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Optical, thermal and nonlinear optical properties of amaranth dye-doped sulphamic acid single crystals

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Abstract

The optically transparent single crystals of pure and amaranth dye-doped (0.1 and 0.2 mol%) sulphamic acid (SA) are grown by slow evaporation solution technique. The unit cell parameters of the grown crystals were calculated by single-crystal X-ray diffraction. The various planes and its crystallinity were analysed by powder X-ray diffraction studies. The presence of amaranth dye molecules in the grown SA crystal lattice was confirmed by energy dispersive X-ray analysis. The optical quality of the crystal was analysed by ultraviolet–visible analysis and it reveals that the grown crystals have the good optical transmission in the whole visible region. No weight loss observed up to 212 °C, 214 °C (0.1 mol%) and 215 °C (0.2 mol%) for pure and amaranth dye-doped SA crystals, respectively. The increasing hardness and laser damage threshold properties of the crystals may be due to the incorporation of amaranth dye in the SA crystal lattices. Photoconductivity analysis shows that the pure and doped SA crystals possess negative photoconductive nature. The third-order nonlinear optical susceptibility values also increased as an effect of amaranth dopant.

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References

  1. S. Zongo, K. Sanusi, J. Britton, P. Mthunzi, T. Nyokung, M. Maaza, B. Sahraoui, Opt. Mater. 46, 270–275 (2015)

    CAS  Google Scholar 

  2. Y. Asakuma, Q. Li, H.M. Ang, M. Tade, K. Maeda, K. Fukui, Appl. Surf. Sci. 254, 4524 (2008)

    CAS  Google Scholar 

  3. K. Srinivasan, J. Arumugam, Opt. Mater. 30, 40–43 (2007)

    CAS  Google Scholar 

  4. C. Chen, Y. Wu, A. Jiang, B. Wu, G. You, R. Li, S. Li, J. Opt. Soc. Am. B 6, 616–621 (1989)

    CAS  Google Scholar 

  5. P.N. Prasad, D.J. Williams, Introduction to nonlinear optical effects in molecules and polymers, 1st edn. (Wiley, New York, 1991)

    Google Scholar 

  6. X. Zhang, M. Li, Z. Shi, Z. Cui, Mater. Lett. 65, 1404–1406 (2011)

    CAS  Google Scholar 

  7. G.D. Boyd, R.C. Miller, K. Nassau, W.L. Bond, A. Savage, Appl. Phys. Lett. 5, 234–236 (1964)

    CAS  Google Scholar 

  8. R. Ramesh Babu, K. Sethuraman, N. Vijayan, R. Gopalakrishnan, P. Ramasamy, Matter. Lett. 61, 3480–3485 (2007)

    Google Scholar 

  9. J. Arumugam, M. Selvapandiyan, S. Chandran, M. Srinivasan, P. Ramasamy, J. Mater. Sci. 31, 6084–6096 (2020)

    CAS  Google Scholar 

  10. T. Thaila, S. Kumararaman, Spectrachim. Acta A. 82, 20–24 (2011)

    CAS  Google Scholar 

  11. B. Singh, M. Shkir, S. AlFaify, A. Kaushal, N. Nasani, I. Bdikin, H. Shoukry, I.S. Yashia, H. Algarni, J. Mol. Struct. 1119, 365–372 (2016)

    CAS  Google Scholar 

  12. R.R. Babu, R. Ramesh, R. Gopalakrishnan, K. Ramamurthi, G. Bhagavannarayana, Spectrochim Acta Part A 76, 470–475 (2010)

    Google Scholar 

  13. B. Brahmaji, S. Rajyalakshmi, C.S. Kamal, V. Atla, V. Veeraiah, K.V. Rao, K.R. Rao, Opt. Mater. 64, 100–105 (2017)

    CAS  Google Scholar 

  14. K. Mahendra, N.K. Udayashankar, J. Modern, Phys B. 33, 2050002–2050012 (2020)

    Google Scholar 

  15. J. George, D. Sajan, J. Alex, A. Aravind, G. Vinitha, R. Chitra, Opt. Laser Technol. 105, 207–220 (2018)

    CAS  Google Scholar 

  16. S. Sonia, N. Vijayan, M. Vij, K. Thukral, N. Khan, D. Haranath, M.S.J. Rajnikant, Chin. J. Chem. Eng. 27, 701–708 (2019)

    CAS  Google Scholar 

  17. T.F. Kuech, E. Veuhoff, T.S. Kuan, V. Deline, R. Potemski, J. Cryst. Growth. 77, 257–271 (1986)

    CAS  Google Scholar 

  18. R.K. Choubey, S. Medhekar, R. Kumar, S. Mukherjee, Sunil Kumar. J. Mater. Sci. : Mater. Electron. 25, 1410–2141 (2014)

