The effect of neodymium addition in the composition of complex bismuth cuprates Bi2Sr2–xNdxCaCu2Oy (0 ≤ x ≤ 0.1) on their structural and electrophysical characteristics and catalytic properties is found. It is established that increase in the neodymium content is accompanied by antibate (inverse) change in the unit cell parameters, increased structural defectiveness, and slight increase of the superconducting temperature. The increased activity of the Nd-substituted cuprates in the oxidation of CO is due to increase in the defectiveness of the structure and the content of mobile oxygen in the crystal lattice.
Similar content being viewed by others
References
G. Ravikumar and J. V. Yakhmi, Functional Materials: Preparation, Processing and Applications (Eds. S. Banerjee, A. K. Tyagi), Elsevier, Amsterdam, etc. (2011), pp. 261-284.
K. W. Wong and W. Y. Ching, Physica C, 416, No. 1/2, 47-67 (2004).
I. M. Golev, A. V. Sergeev, and O. V. Kalyadin, Phys. Solid State, 59, No. 1, 16-20 (2017).
J. B. Goodenough and A. Manthiram, J. Solid State Chem., 88, 115-139 (1990).
P. Majewski, J. Mater. Res., 15, No. 4, 854-870 (2000).
I. M. Golev, Fizika Tverdogo Tela, 59, No. 1, 19-22 (2017).
A. Sergeeva, I. Golev, Mater. Today-Proc., 11, 489-493 (2019).
D. Klissurski and V. Rives, Appl. Catal. A, 109, No. 1, 1-44 (1994).
S. M. Haile, Acta Mater., 51, 5981-6000 (2003).
L. Xiang, A. Didier, Coord. Chem. Rev., 359, 112-126 (2018).
A. V. Knot’ko, A. V. Garshev, M. N. Pul’kin, et al., 46, No. 3, 414-418 (2004).
Yu. D. Tret’yakov and E. A. Gudilin, Uspekhi Khimii, 69, No. 1, 1-34 (2000).
A. P. Mozhaev, V. I. Pershin, and V. P. Shabatin, Zh. Vsesoyuz. Khim. Ob-va im. D. I. Mendeleeva, 34, No. 4, 504-508 (1989).
R. M. Hazen, C. T. Prewitt, R. J. Angel, et al., Phys. Rev. Lett., 60, No. 12, 1174-1177 (1988).
S. Nedil’ko, D. Naumova, and T. Voitenko, Visn. Kiiv. Nats. Un-tu im. T. Shevchenka. Ser. Khimiya, No. 48, 4-5 (2010).
D. D. Naumova, I. O. Korbut, T. A. Voitenko, and S. A. Nedil’ko, Fizika i Khimiya Tverdogo Tila, 13, No. 1, 142-145 (2012).
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated from Teoreticheskaya i Éksperimental’naya Khimiya, Vol. 56, No. 2, pp. 122-126, March-April, 2020.
Rights and permissions
About this article
Cite this article
Didenko, O.Z., Kosmambetova, G.R., Fesych, I.V. et al. Effect of Composition of Superconducting Cuprates Bi2Sr2–xNdxCaCu2Oy(0≤ x ≤ 0.1) on their Electrophysical Characteristics and Catalytic Properties in Carbon Monoxide Oxidation. Theor Exp Chem 56, 130–135 (2020). https://doi.org/10.1007/s11237-020-09646-2
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11237-020-09646-2