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Synthesis and properties of novel polyimides based on 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10H)-anthrone

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Abstract

A new aromatic diamine bearing ether and pendant 9(10H)-anthrone groups, 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10H)-anthrone was reacted with various aromatic dianhydrides to yield the corresponding cardo polyimides via the poly(amic acid) (PAA) precursors and thermal or chemical imidization. The PAAs were produced with moderate to high inherent viscosities of 0.91–1.53 dL/g. All the PAAs could be cast from DMAc solution and thermally converted into transparent, flexible and tough polyimide films with tensile strength of 79.6–115.2 MPa, tensile modulus of 1.97–2.48 GPa, and elongation at break of 10.8–21.7%. These polyimides were predominantly amorphous, and displayed excellent thermal stability with glass-transition temperature of 290–359 °C, 10% weight loss temperature of 522–566 °C, and the residue of 59–65% at 800 °C in nitrogen. Most of the polyimides obtained by chemical cyclodehydration procedure were found to be soluble in NMP, DMF and mcresol at room temperature.

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Acknowledgments

The financial support for this work provided by the National Natural Science Foundation of China (No. 21564005, 51663011), the Research Program of Jiangxi Science and Technology Department (No. 20192BBE50049), the Ground Project for Science and Technology of Jiangxi Universities (No. KJLD14022) and the Research Program of Jiangxi Province Department of Education (No. GJJ14236) is gratefully acknowledged.

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Correspondence to Zhen-Zhong Huang.

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Li, J., Mao, XC., Huang, ZZ. et al. Synthesis and properties of novel polyimides based on 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10H)-anthrone. J Polym Res 27, 214 (2020). https://doi.org/10.1007/s10965-020-02190-6

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