Abstract
The activity of polyvalent elements in the geochemical processes is to a considerable extent determined by the valence state. A change in the valence is dependent on many factors, but the redox conditions of the medium where magma is generated are considered the main factor. The ratio between divalent and trivalent iron in magmatic rocks is a reliable and an accessible indicator of the redox conditions that determine a whole set of mineralogical, geochemical and physical parameters including ferruginosity of dark-colored minerals, the ore mineral (magnetite–ilmenite) composition, the weight of the ore fraction, and magnetic susceptibility. Based on the above parameters, the zones are distinguished where magmatic rocks of the magnetite and ilmenite series are developed in the Sikhote Alin Orogenic Belt. All known tin and tungsten deposits and occurrences in the Sikhote Alin are confined to the ilmenite series (the axial zone of the belt). The ilmenite rock series are framed by the magmatic rocks of the magnetite series; the epithermal gold–silver and copper–porphyry deposits are associated with these rocks.
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REFERENCES
G. L. Amel’chenko, V. V. Golozubov, E. B. Volynets, and V. S. Markevich, “Stratigraphy of the Cretaceous Alchan cepicontinental basin, western Sikhote-Alin,” Tikhookean. Geol. 20 (1), 57–71 (2001).
Barsukov, V.L., The Main Features of Tin Geochemistry, (Nauka, Moscow, 1974).
A. A. Borisov, E. V. Zharkova, A. A. Kadik, I. F. Kravchuk, O. A. Lukanin, S. D. Malinin, and S. N. Shilobreeva, Fluids and Redox Equilibria in Magmatic Systems (Nauka, Moscow, 1991) [in Russian].
G. A. Valui and A. A. Strizhkova, Petrology of Shallow Granitoids with Reference to the Dal’negorsk District, Primorye (Dal’nauka, Vladivostok, 1997) [in Russian].
G. A. Valui, Petrology of Granitoids and Differentiation of Melts under Shallow Conditions (Eastern Sikhote Alin Volcanic Belt) (Dal’nauka, Vladivostok, 2014) [in Russian].
Geology of Tin Deposits of the USSR.Volume 1. Geological Principles of Prediction, Prospecting, and Assessment of Tin Deposits, Ed. by S. F. Lugov (Nedra, Moscow, 1986), p. 332 [in Russian].
V. V. Golozubov, Tectonics of the Jurassic and Lower Cretaceous Complexes of the Northwestern Facific Framing (Dal’nauka, Vladivostok, 2006) [in Russian].
V. G. Gonevchuk, V. O. Khudolozhkin, and G. A. Gonevchuk, “Redox conditions of the formation of ilmenite and magnetite-series granitoids in relation with problem of their ore potential,” Tikhookean. Geol., No. 1, 23–30 (1992).
V. G. Gonevchuk, A. I. Khanchuk, G. A. Gonevchuk, and V. A. Lebedev, “New K–Ar Biotite and amphibole ages of granitoids of Sikhote-Alin (Russian Far East): criteria of reliability and interpretation,” Russ. J. Pac. Geol. 9 (6), 411–427 (2015).
State Geological Map of the Russian Federaion. Map of Mineral Resources. 1 : 1 000 000. Far East Series. Sheets L-(52)53; K-52,53, Ed. by S. V. Kovalenko (Primorskaya PSE, FGBU VSEGEI, 2007).
Kadik, A.A. and Lukanin, O.A., Devolatilization of the Upper Mantle during Its Melting (Nauka, Moscow, 1986).
A. A. Kadik, “Mantle-derived reduced fluids: relationship to the chemical differentiation of planetary matter,” Geochem. Int. 41 (9), 844–855 (2003).
Map of Mineral Resources of the Khabarovsk Krai. 1 : 1 000 000. FGUGP, Ed. by A.F. Vas’kin and G.V. Roganov (FGUGGP Khabarovsk Geologiya, Kha-barovsk, 2004) [in Russian].
I. V. Kemkin, Geodynamic Evolution of the Sikhote Alin and Sea of Japan Region in the Mesozoic (Nauka, Moscow, 2006) [in Russian].
N. N. Kruk, V. I. Gvozdev, A. A. Orekhov, E. A. Krug, S. A. Kasatkin, V. V. Golozubov, S. N. Rudnev, Sh. Aoki, T. I. Komiya, V. P. Kovach, and P. A. Serov, “Early Cretaceous granitic and monzonitic rocks of the southern part of the Zhuravlevka Terrane (Sikhote-Alin): geochemical composition and melt sources,” Russ. J. Pac. Geol. 13 (3), 220–238 (2019).
