Abstract
Tm3+/Yb3+ co-doped CaBi4Ti4O15 (CBT) bismuth layer structured ferroelectric ceramics were synthesized by a solid state reaction method and their microstructural and up-conversion (UC) luminescence properties were studied. Under 980-nm laser excitation, a strong blue light (475 nm) and a weaker red (650 nm) UC emission band were obtained, in which a three-photon UC mechanism is dominant, contributing to the transitions of 1G4 → 3H6, and 1G4 → 3F4. The optimal UC emission intensity was observed in the CBT: 0.005Tm3+/0.04Yb3+ samples. The transition 1G4 → (3H6, 3F4) of Tm3+ indicated a temperature-dependent behavior in the 163–503 K range. The maximum sensitivity was found to be 0.016 K−1 at 503 K based on the blue and red emissions. This indicates that CBT: 0.005Tm3+/0.04Yb3+ ferroelectric ceramics have great potential for applications in optical temperature sensors.
Similar content being viewed by others
References
Y. Zhao, X. Wang, Y. Zhang, Y. Li, and X. Yao, J. Alloys Compd. 770, 152691 (2020).
J.C. Boyer, F. Vetrone, J. Capobianco, A. Speghini, and M. Bettinelli, Chem. Phys. Lett. 390, 403 (2004).
J. Ikuta, K. Maeda, T. Sakai, T. Ikari, K. Koughia, M. Munzar, and S.O. Kasap, J. Mater. Sci. Mater. Electron. 18, S231 (2007).
D. Peng, X. Wang, C. Xu, X. Yao, J. Lin, and T. Sun, J. Appl. Phys. 111, 104111 (2012).
H. Zou, Y. Hu, X. Zhu, D. Peng, X. Chai, X. Wang, B. Liu, and D. Shen, J. Mater. Sci. Mater. Electron. 28, 11921 (2017).
D.C. Nguyen, G.E. Faulkner, and M. Dulick, Appl. Opt. 28, 3553 (1989).
Y. Miao, P. Wang, H. Guan, and Y. Chen, J. Mater. Sci. Mater. Electron. 26, 5748 (2015).
G. Ding, F. Gao, G. Wu, and D. Bao, J. Appl. Phys. 109, 123101 (2011).
Y. Gu, Y. Li, F. Zheng, and X. Wang, J. Mater. Sci. Mater. Electron. 28, 501 (2017).
X. Gong, Y. Li, Y. Zhang, and X. Wang, J. Mater. Sci. Mater. Electron. 29, 13286 (2018).
H. Zou, X. Yang, B. Chen, Y. Du, B. Ren, X. Sun, X. Wang, Q. Zhang, and F. Wang, Angew. Chem. Int. Ed. 58, 17255 (2019).
H.K. Yang, J.H. Oh, B.K. Moon, J.H. Jeong, and S.S. Yi, J. Ceram. Int. 40, 13357 (2014).
L. Xing, Y. Xu, R. Wang, W. Xu, S. Gu, and X. Wu, J. Chem. Phys. Lett. 577, 53 (2013).
W. Xu, J. Chen, P. Wang, Z. Zhang, and W. Cao, Opt. Lett. 37, 205 (2012).
A. Rosas Camacho, F. de Carrillo Romo, A. García Murillo, J. Oliva, and C.R. Garcia, Mater. Lett. 226, 34 (2018).
Y. Huang and L. Luo, J. Alloys Compd. 706, 312 (2017).
C. Diao, J. Xu, H. Zheng, L. Fang, Y. Gu, and W. Zhang, Ceram. Int. 39, 6991 (2013).
V.B. Santos, J.C. M’ Peko, M. Mir, V.R. Mastelaro, and A.C. Hemandes, J. Eur. Ceram. Soc. 29, 751 (2009).
Q. Cao Deng, P.H. Zou, J. Li, X. Wang, and X. Yao, J. Adv. Dielectr. 4, 450018 (2014).
S.A. Song, D.S. Kim, H.M. Jeong, and K.S. Lim, J. Lumin. 152, 75 (2014).
W.T. Carnall, G.L. Goodman, K. Rajnak, and R.S. Rana, J. Chem. Phys. 90, 3443 (1989).
Q. Han, H. Hao, J. Yang, Z. Sun, J. Sun, and Y. Song, J. Alloys Compd. 786, 770 (2019).
B. Dong, R.N. Hua, and B.S. Cao, et al., Phys. Chem. Chem. Phys. 16, 20009 (2014).
P. Du, L. Luo, Q. Yue, and W. Li, Mater. Lett. 143, 209 (2015).
S. Zheng, W. Chen, D. Tan, J. Zhou, Q. Guo, W. Jiang, C. Xu, X. Liu, and J. Qiu, Nanoscale 6, 5675 (2014).
K. Zheng, W. Song, G. He, Z. Yuan, and W. Qin, Optic. Express. 23, 7653 (2015).
Acknowledgments
This work was supported by the National Natural Science Foundation of China (Grant No. 51572195)
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Fu, T., Wang, X., Ye, H. et al. Up-conversion Luminescence and Temperature Sensing Properties of CaBi4Ti4O15:Tm3+, Yb3+ Ceramics. J. Electron. Mater. 49, 5047–5052 (2020). https://doi.org/10.1007/s11664-020-08239-y
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11664-020-08239-y