Abstract
The crystal structures of the solid solution LaNi5–xInx (x = 0.51) and the ternary compound LaNi9–xIn2+x (x = 0.80) have been investigated by single-crystal X-ray data. The LaNi5–xInx phase is isotypic with CaCu5: space group P6/mmm, a = 5.042(2), c = 4.009(1) Å. The crystal structure investigation of LaNi9–xIn2+x (x = 0.80) was performed at T = 295 and 100 K: YNi9In2 type, space group P4/mbm, a = 8.3976(3), c = 5.0439(3) Å for T = 295 K and a = 8.3814(2), c = 5.0352(2) Å for T = 100 K. The lanthanum atoms are located on split positions 2a (0 0 0) and 4e (0 0 0.05).
Author contribution: All the authors have accepted responsibility for the entire content of this submitted manuscript and approved submission.
Research funding: None declared.
Conflict of interest statement: The authors declare no conflicts of interest regarding this article.
References
1. Tyvanchuk, Y. B., Zaremba, V. I., Akselrud, L. G., Szytula, A., Kalychak, Y. M. J. Alloys Compd. 2017, 704, 717–723. http://dx.doi.org/10.1016/j.jallcom.2017.02.023.10.1016/j.jallcom.2017.02.023Search in Google Scholar
2. Tyvanchuk, Y. B., Lukachuk, M., Pöttgen, R., Szytuła, A., Kalychak, Y. M. Z. Naturforsch. 2015, 70b, 665–670. http://dx.doi.org/10.1515/znb-2015-0075.10.1515/znb-2015-0075Search in Google Scholar
3. Szytuła, A., Baran, S., Przewoźnik, J., Tyvanchuk, Y., Kalychak, Y. J. Magn. Magn. Mater. 2015, 387, 83–89. https://doi.org/10.1016/j.jmmm.2015.03.084.10.1016/j.jmmm.2015.03.084Search in Google Scholar
4. Kurleto, R., Starowicz, P., Goraus, J., Baran, S., Tyvanchuk, Y., Kalychak, Y.M., Szytuła, A. Solid State Commun 2015, 206, 46–50. http://dx.doi.org/10.1016/j.ssc.2015.01.014.10.1016/j.ssc.2015.01.014Search in Google Scholar
5. Kalychak, Ya. M., Zaremba, V. I., Pöttgen, R., Lukachuk, M., Hoffmann, R.-D. In Handbook on the Physics and Chemistry of Rare Earths; Gschneidner Jr, K. A., Pecharsky, V. K., Bünzli, J.-C. Eds.; Vol. 34, Elsevier: Amsterdam, 2005; p. 1. chapter 218. https://doi.org/10.1016/S0168-1273(04)34001-8.10.1016/S0168-1273(04)34001-8Search in Google Scholar
6. Villars, P., Cenzual, K., Gladyshevskii, R. Handbook of Inorganic Substances 2017; Walter de Gruyter: Berlin, 2017.10.1515/9783110445404Search in Google Scholar
7. Drašner, A., Blažina, Ž. J. Alloys Compd. 2006, 420, 213–217. http://dx.doi.org/10.1016/j.jallcom.2005.11.003.10.1016/j.jallcom.2005.11.003Search in Google Scholar
8. Drulis, H., Hackemer, A., Folcik, L., Giza, K., Bala, H., Gondek, Ł., Figiel, H. Int. J. Hydrogen Energy 2012, 37, 15850–15854. http://dx.doi.org/10.1016/j.ijhydene.2012.08.010.10.1016/j.ijhydene.2012.08.010Search in Google Scholar
9. Kalychak, Ya. M., Akselrud, L. G., Zaremba, V. I., Baranyak, V. M. Dopov. Akad. Nauk Ukr. RSR, Ser. B 1984, 3, 39–42.Search in Google Scholar
10. Bigun, I., Dzevenko, M., Havela, L., Kalychak, Y. Eur. J. Inorg. Chem. 2014, 2631–2642. http://dx.doi.org/10.1002/ejic.201400058.10.1002/ejic.201400058Search in Google Scholar
11. Sheldrick, G. M. Acta Crystallogr 2015, C71, 3–8. https://doi.org/10.1107/S2053229614024218.10.1107/S2053229614024218Search in Google Scholar PubMed PubMed Central
12. Spek, A. L. PLATON, A Multipurpose Crystallographic Tool; Utrecht University: Utrecht (The Netherlands), 2000.Search in Google Scholar
13. Emsley, J. The Elements, 2nd ed.; Clarendon Press: Oxford, 1991.Search in Google Scholar
14. Nowotny, H. Z. Metallkd. 1942, 34, 247–253.Search in Google Scholar
15. Joubert, J.-M., Černý, R., Latroche, M., Leroy, E., Guénée, L., Percheron-Guégan, A., Yvonw, K. J. Solid State Chem. 2002, 166, 1–6. https://doi.org/10.1006/jssc.2001.9499.10.1006/jssc.2001.9499Search in Google Scholar
16. Krypyakevich, P. I. Structure Types of the Intermetallic Compounds; Nauka: Мoscow, 1977.Search in Google Scholar
17. Sysa, L. V., Kalychak, Y. M., Galadzhun, Y. V., Zaremba, V. I., Akselrud, L. G., Skolozdra, R. V. J. Alloys Compd. 1998, 266, 17–21. https://doi.org/10.1016/S0925-8388(97)00500-8.10.1016/S0925-8388(97)00500-8Search in Google Scholar
18. Sysa, L. V., Kalychak, Ya. M. Neorg. Mater. 1994, 30, 779–782.Search in Google Scholar
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