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Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with Boron Cluster Anions [M(solv)6][BnHn] (M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12)

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Abstract

Complex compounds [M(solv)6][BnHn], where M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12, have been synthesized and studied by physicochemical methods (IR spectroscopy, electronic absorption spectroscopy, and X-ray diffraction). The structures of complexes [Cd(DMF)6][B10H10] and [Zn(DMSO)6][B10H10] have been determined by X-ray diffraction. Based on the obtained data, methods for the synthesis of Zn(II) and Cd(II) coordination compounds with nitrogen-containing organic ligands in the presence of boron cluster anions [BnHn]2– (n = 10, 12) have been determined.

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Funding

This work was carried out as part of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research.

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Correspondence to S. E. Korolenko.

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Translated by V. Avdeeva

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Korolenko, S.E., Goeva, L.V., Kubasov, A.S. et al. Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with Boron Cluster Anions [M(solv)6][BnHn] (M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12). Russ. J. Inorg. Chem. 65, 846–853 (2020). https://doi.org/10.1134/S0036023620060091

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