Abstract
Complex compounds [M(solv)6][BnHn], where M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12, have been synthesized and studied by physicochemical methods (IR spectroscopy, electronic absorption spectroscopy, and X-ray diffraction). The structures of complexes [Cd(DMF)6][B10H10] and [Zn(DMSO)6][B10H10] have been determined by X-ray diffraction. Based on the obtained data, methods for the synthesis of Zn(II) and Cd(II) coordination compounds with nitrogen-containing organic ligands in the presence of boron cluster anions [BnHn]2– (n = 10, 12) have been determined.
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This work was carried out as part of the State Assignment of the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences in the field of fundamental research.
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Korolenko, S.E., Goeva, L.V., Kubasov, A.S. et al. Synthesis, Structures, and Properties of Zinc(II) and Cadmium(II) Complexes with Boron Cluster Anions [M(solv)6][BnHn] (M = Zn(II), Cd(II); solv = DMF, DMSO; n = 10, 12). Russ. J. Inorg. Chem. 65, 846–853 (2020). https://doi.org/10.1134/S0036023620060091
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DOI: https://doi.org/10.1134/S0036023620060091