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Three Different Co(II) Metal–Organic Frameworks Based on 4,4′-Bis(imidazolyl)diphenyl Ether: Syntheses, Crystal Structure and Photocatalytic Properties

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Abstract

Three Co(II) metal–organic frameworks (Co-MOFs) build by 4,4′-bis(imidazolyl)diphenyl ether (bidpe), m-Phthalic acid (H2mpa), 5-Nitroisophthalic acid (H2nmpa) and 5-sulfonatobenzene-1,3-dicarboxylate (H2smpa), namely: [Co(mpa)(bidpe)]n (1), [Co(nmpa)(bidpe)]n (2), {[Co1.5(smpa)(bidpe)2]·1.5H2O·0.25DMA}n (3), were synthesized under same solvothermal condition. The compounds have been characterized by elemental analysis, IR spectroscopy, single-crystal X-ray diffraction, thermogravimetric (TG) analysis and powder X-ray diffraction (PXRD). The single-crystal X-ray diffraction analysis reveals that compound 1 shows a 4-connected sql net with Schläfli point symbol (44·62). Compound 2 displays a 3, 5-connected net with Schläfli point symbol (42·67·8)(42·6). Compound 3 possesses a 3-connected net with Schläfli point symbol (42·6). The photocatalytic investigations indicate that compounds 1–3 afford good photocatalytic capabilities in degradation of methylene blue (MB) and methylene violet (MV). Furthermore, the possible photocatalytic mechanisms have been discussed.

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Acknowledgements

This work was supported by the Fundamental Research Funds for the Central Universities (Grant No. 201822012), the National Natural Science Foundation of China (Grant Nos. 21476218 and 21601171). Guangxi Natural Science Foundation Program (Grant No. 2019GXNSFBA245086).

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Authors and Affiliations

  1. Ocean University of China, Qingdao, 266100, Shandong, China

    Dongmei Zhang, Caifeng Bi & Yuhua Fan

  2. School of Laboratory Medicine, Youjiang Medical University for Nationalities, Baise, 533000, Guangxi, China

    Ziao Zong

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  1. Dongmei Zhang
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  2. Caifeng Bi
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  3. Ziao Zong
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  4. Yuhua Fan
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Correspondence to Ziao Zong or Yuhua Fan.

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Zhang, D., Bi, C., Zong, Z. et al. Three Different Co(II) Metal–Organic Frameworks Based on 4,4′-Bis(imidazolyl)diphenyl Ether: Syntheses, Crystal Structure and Photocatalytic Properties. J Inorg Organomet Polym 30, 5148–5156 (2020). https://doi.org/10.1007/s10904-020-01657-9

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