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N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion

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Abstract

Methods for the preparation of N-substituted hydroxylamine [B12H11NH2OH]– have been developed and optimized. The possibility of using two synthetic methods has been shown: (i) based on the hydroxylation of the deprotonated amino-closo-dodecaborate and (ii) the ipso-substitution of the iodonium substituent with free hydroxylamine. A theoretical study of the [B12H11NH2OH]– anion has been carried out by quantum-chemical calculations in the framework of density functional theory in order to determine its main structural characteristics.

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ACKNOWLEDGMENTS

Equipment at the Shared Facilities Center of the Kurnakov Institute, functioning with the support of the State Assignment to the Kurnakov Institute in the field of fundamental research, was used.

Funding

This work was supported by the Russian Science Foundation (grant no. 18-13-00459).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    A. V. Nelyubin, N. A. Selivanov, A. Yu. Bykov, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin & N. T. Kuznetsov

  2. St. Petersburg State University, Institute of Chemistry, 199034, St. Petersburg, Russia

    A. S. Novikov

Authors
  1. A. V. Nelyubin
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  2. N. A. Selivanov
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  3. A. Yu. Bykov
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  4. I. N. Klyukin
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  5. A. S. Novikov
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  6. A. P. Zhdanov
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  7. K. Yu. Zhizhin
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  8. N. T. Kuznetsov
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Corresponding author

Correspondence to A. P. Zhdanov.

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Authors declare that they have no conflict of interest.

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Translated by V. Avdeeva

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Nelyubin, A.V., Selivanov, N.A., Bykov, A.Y. et al. N-Borylated Hydroxylamines [B12H11NH2OH]– as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion. Russ. J. Inorg. Chem. 65, 795–799 (2020). https://doi.org/10.1134/S0036023620060133

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