Skip to main content
SpringerLink
Log in

Optimization of Magnesium-Based Solid-State Hydrogen Storage for Vehicles

  • PHYSICAL SCIENCE OF MATERIALS
  • Published:
Technical Physics Aims and scope Submit manuscript

Abstract

Magnesium powders with small additives of other metals are studied to determine the optimal conditions for hydrogenation and dehydrogenation for using them as a solid-state hydrogen storage for vehicles. An optimal composition with the weight formula Mg10Ni has been found. Only this composition is not subject to degradation of the reversible hydrogen capacity during cycling. It has been found that the maximum reversible capacity is achieved at the minimum hydrogenation temperature. An idea for choosing the optimal magnesium additive is proposed that is based on the atomic and electronic level.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.

Similar content being viewed by others

REFERENCES

  1. A. N. Podgornyi, I. L. Varshavskii, A. A. Makarov, and A. I. Mishchenko, Preprint No. 45 (IP Mash AN USSR. Khar’kov, 1977).

  2. I. L. Varshavskii, A. I. Mishchenko, and V. Yu. Stepanov, in Proceedings of the All-Union Conference on Protection of the Air Basin from Pollution by Toxic Emissions of Vehicles, Khar’kov (IP Mash AN USSR, Khar’kov, 1977), Vol. 1, p. 83.

  3. I. L. Varshavskii, in Hydrogen Atomic Energy and Technology (Atomizdat, Moscow, 1980), No. 3 [in Russian].

  4. N. D. Kuznetsov, in Hydrogen Atomic Energy and Technology (Atomizdat, Moscow, 1980), No. 3 [in Russian].

  5. A. I. Mishchenko, The Use of Hydrogen for Automotive Engines (Naukova Dumka, Kiev, 1984) [in Russian].

    Google Scholar 

  6. A. S. Koroteev, V. V. Mironov, and V. A. Smolyarov, Al’tern. Energet. Ekol., No. 1, 5 (2004).

  7. A. V. Vakhrushev, Yu. G. Yanovskii, I. A. Shestakov, and A. Yu. Fedotov, Al’tern. Energet. Ekol. 34, 41 (2004).

    Google Scholar 

  8. A. S. Baibikov, Al’tern. Energet. Ekol., No. 10, 30 (2009).

  9. Mosk. Pravda, No. 247 (16954) (1975).

  10. F. M. Konarev, Water is a New Source of Energy, 3rd ed. (Krasnodar, 2001) [in Russian].

    Google Scholar 

  11. Hydrogen. Properties, Receipt, Storage, Transportation, Application, Reference Book, Ed. by D. Yu. Gamburg and N. F. Dubovkin (Khimiya, Moscow, 1989) [in Russian].

    Google Scholar 

  12. A. I. Mishchenko and Yu. V. Cherkashin, Avtomobil. Prom-st', No. 9, 21 (1980).

  13. A. S. Chernikov, V. N. Fadeev, and V. I. Savin, in Hydrogen Atomic Energy and Technology (Atomizdat, Moscow, 1980), No. 3 [in Russian].

  14. Yu. I. Shanin, Al’tern. Energet. Ekol., No. 3, 50 (2002).

  15. E. E. Shpil’rain, S. P. Malyshenko, and G. G. Kuleshov, Introduction to Hydrogen Energy (Energoatomizdat, Moscow, 1984) [in Russian].

    Google Scholar 

  16. G. C. Sarter and F. L. Carter, Metal-Hydrogen Systems, Ed. by T. N. Veziroglu (Pergamon, Oxford, 1982), p. 503.

    Google Scholar 

  17. P. P. Turillon, in Hydrogen Energy Progress IV, Ed. by T. N. Veziroglu (Pergamon, Oxford, 1982), Vol. 3, p. 1289.

    Google Scholar 

  18. H. Buchner, in Hydrogen Energy Progress IV, Ed. by T. N. Veziroglu and W. Seifritz (Pergamon, Oxford, 1978), Vol. 4, p. 1749.

    Google Scholar 

  19. M. M. Antonova, Preprint No. 93–1 (Inst. Probl. Sci. Mater., Acad. Sci. Ukr., Kiev, 1992).

  20. A. I. Zakharov, Vas. V. Ivankov, Vyach. V. Ivankov, V. N. Terekhov, and O. A. Milovanova, Al’tern. Energet. Ekol., No. 2, 20 (2002).

