Skip to main content
SpringerLink
Log in

X-ray Spectroscopic Studies of the Atomic and Electronic Structure of the PANI/Cu Nanocomposite

  • Published:
Journal of Surface Investigation: X-ray, Synchrotron and Neutron Techniques Aims and scope Submit manuscript

Abstract

X-ray absorption near edge structure spectroscopy (XANES; NEXAFS is used for soft X-rays) and X-ray photoelectron spectroscopy (XPS) are used to study the local structure of the PANI/Cu nanocomposite obtained in the polymerization of aniline by chemical oxidation in the presence of copper-chloride dihydrate without the addition of acid. Copper in the composite is divalent and copper atoms with different local environments are present. Polyaniline is oxidized and protonated during the formation of the nanocomposite. Protonation occurs through imine groups.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. P. J. Kinlen, J. Liu, and Y. Ding, Macromolecules 31 (6), 1735 (1998).

    Article  CAS  Google Scholar 

  2. L. G. Bulusheva, E. O. Fedorovskaya, A. V. Okotrub, E. A. Maximovskiy, D. V. Vyalikh, X. Chen, and H. Song, Phys. Status Solidi B 248 (11), 2484 (2011).

    Article  CAS  Google Scholar 

  3. V. V. Abalyaeva, N. N. Dremova, and N. N. Vershinin, Russ. J. Electrochem. 49 (9), 863 (2013).

    Article  CAS  Google Scholar 

  4. N. M. Ivanova, E. A. Soboleva, Ya. A. Visurkhanova, and I. V. Kirilyus, Russ. J. Electrochem. 51, 166 (2015).

    Article  CAS  Google Scholar 

  5. A. A. Matnishyan, T. L. Akhnazaryan, G. V. Abagyan, G. R. Badalyan, S. I. Petrosyan, and V. D. Kravtsova, Phys. Solid State 53, 1727 (2011).

    Article  CAS  Google Scholar 

  6. P. K. Khann, M. V. Kulkarni, N. Singh, S. P. Lonkar, V. V. V. S. Subbarao, and A. K. Viswanath, Mater. Chem. Phys. 95 (1), 24 (2006).

    Article  Google Scholar 

  7. K. Mallick, M. J. Witcomb, A. Dinsmore, and M. S. Scurrell, J. Polym. Res. 13, 397 (2006).

    Article  CAS  Google Scholar 

  8. R. Ullah, G. A. Bowmaker, C. Laslau, G. I. N. Waterhouse, Z. D. Zujovic, K. Ali, A. U. H. Ali Shah, and J. Travas-Sejdic, Synth. Met. 198, 203 (2014).

    Article  CAS  Google Scholar 

  9. G. E. Yalovega, T. N. Myasoedova, V. A. Shmatko, M. M. Brzhezinskaya, and Y. V. Popov, Appl. Surf. Sci. 372, 93 (2016).

    Article  CAS  Google Scholar 

  10. M. A. Kremennaya, M. A. Soldatov, Y. S. Podkovyrina, I. A. Dadasheva, and A. V. Soldatov, J. Struct. Chem. 58 (6), 1213 (2017).

    Article  CAS  Google Scholar 

  11. A. O. Porto, J. M. Pernaut, H. Daniel, P. J. Schilling, and M. C. Martins Alves, Synth. Met. 104, 89 (1999).

    Article  CAS  Google Scholar 

  12. J. L. Fulton, M. M. Hoffmann, J. G. Darab, and B. J. Palmer, J. Phys. Chem. A 104, 11651 (2000).

    Article  CAS  Google Scholar 

  13. G. Yalovega, T. Myasoedova, A. Funik, N. Plugotarenko, M. Brzhezinskaya, and A. Bahmatskaya, Phys. Status Solidi B 253 (11), 2217 (2016).

    Article  CAS  Google Scholar 

  14. C. M. S. Izumi, V. R. L. Constantino, and M. L. A. Temperini, J. Phys. Chem. B 109, 22131 (2005).

    Article  CAS  Google Scholar 

  15. M. Todaro, L. Sciortino, F. M. Gelardi, and G. Buscarino, J. Phys. Chem. C 121, 24853 (2017).

    Article  CAS  Google Scholar 

  16. A. Gaur, W. Klysubun, B. Sonic, D. Shrivastav, J. Prasad, and K. Srivastava, J. Mol. Struct. 1121, 119 (2016).

    Article  CAS  Google Scholar 

  17. J. Melke, B. Peter, A. Habereder, J. Ziegler, C. Fasel, A. Nefedov, H. Sezen, C. Wöll, H. Ehrenberg, and C. Roth, ACS Appl. Mater. Interfaces 8 (1), 82 (2016).

    Article  CAS  Google Scholar 

  18. C. Hennig, K. H. Hallmeier, and R. Szargan, Synth. Met. 92 (2), 161 (1998).

    Article  CAS  Google Scholar 

  19. H. Mi, F. Li, C. He, X. Chai, Q. Zhang, C. Li, Y. Li, and J. Liu, Electrochim. Acta 190, 1032 (2016).

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the Presidential Grant MK-4933.2018.2 and in part by the Internal Grant of the Southern Federal University (VnGr-07/2017-30).

Author information

Authors and Affiliations

  1. Southern Federal University, 344006, Rostov-on-Don, Russia

    V. A. Shmatko, T. N. Myasoedova & G. E. Yalovega

  2. National Research Center “Kurchatov Institute”, 123181, Moscow, Russia

    A. L. Trigub

Authors
  1. V. A. Shmatko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. T. N. Myasoedova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. L. Trigub
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. G. E. Yalovega
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. A. Shmatko.

Additional information

Translated by L. Mosina

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shmatko, V.A., Myasoedova, T.N., Trigub, A.L. et al. X-ray Spectroscopic Studies of the Atomic and Electronic Structure of the PANI/Cu Nanocomposite. J. Surf. Investig. 14, 479–483 (2020). https://doi.org/10.1134/S1027451020030179

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1027451020030179

Keywords:

Search

Navigation