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Extracts of curcumin-incorporated hybrid sol–gel coatings for the corrosion mitigation of mild steel in 0.5 M HCl

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Abstract

Curcumin was extracted from turmeric using two solvents (ethanol and water), doped with hybrid (TEOS-APTES) sol–gel coatings for the corrosion protection of mild steel. Characterization of curcumin extracts was carried out using integral analyses, namely FTIR, NMR, DSC, TGA, total phenolic content, and antioxidant assay. Corrosion-inhibitive ability of coatings doped with curcumin extracts (25, 50, 75, and 100 ppm) were evaluated via electrochemical impedance spectroscopy and potentiodynamic polarization measurements. It was evident that sol–gel incorporated with 100 ppm ethanol extract provided more than 90% of inhibition efficiency. Coated mild steel surfaces were characterized using FTIR, SEM/EDX, and water contact angle analysis where coatings incorporated with curcumin extracts were found to be hydrophobic (θ = 100.2°).

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References

  1. Hussin, MH, Kassim, MJ, “The Corrosion Inhibition and Adsorption Behavior of Uncaria Gambir Extract on Mild Steel in 1 M HCl.” Mater. Chem. Phys., 125 (3) 461–468 (2011)

    CAS  Google Scholar 

  2. Al-Otaibi, MS, Al-Mayouf, AM, Khan, M, Mousa, AA, Al-Mazroa, SA, Alkhathlan, HZ, “Corrosion Inhibitory Action of Some Plant Extracts on the Corrosion of Mild Steel in Acidic Media.” Arab. J. Chem., 7 (3) 340–346 (2014)

    CAS  Google Scholar 

  3. Hamidon, TS, Hussin, MH, “Susceptibility of Hybrid Sol–Gel (TEOS-APTES) Doped with Caffeine as Potent Corrosion Protective Coatings for Mild Steel in 3.5 wt% NaCl.” Prog. Org. Coat., 140 105478 (2020)

    CAS  Google Scholar 

  4. Raja, PB, Sethuraman, MG, “Natural Products as Corrosion Inhibitor for Metals in Corrosive Media—A Review.” Mater. Lett., 62 (1) 113–116 (2008)

    CAS  Google Scholar 

  5. Asadi, N, Naderi, R, Saremi, M, Arman, SY, Fedel, M, Deflorian, F, “Study of Corrosion Protection of Mild Steel by Eco-Friendly Silane Sol–Gel Coating.” J. Sol–Gel. Sci. Technol., 70 (3) 329–338 (2014)

    CAS  Google Scholar 

  6. Jantaping, N, Schuh, CA, Boonyongmaneerat, Y, “Influences of Crystallographic Texture and Nanostructural Features on Corrosion Properties of Electrogalvanized and Chromate Conversion Coatings.” Surf. Coat. Technol., 329 120–130 (2017)

    CAS  Google Scholar 

  7. Jones, FN, Nichols, ME, Pappas, SP, Organic Coatings: Science and Technology. Wiley, Hoboken (2017)

    Google Scholar 

  8. Hamidon, TS, Qiang, TZ, Hussin, MH, “Anticorrosive Performance of AA6061 Aluminium Alloy Treated with Sol–Gel Coatings Doped with Mangrove Bark Tannins in 3.5 wt% NaCl.” Mater. Res. Express., 6 (9) 096417 (2019)

    CAS  Google Scholar 

  9. Vignesh, RB, Sethuraman, MG, “Corrosion Protection Behaviour of Sol–Gel Derived N,N-Dimethylthiourea Doped 3-Glycidoxypropyltrimethoxysilane on Aluminium.” Prog. Org. Coat., 77 (1) 136–141 (2014)

    CAS  Google Scholar 

  10. Wang, D, Bierwagen, GP, “Sol–Gel Coatings on Metals for Corrosion Protection.” Prog. Org. Coat., 64 (4) 327–338 (2009)

    CAS  Google Scholar 

  11. Suleiman, R, Khaled, M, Wang, H, Smith, TJ, Gittens, J, Akid, R, Mohamad El Ali, B, Khalil, A, “Comparison of Selected Inhibitor Doped Sol–Gel Coating Systems for Protection of Mild Steel.” Corros. Eng. Sci. Technol., 49 (3) 189–196 (2014)

