Skip to main content
SpringerLink
Log in

Determination of Cysteine by Diffuse Reflectance Spectroscopy by Its Influence on the Formation of Gold Nanocomposites Based on Polyurethane Foam

  • ARTICLES
  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

A method is proposed for the determination of cysteine in an aqueous solution by its effect on the formation of gold nanoparticles on the surface of polyurethane foams. The method is based on the interaction of in situ formed gold nanoparticles with cysteine, which results in their stabilization in solution and in a decrease in the color intensity of the nanocomposite detected by diffuse reflectance spectroscopy. The effect of the concentration of the precursor, aurichlorohydric acid, contact time of phases, and the pH of the solution on the sensitivity of cysteine determination is studied. Under the selected conditions, the limit of detection for cysteine was 0.36 μg/mL. A possibility of using the proposed method for the determination of cysteine in brewer’s yeast is demonstrated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Lavergne, V., Taft, R.J., and Alewood, P.F., Curr. Top. Med. Chem., 2012, vol. 12, p. 1514.

    Article  CAS  Google Scholar 

  2. Lee, P.T., Thomson, J.E., Karina, A., Salter, C., Johnston, C., Davies, S.G., and Compton, R.G., Analyst, 2015, vol. 140, p. 236.

    Article  CAS  Google Scholar 

  3. Reddie, K.G. and Carroll, K.S., Curr. Opin. Chem. Bi-ol., 2013, vol. 12, p. 746.

    Article  Google Scholar 

  4. Adams, S.H., Adv. Nutr., 2011, vol. 2, p. 445.

    Article  CAS  Google Scholar 

  5. Miki, H. and Funato, Y., J. Biochem., 2012, vol. 151, p. 255.

    Article  CAS  Google Scholar 

  6. McLennan, S.V., Abdollahi, M., and Twigg, S.M., Curr. Opin. Nephrol. Hypertens., 2013, vol. 22, p. 85.

    Article  CAS  Google Scholar 

  7. Zhang, L.-N., Sun, Y.-J., Pan, S., Li, J.-X., Qu, Y.-E., Li, Y., Wang, Y.-L., and Gao, Z.-B., Fundam. Clin. Pharmacol., 2013, vol. 27, p. 96.

    Article  Google Scholar 

  8. Chaihi, M.J., Ehsani, M., Khajvand, Y., Golchoubian, H., and Rezaee, E., Spectrochim. Acta, Part A, 2014, vol. 122, p. 405.

    Article  Google Scholar 

  9. Lu, J., Sun, C., Chen, W., Ma, H., Shi, W., and Li, X., Talanta, 2011, vol. 83, p. 1050.

    Article  CAS  Google Scholar 

  10. Liu, W., Luo, J., Guo, Y., Kou, J., Li, B., and Zhang, Z., Talanta, 2012, vol. 120, p. 341.

    Google Scholar 

  11. Wang, K., Qian, J., Jiang, D., Yang, Z., Du, X., and Wang, K., Biosens. Bioelectron., 2015, vol. 65, p. 83.

    Article  Google Scholar 

  12. Kargosha, K., Ahmadi, S.H., Zeeb, M., and Moeinossadat, S.R., Talanta, 2008, vol. 74, p. 753.

    Article  CAS  Google Scholar 

  13. Rezanka, P., Koktan, J., Rezankova, H., Matejka, P., and Kral, V., Colloids Surf., A, 2013, vol. 436, p. 961.

    Article  CAS  Google Scholar 

  14. Bronowicka-Adamska, P., Zagajewski, J., Czubak, J., and Wrobel, M., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2011, vol. 879, p. 2005.

    Article  CAS  Google Scholar 

  15. Cevasco, G., Piatek, A.M., Scapolla, C., and Thea, S., J. Chromatogr. A, 2010, vol. 1217, p. 2158.

    Article  CAS  Google Scholar 

  16. Ferin, R., Pavao, M.L., and Baptiata, J., J. Chromatogr. B: Anal. Technol. Biomed. Life Sci., 2012, vol. 911, p. 15.

    Article  CAS  Google Scholar 

  17. Hsiao, Y.-P., Su, W.-Y., Cheng, J.-R., and Cheng, S.-H., Electrochim. Acta, 2011, vol. 56, p. 6887.

    Article  CAS  Google Scholar 

  18. Xu, H., Xiao, J., Liu, B., Griveau, S., and Bedioui, F., Biosens. Bioelectron., 2015, vol. 66, p. 438.

    Article  CAS  Google Scholar 

  19. De Carvalho Castro e Silva, C., Breitkreitz, M.C., Santhiago, M., Corrêa, C.C., and Kubota, L.T., Electrochim. Acta, 2012, vol. 71, p. 150.

