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Licensed Unlicensed Requires Authentication Published by De Gruyter July 6, 2020

Single-crystal structure determination of LaNi5–xInx and LaNi9–xIn2+x

  • Yaroslav Kalychak , Mariya Dzevenko EMAIL logo , Volodymyr Babizhetskyy , Marek Daszkiewicz and Lubomir Gulay

Abstract

The crystal structures of the solid solution LaNi5–xInx (x = 0.51) and the ternary compound LaNi9–xIn2+x (x = 0.80) have been investigated by single-crystal X-ray data. The LaNi5–xInx phase is isotypic with CaCu5: space group P6/mmm, a = 5.042(2), c = 4.009(1) Å. The crystal structure investigation of LaNi9–xIn2+x (x = 0.80) was performed at T = 295 and 100 K: YNi9In2 type, space group P4/mbm, a = 8.3976(3), c = 5.0439(3) Å for T = 295 K and a = 8.3814(2), c = 5.0352(2) Å for T = 100 K. The lanthanum atoms are located on split positions 2a (0 0 0) and 4e (0 0 0.05).


Corresponding author: Mariya Dzevenko, Chemical Faculty,Ivan Franko National University of Lviv, Kyryla i Mefodiya Street 6, UA-79005, Lviv, Ukraine, E-mail:

  1. Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.

  2. Research funding: None declared.

  3. Conflict of interest statement: The authors declare no conflicts of interest regarding this article.

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Received: 2020-01-27
Accepted: 2020-03-15
Published Online: 2020-07-06
Published in Print: 2020-08-27

© 2020 Walter de Gruyter GmbH, Berlin/Boston

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