang, Y.-C. Wu, K. Zhao & H.-L. Wu

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  1. Y. Qu
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  2. C. Wang
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  3. Y.-C. Wu
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  5. H.-L. Wu
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Correspondence to H.-L. Wu.

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Published in Zhurnal Prikladnoi Spektroskopii, Vol. 87, No. 3, pp. 387–394, May–June, 2020.

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Qu, Y., Wang, C., Wu, YC. et al. Fluorescent Probe Derived from 1,8-Naphthalimide-Schiff Base for Copper(Ii) Ion: Synthesis, Characterization, and Application. J Appl Spectrosc 87, 429–436 (2020). https://doi.org/10.1007/s10812-020-01018-x

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