    CAS  Google Scholar 

  12. Ostovari, A, Hoseinieh, SM, Peikari, M, Shadizadeh, SR, Hashemi, SJ, “Corrosion Inhibition of Mild Steel in 1 M HCl Solution by Henna Extract: A Comparative Study of the Inhibition by Henna and Its Constituents (Lawsone, Gallic Acid, α-d-Glucose and Tannic Acid).” Corros. Sci., 51 (9) 1935–1949 (2009)

    CAS  Google Scholar 

  13. Bouyanzer, A, Hammouti, B, Majidi, L, “Pennyroyal Oil from Mentha pulegium as Corrosion Inhibitor for Steel in 1 M HCl.” Mater. Lett., 60 (23) 2840–2843 (2006)

    CAS  Google Scholar 

  14. Johnsirani, V, Sathiyabama, J, Rajendran, S, Nagalakshmi, R, “Corrosion Inhibition by an Aqueous Extract of Curcumin Dye for Carbon Steel in Sea Water.” Eur. Chem. Bull., 2 (6) 401–406 (2013)

    CAS  Google Scholar 

  15. Bagchi, A, “Extraction of Curcumin.” IOSR J. Environ. Sci. Toxicol. Food Technol., 1 (3) 1–16 (2012)

    CAS  Google Scholar 

  16. Sae-Yun, A, Ovatlarnporn, C, Itharat, A, Wiwattanapatapee, R, “Extraction of Rotenone from Derris elliptica and Derris malaccensis by Pressurized Liquid Extraction Compared with Maceration.” J. Chromatogr. A, 1125 (2) 172–176 (2006)

    CAS  Google Scholar 

  17. Rajendran, S, Shanmugapriya, S, Rajalakshmi, T, Raj, AJA, “Corrosion Inhibition by an Aqueous Extract of Rhizome Powder.” Corrosion, 61 (7) 685–692 (2005)

    CAS  Google Scholar 

  18. Hussin, MH, Rahim, AA, Ibrahim, MNM, Perrin, D, Brosse, N, “Enhanced Properties of Oil Palm Fronds (OPF) Lignin Fractions Produced via Tangential Ultrafiltration Technique.” Ind. Crop. Prod., 66 1–10 (2015)

    CAS  Google Scholar 

  19. Wu, Y, Du, Z, Wang, H, Cheng, X, “Synthesis of Aqueous Highly Branched Silica Sol as Underlying Crosslinker for Corrosion Protection.” Prog. Org. Coat., 111 381–388 (2017)

    CAS  Google Scholar 

  20. Pourriahi, M, Nasr-Esfahani, M, Motalebi, A, “Effect of Henna and Rosemary Extracts on the Corrosion of 304L Stainless Steel in 3.5% NaCl Solution.” Surf. Eng. Appl. Elec., 50 (6) 525–533 (2014)

    Google Scholar 

  21. Abdulmajid, A, Hamidon, TS, Rahim, AA, Hussin, MH, “Tamarind Shell Tannin Extracts as Green Corrosion Inhibitors of Mild Steel in Hydrochloric Acid Medium.” Mater. Res. Express., 6 (10) 106579 (2019)

    CAS  Google Scholar 

  22. Hussin, MH, Kassim, MJ, Razali, NN, Dahon, NH, Nasshorudin, D, “The Effect of Tinospora crispa Extracts as a Natural Mild Steel Corrosion Inhibitor in 1 M HCl Solution.” Arab. J. Chem., 9 S616–S624 (2016)

    CAS  Google Scholar 

  23. Athira, GK, Jyothi, AN, “Preparation and Characterization of Curcumin Loaded Cassava Starch Nanoparticles with Improved Cellular Absorption.” Int. J. Pharm. Pharm. Sci., 6 (10) 171–176 (2014)

    CAS  Google Scholar 

  24. Haiyee, ZA, Saim, N, Said, M, Illias, RM, Mustapha, WAW, Hassan, O, “Characterization of Cyclodextrin Complexes with Turmeric Oleoresin.” Food Chem., 114 (2) 459–465 (2009)