    CAS  Google Scholar 

  19. R. Ragu, P.S. Latha Mageshwari, M. Akilan, J.P. Angelena, S. Jerome Das, J. Mater. Sci. 30, 1670–1676 (2019)

    CAS  Google Scholar 

  20. N. Sinha, N. Goel, B.K. Singh, M.K. Gupta, B. Kumar, Solid State Chem. 190, 180–185 (2012)

    CAS  Google Scholar 

  21. R. Valluvan, K. Selvaraju, S. Kumararaman, Mater. Chem. Phys 97, 81–84 (2006)

    CAS  Google Scholar 

  22. V.T. Phan, T.T.V. Vo, K.D. Nguyen, T.T. Phuong Do, D.T. Nguyen, A.T. Quynh Le, D.T. Huynh, Opt. Mater. 105, 109894 (2020)

    CAS  Google Scholar 

  23. P.R. Deepthi, A. Sukhdev, P.M. Kumar, J. Shanthi, B.N. Pavithra, B.C. Hemaraju, Indian J. Phys. 93, 991–1000 (2019)

    CAS  Google Scholar 

  24. S. Samueia, F. Arjmandi Rad, Z. Rezvani, Appl. Clay. Sci. 184, 105388 (2020)

    Google Scholar 

  25. J.H. Joshi, K.P. Dixit, K.D. Parikh, H.O. Jethva, D.K. Kanchan, S. Kalainathan, M.J. Joshi, J. Mater. Sci. 29, 5837–5852 (2018)

    CAS  Google Scholar 

  26. M. Cheraghizade, F. Jamali-Sheini, R. Yousefi, Appl. Phys. A. 123, 390 (2017)

    Google Scholar 

  27. L. Xing, W. Yang, J. Lin, M. Huang, Y. Xue, Sci. Rep. 7, 14725 (2017)

    Google Scholar 

  28. S. Goel, N. Sinha, H. Yadav, A.J. Joseph, A. Hussain, B. Kumar, Arab. J. Chem. 13, 146–159 (2020)

    CAS  Google Scholar 

  29. J.H. Joshi, S. Kalainathan, D.K. Kanchan, M.J. Joshi, K.D. Parikh, Arab. J. Chem. 13, 1532–1550 (2020)

    CAS  Google Scholar 

  30. M. Lenin, N. Balamurugan, P. Ramasamy, Cryst. Res. Technol. 42, 39–43 (2007)

    CAS  Google Scholar 

  31. C. Senthilkumar, P. Rajesh, P. Ramasamy, Mater. Chem. Phys. 186, 365–371 (2017)

    Google Scholar 

  32. K. Kanagasabapathy, R. Rajasekaran, Optik 124, 4240–4245 (2013)

    CAS  Google Scholar 

  33. S. Bhandari, N. Sinha, G. Ray, A. Hussian, B. Kumar, Chem. Phys. Lett. 591, 10–15 (2014)

    CAS  Google Scholar 

  34. S. Goel, N. Sinha, H. Yadav, A. Hussain, B. Kumar, Mater. Res. Bull. 83, 77–87 (2016)

    CAS  Google Scholar 

  35. M. Anis, R.N. Shaikh, M.D. Shirsat, S.S. Hussaini, Opt. Laser Technol. 60, 124–129 (2014)

    Google Scholar 

  36. T. Prasanyaa, M. Haris, V. Mathivanan, M. Amgalan, V. Jayaramakrishnan, J. Therm. Anal. Calorim. 117, 285–291 (2014)

    CAS  Google Scholar 

  37. N. Sinha, K. Batra, S. Bhukkal, R. Kumar, S. Kumar, S. Goel, B. Kumar, Arab. J. Chem. 13, 5750–5764 (2020)

    CAS  Google Scholar 

  38. J.H. Joshi, S. Kalainathan, M.J. Joshi, K.D. Parikh, J. Mater. Sci. 30, 14243–14255 (2019)

    CAS  Google Scholar 

  39. J.H. Joshi, S. Kalainathan, D.K. Kanchan, M.J. Joshi, K.D. Parikh, J. Mater. Sci. 30, 2985–2993 (2019)

    CAS  Google Scholar 

  40. N. Sinha, S. Bhandari, H. Yadav, G. Ray, S. Godra, N. Tyagi, J. Dalal, S. Kumar, B. Kumar, Cryst. Eng. Commun. 17, 5757–5767 (2015)