R. G. Kulinich, Extended Abstract of Candidate’s Dissertation in Geology and Mineralogy (TOI DVNTs AN SSSR, Vladivostok, 1969).
T. V. Merkulova and L. F. Mishin, “Redox processes in the Mesozoic–Cenozoic volcanoplutonic systems and their role in the formation of regional gravity and magnetic anomalies of Far East,” Tikhookean. Geol. 34 (6), 112–124 (2015).
O. V. Minina, I. F. Migachev, and V. S. Zvezdov, “Prediction–metallogenic zoning of the southern Far East region for copper–porphyry mineralization,” Otechestvennaya Geol., No. 1, 35–49 (2019).
L. F. Mishin, N. P. Romanovskii, and V. G. Gurovich, “Two types of volcanoplutonic associations,” Dokl. Akad. Nauk SSSR 298 (5), 1186–1188 (1988).
L. F. Mishin and L. L. Petukhova, “Oxidation state of iron as indicator of metallogenic specialization of volcanoplutonic complexes by the example of the East USSR,” Tikhookean. Geol. 9 (3), 69–77 (1990).
L. F. Mishin and N. P. Romanovskii, “Redox settings of the formation and metallogenic specialization of the ore-magmatic systems of the southern Far East,” Tikhookean. Geol. 11 (6), 31–42 (1992).
L. F. Mishin, Felsic Subvolcanic Intrusions (Nauka, Moscow, 1994) [in Russian].
L. F. Mishin and N. V. Berdnikov, BIFs and their Ore Potential (Dal’nauka, Vladivostok, 2003) [in Russian].
L. F. Mishin, Ch. Chzhao, and A. I. Soldatov, “Mesozoic–Cenozoic volcanoplutonic belts and systems in the continental East Asia and their zoning,” Tikhookean. Geol. 22 (3), 28–47 (2003).
L. F. Mishin, G. L. Kirillova, T. G. Merkulova, and E. A. Konovalova, “Postcollision magmatism of western sector of the Mongol–Okhotsk Orogenic Belt: oxidation conditions and metallogenic zoning,” Russ. J. Pac. Geol. 13 (4), 311–319 (2019).
I. Ya. Nekrasov, Tin in Magmatic and Postmagmatic Processes (Nauka, Moscow, 1984) [in Russian].
A. V. Oleinikov, “Discussion on Paper by Likht F.R. “Geological conditions and stratigraphy of the Lower Cretaceous deposits of Southern Primorye,” Tikhookean. Geol. 13 (6), 55–67 (1994).
R. I. Petrachenko, BIFs, Propylites, and Mineralization in the Mesozoic and Cenozoic Volcanic Rocks of Primorye (Nauka, Novosibirsk, 1974) [in Russian].
D. M. Pecherskii, “Magnetic properties of granitoids of Northwastern USSR,” in Magnetic Properties of Igneous Rocks (Magadan, 1964), pp. 6–158 [in Russian].
A. V. Putintsev and S. I. Grigor’ev, “Composition of biotites from granites and petrogenetic typification of orogenic granitoid series,” Zap. Vseross. Mineral. O-va 122 (4), 18–34 (1993).
Yu. P. Razmakhnin and E. M. Razmakhnina, “Systematics, zoning, and metallogenic significance of metasomatites of the Sikhote-Alin tin belts of,” Geol. Rudn. Mestorozhd., No. 1, 126–144 (1973).
N. P. Romanovskii, “Magnetic susceptibility of ore-bearing granitoids of Primorye,” Geol. Rudn. Mestorozhd. 17 (5), 97–101 (1975).
N. P. Romanovskii and E. L. Reinlib, “On the mantle nature of decompaction zones of the near-Pacific orogenic systems,” Tikhookean. Geol. 3 (2), 87–89 (1984).
N. P. Romanovskii, Petrophysics of Granitoid Ore-Magmatic Systems of the Pacific Belt (Nauka, Moscow, 1987) [in Russian].