    CAS  Google Scholar 

  25. Gören, AC, Çıkrıkçı, S, Çergel, M, Bilsel, G, “Rapid Quantitation of Curcumin in Turmeric via NMR and LC–Tandem Mass Spectrometry.” Food Chem., 113 (4) 1239–1242 (2009)

    Google Scholar 

  26. Anderson, AM, Mitchell, MS, Mohan, RS, “Isolation of Curcumin from Turmeric.” J. Chem. Educ., 77 (3) 359–360 (2000)

    CAS  Google Scholar 

  27. Payton, F, Sandusky, P, Alworth, WL, “NMR Study of the Solution Structure of Curcumin.” J. Nat. Prod., 70 (2) 143–146 (2007)

    CAS  Google Scholar 

  28. Yadav, D, Kumar, N, “Nanonization of Curcumin by Antisolvent Precipitation: Process Development, Characterization, Freeze Drying and Stability Performance.” Int. J. Pharm., 477 (1–2) 564–577 (2014)

    CAS  Google Scholar 

  29. Marcolino, VA, Zanin, GM, Durrant, LR, Benassi, MDT, Matioli, G, “Interaction of Curcumin and Bixin with β-Cyclodextrin: Complexation Methods, Stability, and Applications in Food.” J. Agric. Food Chem., 59 (7) 3348–3357 (2011)

    CAS  Google Scholar 

  30. Kassim, MJ, Hussin, MH, Achmad, A, Dahon, NH, Suan, TK, Hamdan, HS, “Determination of Total Phenol, Condensed Tannin and Flavonoid Contents and Antioxidant Activity of Uncaria gambir Extracts.” Indones. J. Pharm., 22 50–59 (2011)

    CAS  Google Scholar 

  31. Sahne, F, Mohammadi, M, Najafpour, GD, Moghadamnia, AA, “Extraction of Bioactive Compound Curcumin from Turmeric (Curcuma longa L.) via Different Routes: A Comparative Study.” Pak. J. Biotechnol, 13 (3) 173–180 (2016)

    Google Scholar 

  32. Péret-Almeida, L, Cherubino, APF, Alves, RJ, Dufossé, L, Glória, MBA, “Separation and Determination of the Physico-chemical Characteristics of Curcumin, Demethoxycurcumin and Bisdemethoxycurcumin.” Food Res. Int., 38 (8–9) 1039–1044 (2005)

    Google Scholar 

  33. Rozuli, NA, Hamidon, TS, Hussin, MH, “Evaluation of Piper sarmentosum Extract’s Corrosion Inhibitive Effects and Adsorption Characteristics for the Corrosion Protection of Mild Steel in 0.5 M HCl.” Mater. Res. Express., 6 (10) 106524 (2019)

    CAS  Google Scholar 

  34. Shahba, RMA, Fouda, AE-AE-S, El-Shenawy, AE-S, Osman, ASM, “Effect of Catharanthus roseus (Vince rosea) and Turmeric (Curcuma longa) Extracts as Green Corrosion Inhibitors for Mild Steel in 1 M HCl.” Mater. Sci. Appl., 7 (10) 654–671 (2016)

    CAS  Google Scholar 

  35. Al-Amiery, A, Kadhum, A, Mohamad, A, Musa, A, Li, C, “Electrochemical Study on Newly Synthesized Chlorocurcumin as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid.” Materials, 6 (12) 5466–5477 (2013)

    CAS  Google Scholar 

  36. Elmsellem, H, Youssouf, MH, Aouniti, A, Ben Hadda, T, Chetouani, A, Hammouti, B, “Adsorption and Inhibition Effect of Curcumin on Mild Steel Corrosion in Hydrochloric Acid.” Russ. J. Appl. Chem., 87 (6) 744–753 (2014)

    CAS  Google Scholar 

  37. Motalebi, A, Nasr-Esfahani, M, “Electrochemical and In Vitro Behavior of Nanostructure Sol–Gel Coated 316L Stainless Steel Incorporated with Rosemary Extract.” J. Mater. Eng. Perform., 22 (6) 1756–1764 (2013)

    CAS  Google Scholar 

  38. Khoshkhou, Z, Torkghashghaei, M, Baboukani, AR, “Corrosion Inhibition of Henna Extract on Carbon Steel with Hybrid Coating TMSM-PMMA in HCL Solution.” Open J. Synth. Theory Appl., 7 (1) 1–16 (2018)