    CAS  Google Scholar 

  41. C. Senthilkumar, P. Rajesh, P. Ramasamy, Mater. Res. Bull. 68, 210–215 (2015)

    Google Scholar 

  42. P. Kumaresan, S.M. Babu, P.M. Anbarasan, Mater. Res. Bull. 43, 1716–1723 (2008)

    CAS  Google Scholar 

  43. S. Goel, N. Sinha, A. Hussaini, A.J. Joseph, H. Yadav, B. Kumar, J. Mater. Sci. 29, 13449–13463 (2018)

    CAS  Google Scholar 

  44. N. Vijayan, G. Bhagavannarayana, R.R. Babu, R. Gopalakrishnan, K.K. Maurya, P. Ramasamy, Cryst. Growth Des. 6, 1542 (2006)

    CAS  Google Scholar 

  45. E.M. Onitsch, Uber die Mikroharte der Metalle Mikroscopia 2, 131 (1947)

    Google Scholar 

  46. C. Senthilkumar, P. Rajesh, P. Ramasamy, Opt. Mater. 73, 154–162 (2017)

    Google Scholar 

  47. S.K. Jat, N. Vijayan, A. Krishna, J. Philip, S. Verma, I. Bdikin, B. Singh, G. Bhagavannarayana, S.K. Halder, Cryst. Eng. Comm. 15, 10034–10042 (2013)

    CAS  Google Scholar 

  48. C. Ji, T. Chen, Z. Sun, Y. Ge, W. Lin, J. Luo, Q. Shi, M. Hong, Cryst Eng Commun 15, 2157–2162 (2013)

    CAS  Google Scholar 

  49. K. Senthil, S. Kalainathan, F. Hamada, M. Yamada, P.G. Aravindan, Opt. Mater. 46, 565–577 (2015)

    CAS  Google Scholar 

  50. T. Kubendiran, S.M. Ravi Kumar, S.E. AllenMoses, A. Nasareena Banu, C. Shanthi, S. Sivaraj, J. Mater. Sci. 30, 17559–17571 (2019)

    CAS  Google Scholar 

  51. S. Suresh, Lat. Am. J. Phys. Educ. 6, 547 (2012)

    Google Scholar 

  52. G. Rajasekar, M.K. Dhatchaiyini, G. Vinitha, A. Bhaskaran, J. Mol. Struct. 1177, 594–602 (2019)

    CAS  Google Scholar 

  53. J. Arumugam, M. Selvapandiyan, S. Chandran, M. Srinivasan, P. Ramasamy, Mater. Chem. Phys. 242, 122479 (2020)

    CAS  Google Scholar 

  54. M. Anis, D.A. Hakeem, G.G. Muley, Results Phys. 6, 645–650 (2016)

    Google Scholar 

  55. J. Arumugam, N. Suresh, M. Selvapandiyan, S. Sudhakar, M. Prasath, Heliyon. 5, e01988 (2019)

    CAS  Google Scholar 

  56. J.H. Joshi, S. Kalainathan, M.J. Joshi, K.D. Parikh, Arab. J. Chem. 13, 5018–5026 (2020)

    CAS  Google Scholar 

  57. I. Pritula, V. Gayvoronsky, Yu Gromov, M. Kopylovsky, M. Kolybaeva, V. Puzikov, A. Kosinova, Yu Savvin, Yu Velikhov, A. Levchenko, Opt. Commun. 282, 1141–1147 (2009)

    CAS  Google Scholar 

  58. R.N. Shaikh, M. Anis, M.D. Shirsat, S.S. Hussaini, Spectrochim. Acta A. 136, 1243–1248 (2015)

    CAS  Google Scholar 

  59. M. Anis, G.G. Muley, A. Hakeem, M.D. Shirsat, S.S. Hussaini, Opt. Mater. 46, 517–521 (2015)

    CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Periyar University PG Extension Centre, Tamil Nadu, Dharmapuri, 636 705, India

    Jemini Arumugam & M. Selvapandiyan

  2. Department of Physics, Sri Vidya Mandir Arts & Science College, Tamil Nadu, Uthangarai, 636 902, India

    Jemini Arumugam

  3. Department of Physics, Periyar University, Tamil Nadu, Salem, 636 011, India

    Jemini Arumugam

  4. Department of Physics, Govt. Arts and Science College, Tamil Nadu, Hosur, 635110, India

    Senthilkumar Chandran

  5. Department of Physics, SSN Engineering College, Crystal Growth Centre, Tamil Nadu, Kalavakkam, 603110, India

    M. Srinivasan, P. Ramasamy & P. Karuppasamy

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  1. Jemini Arumugam
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  2. M. Selvapandiyan
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  3. Senthilkumar Chandran
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  4. M. Srinivasan
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Correspondence to M. Selvapandiyan.

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Arumugam, J., Selvapandiyan, M., Chandran, S. et al. Optical, thermal and nonlinear optical properties of amaranth dye-doped sulphamic acid single crystals. J Mater Sci: Mater Electron 31, 13173–13185 (2020). https://doi.org/10.1007/s10854-020-03869-8

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