  21. B. P. Tarasov, V. N. Fokin, D. N. Borisov, E. I. Gusachenko, S. N. Klyamkin, N. A. Yakovleva, and S. P. Shilkin, Al’tern. Energet. Ekol., No. 1 (9), 47 (2004).

  22. B. P. Tarasov, Al’tern. Energet. Ekol., No. 2 (34), 11 (2006).

  23. V. M. Azhazha, M. A. Tikhonovskii, A. G. Shepelev, Yu. P. Kurilo, T. A. Ponomarenko, and D. V. Vinogradov, Vopr. At. Nauki Tekh., No. 1, 145 (2006).

  24. Al'tern. Energet. Ekol., No. 3 (59), 160 (2008).

  25. L. Belkbir, N. Gerard, and A. Percheron-Guegan, Int. J. Hydrogen Energy 4, 541 (1978).

    Article  Google Scholar 

  26. Sh. Z. Dzhamagidze, B. M. Zykov, E. P. Sabo, and R. R. Shvangiradze, Nauka Tekhnol. Prom-sti, No. 4, 35 (2008).

    Google Scholar 

  27. T. N. Dymova, Z. K. Sterlyadkina, and V. G. Safronov, Zh. Neorg. Khim. 6, 763 (1961).

    Google Scholar 

  28. W. M. Mueller, J. P. Blackledge, and G. G. Libowitz, Metal Hydrides (Academic, New York, 1968).

    Google Scholar 

  29. Transition Metal Hydrides, Ed. by E. L. Muetterties (Marcel Dekker, New York, 1971).

    Google Scholar 

  30. M. M. Antonova and R. A. Morozova, Preparative Chemistry of Hydrides, The Handbook (Naukova Dumka, Kiev, 1976) [in Russian].

    Google Scholar 

  31. Hydrogen in Metals, Vol. 2: Application-Oriented Properties, Ed. by G. Alefeld and J. Vüuolkl (Springer, Berlin, 1978).

  32. B. M. Bulychev and P. A. Storozhenko, Al’tern. Energet. Ekol., No. 4, 5 (2004).

  33. Physicochemical Properties of Elements, Ed. G. V. Samsonov (Naukova Dumka, Kiev, 1965) [in Russian].

    Google Scholar 

  34. B. M. Zykov, D. S. Ikonnikov, and V. K. Tskhakaya, Sov. Phys. Solid State 17, 163 (1975).

    Google Scholar 

  35. B. M. Zykov, D. S. Ikonnikov, and V. K. Tskhakaya, Sov. Phys. Solid State 19, 2144 (1977).

    Google Scholar 

  36. B. M. Zykov, V. P. Kobyakov, and Yu. I. Nardaya, Vysokochist. V-va, No. 1, 71 (1991).

    Google Scholar 

  37. I. I. Kornilov and V. V. Glazova, Interaction of Refractory Metals of Transition Groups with Oxygen (Nauka, Moscow, 1967) [in Russian].

    Google Scholar 

  38. B. M. Zykov and A. M. Sabel’nikov, Poverkhnost’, No. 10, 61 (1988).

  39. J. J. Sarrol and A. J. Melmed, Surf. Sci. 16, 251 (1969).

    Article  ADS  Google Scholar 

  40. A. V. Bravarets, B. M. Zykov, V. N. Zykova, V. N. Lebedev, and Yu. K. Udovichenko, Zh. Tekh. Fiz. 47, 1176 (2002).

    Google Scholar 

  41. B. M. Zykov, V. N. Zykova, V. N. Lebedev, and Yu. K. Udovichenko, Zh. Tekh. Fiz. 47, 742 (2002).

    Google Scholar 

  42. Yu. N. Kukushkin and E. I. Maslov, Atom Structure and Chemical Bonding (Leningr. Univ., Leningrad, 1973) [in Russian].

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Sukhumi Institute of Physics and Technology, Academy of Sciences of Abkhazia, Sukhumi, Abkhazia, Russia

    B. M. Zykov, T. M. Krasnenkova, B. A. Lazba & A. I. Markoliya

Authors
  1. B. M. Zykov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. M. Krasnenkova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. B. A. Lazba
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. Markoliya
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. M. Krasnenkova.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

Translated by E. Chernokozhin

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Zykov, B.M., Krasnenkova, T.M., Lazba, B.A. et al. Optimization of Magnesium-Based Solid-State Hydrogen Storage for Vehicles. Tech. Phys. 65, 946–956 (2020). https://doi.org/10.1134/S1063784220060298

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1063784220060298

Search

Navigation