V. G. Sakhno, Late Mesozoic–Cenozoic Continental Volcanism of East Asia (Dal’nauka, Vladivostok, 2001) [in Russian].
G. R. Sayadan, V. G. Gonevchuk, N. S. Gerasimov, and V. G. Khomich, “Geological and isotope-geochemical substantiation of age and formation sequences of the magmatic rocks of the Krinichny gold field,” Mineralogical-Geochemical Indicators of Ore Potential and Petrogenesis (DVGI, Vladivostok, 1996), pp. 93–105 [in Russian].
V. A. Trunilina, S. P. Roev, and Yu. S. Orlov, Granitoids of Batholithic Belts of Northeastern Verkhoyansk–Kolyma Mesozoides (Yakutsk, 2013).
A. I. Khanchuk, V. V. Golozubov, V. P. Simanenko, and A. I. Malinovskii, “Giant folds with steeply dipping hinges in structures of orogenic belts: evidence from Sikhote Alin,” Dokl. Earth Sci. 394 (6), 791–795 (2004).
R. W. Douglas, P. Nath, and A. Paul, “Oxygen ion activity and its influence on the redox equilibrium in glasses,” Phys. Chem. Glasses 6 (6), 216–223 (1965).
G. Gastil, “The boundary between the magnetic-series and ilmenite-series granitic rocks in Peninsular California,” Recent Advances in Concepts Concerning Zoned Plutons in Japan and Southern and Baja California (Tokyo, 1990), pp. 91–100.
L. L. Lewis and J. L. Mair, “The Northern Cordilleran Mid-Cretaceous plutonic province: ilmenite/wagnetite-series granitoids and intrusion-related mineralization,” Res. Geol. 54 (3), 253–280 (2004).
A. V. Grebennikov, A. I. Khanchuk, V. G. Gonevchuk, and S. V. Kovalenko, “Cretaceous and Paleogene granitoid suites of the Sikhote-Alin area (Far East Russia): geochemistry and tectonic implications,” Lithos 261, 250–261 (2016).
S. Ishihara, “The magnetite-series and ilmenite-series granitic rocks,” Mining Geol., No. 27, 293–305 (1977).
A. I. Khanchuk, I. V. Kemkin, and N. N. Kruk, “The Sikhote-Alin Orogenic Belt, Russian Southeast: terranes and the formation of continental lithosphere based on geological and isotopic data,” J. Asian Earth Sci, 117–138 (2016).
H. R. Rollinson, Using Geochemical Data: Evaluation, Presentation, Interpretation (Group UK Ltd. Essex, London, 2013).
Kohei. Sato, “Sedimentary crust and metallogeny of granitoid affinity: implications from the geotectonic histories of the Circum-Japan Sea region, Central Andes and Southeastern Australia,” Res. Geol. 62 (4), 329–351 (2012).
Tectonic Map of the Central Asian–Pacific Belts Junction Area, Ed. by L. P. Karsakov and Zhao Chunjing, (ITIG FEB RAS, Khabarovsk, 2001).
M. D. Tucker, L. L. Barton, and B. M. Thomson, “Reduction and immobilization of molybdenum by desulfovibrio desulfuricans,” J. Environ. Qual., 1146–1152 (1997).
P. Zhao, B. Jahn, and B. Xu, “Elemental and Sr-Nd isotopic geochemistry of Cretaceous To Early Paleogene granites and volcanic rocks in the Sikhote-Alin Orogenic Belt (Russian Far East): implications for the regional tectonic evolution,” J. Asian Earth Sci. 146, 283–401 (2017).
ACKNOWLEDGMENTS
The authors express their gratitude to the Academician of the RAS A.I. Khanchuk (FEGI FEB RAS), V.G. Nevstruev, and the reviewers for their critical remarks, which significantly improved the quality of the manuscript.
Funding
The study was performed within the framework of the State Assignment for the Institute of Tectonics and Geophysics of the Far East Branch, Russian Academy of Sciences with partial support of the RFBR (project No. 16-05-00571/16) and partially within the framework of the studies on the State Assignment for “VSEGEI” (dated 30.12.2016 No. 049-00012-17-00), certified by the Federal Agency on nature management.
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Mishin, L., Konovalova, E., Taltykin, Y. et al. Redox conditions and related geochemical and metallogenic zonation of magmatic rocks of the Sikhote Alin Orogenic Belt. Russ. J. of Pac. Geol. 14, 241–256 (2020). https://doi.org/10.1134/S1819714020030057
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DOI: https://doi.org/10.1134/S1819714020030057