    Article  Google Scholar 

  20. Sharma, V.V., Guadagnini, L., Giorgetti, M., and Tonelli, D., Sens. Actuators, B, 2016, vol. 228, p. 16.

    Article  CAS  Google Scholar 

  21. Amendola, V., Pilot, R., Frasconi, M., Maragò, O.M., and Iatì, M.A., J. Phys.: Condens. Matter, 2017, vol. 29.

  22. Ghosh, S.K. and Pal, T., Chem. Rev., 2007, vol. 107, p. 4797.

    Article  CAS  Google Scholar 

  23. Apyari, V.V., Arkhipova, V.V., Dmitrienko, S.G., and Zolotov, Yu.A, J. Anal. Chem., 2014, vol. 69, no. 1, p. 1.

    Article  CAS  Google Scholar 

  24. Apyari, V.V., Arkhipova, V.V., Isachenko, A.I., Volkov, P.A., Dmitrienko, S.G., and Torocheshnikova, I.I., Sens. Actuators, B, 2018, vol. 260, p. 953.

    Article  CAS  Google Scholar 

  25. Wei, X., Qi, L., Tan, J., Liu, R., and Wang, F., Anal. Chim. Acta, 2010, vol. 671, p. 80.

    Article  CAS  Google Scholar 

  26. Apyari, V.V., Arkhipova, V.V., Gorbunova, M.V., Volkov, P.A., Isachenko, A.I., Dmitrienko, S.G., and Zolotov, Yu.A., Talanta, 2016, vol. 161, p. 780.

    Article  CAS  Google Scholar 

  27. Zhang, Y., Jiang, J., Li, M., Gao, P., Zhou, Y., Zhang, G., Shuang, S., and Dong, C., Talanta, 2016, vol. 161, p. 520.

    Article  CAS  Google Scholar 

  28. Ghasemi, F., Hormozi-Nezhad, M.R., and Mahmoudi, M., Anal. Chim. Acta, 2015, vol. 882, p. 58.

    Article  CAS  Google Scholar 

  29. Hormozi-Nezhad, M.R., Seyedhosseinia, E., and Robatjazi, H., Sci. Iran., 2012, vol. 19, p. 958.

    Article  CAS  Google Scholar 

  30. Gao, H., Shen, W., Lu, C., Liang, H., and Yuan, Q., Talanta, 2013, vol. 115, p. 1.

    Article  CAS  Google Scholar 

  31. Dykman, L.A. and Bogatyrev, V.A., Russ. Chem. Rev., 2007, vol. 76, no. 2, p. 181.

    Article  CAS  Google Scholar 

  32. Apyari, V.V., Gorbunova, M.V., Isachenko, A.I., Dmitrienko, S.G., and Zolotov, Yu.A., J. Anal. Chem., 2017, vol. 72, no. 11, p. 1127.

    Article  CAS  Google Scholar 

  33. Apyari, V.V., Dmitrienko, S.G., Batov, I.V., and Zolotov, Yu.A., J. Anal. Chem., 2011, vol. 66, no. 2, p. 144.

    Article  CAS  Google Scholar 

  34. Apyari, V.V., Dmitrienko, S.G., and Zolotov, Yu.A., Sens. Actuators, B, 2013, vol. 188, p. 1109.

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Russian Science Foundation, project no. 18-73-10001.

Author information

Authors and Affiliations

  1. Department of Chemistry, Moscow State University, 119991, Moscow, Russia

    A. I. Isachenko, V. V. Apyari, S. G. Dmitrienko & Yu. A. Zolotov

  2. Institute of Chemical Reagents and Highly Pure Chemicals, National Research Center “Kurchatov Institute,”, 107076, Moscow, Russia

    P. A. Volkov

  3. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    Yu. A. Zolotov

Authors
  1. A. I. Isachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Apyari
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. P. A. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. G. Dmitrienko
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yu. A. Zolotov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to A. I. Isachenko.

Additional information

Translated by V. Kudrinskaya

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Isachenko, A.I., Apyari, V.V., Volkov, P.A. et al. Determination of Cysteine by Diffuse Reflectance Spectroscopy by Its Influence on the Formation of Gold Nanocomposites Based on Polyurethane Foam. J Anal Chem 75, 890–895 (2020). https://doi.org/10.1134/S1061934820070102

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1061934820070102

Keywords:

Search

Navigation