    CAS  Google Scholar 

  39. Nasibi, M, Mohammady, M, Ashrafi, A, Khalaji, AAD, Moshrefifar, M, Rafiee, E, “Nanosized Scale Roughness and Corrosion Protection of Mild Steel in Hydrochloric Acid Solution and in the Presence of Turmeric (Curcuma longa) Extract as a Green Corrosion Inhibitor: FTIR, Polarization, EIS, SEM, EDS, AFM Studies, and Neural Network Modeling.” J. Adhes. Sci. Technol., 28 (20) 2001–2015 (2014)

    CAS  Google Scholar 

  40. Rajkumar, G, Sethuraman, MG, “Corrosion Protection Ability of Self-Assembled Monolayer of 3-Amino-5-mercapto-1,2,4-triazole on Copper Electrode.” Thin Solid Films, 562 32–36 (2014)

    CAS  Google Scholar 

  41. Zhang, S, Dong, D, Sui, Y, Liu, Z, Wang, H, Qian, Z, Su, W, “Preparation of Core Shell Particles Consisting of Cobalt Ferrite and Silica by Sol–Gel Process.” J. Alloys Compd., 415 (1–2) 257–260 (2006)

    CAS  Google Scholar 

  42. Sheffer, M, Groysman, A, Mandler, D, “Electrodeposition of Sol–Gel Films on Al for Corrosion Protection.” Corros. Sci., 45 (12) 2893–2904 (2003)

    CAS  Google Scholar 

  43. Zhang, D, Wang, L, Qian, H, Li, X, “Superhydrophobic Surfaces for Corrosion Protection: A Review of Recent Progresses and Future Directions.” J. Coat. Technol. Res., 13 (1) 11–29 (2016)

    Google Scholar 

  44. Obot, IB, Gasem, ZM, “Theoretical Evaluation of Corrosion Inhibition Performance of Some Pyrazine Derivatives.” Corros. Sci., 83 359–366 (2014)

    CAS  Google Scholar 

  45. Fu, J, Li, S, Wang, Y, Cao, L, Lu, L, “Computational and Electrochemical Studies of Some Amino Acid Compounds as Corrosion Inhibitors for Mild Steel in Hydrochloric Acid Solution.” J. Mater. Sci., 45 (22) 6255–6265 (2010)

    CAS  Google Scholar 

  46. Fu, J, Zang, H, Wang, Y, Li, S, Chen, T, Liu, X, “Experimental and Theoretical Study on the Inhibition Performances of Quinoxaline and Its Derivatives for the Corrosion of Mild Steel in Hydrochloric Acid.” Ind. Eng. Chem. Res., 51 (18) 6377–6386 (2012)

    CAS  Google Scholar 

  47. Yüce, AO, Mert, BD, Kardaş, G, Yazıcı, B, “Electrochemical and Quantum Chemical Studies of 2-Amino-4-methyl-thiazole as Corrosion Inhibitor for Mild Steel in HCl Solution.” Corros. Sci., 83 310–316 (2014)

    Google Scholar 

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Acknowledgments

The authors would like to acknowledge the financial support offered by Universiti Sains Malaysia Short Term Grant 304/PKIMIA/6315100. Tuan Sherwyn Hamidon desires to convey his appreciation to Universiti Sains Malaysia for offering the Graduate Assistant Scheme.

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Authors and Affiliations

  1. Materials Technology Research Group (MaTReC), School of Chemical Sciences, Universiti Sains Malaysia, 11800, Minden, Penang, Malaysia

    Nur ‘Amirah Ishak, Tuan Sherwyn Hamidon, Tan Zi-Hui & M. Hazwan Hussin

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  1. Nur ‘Amirah Ishak
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  2. Tuan Sherwyn Hamidon
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  3. Tan Zi-Hui
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  4. M. Hazwan Hussin
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Correspondence to M. Hazwan Hussin.

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Ishak, N.‘., Hamidon, T.S., Zi-Hui, T. et al. Extracts of curcumin-incorporated hybrid sol–gel coatings for the corrosion mitigation of mild steel in 0.5 M HCl. J Coat Technol Res 17, 1515–1535 (2020). https://doi.org/10.1007/s11998-020-00364-x

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