Abstract
This paper focuses on the study of different Roman mortars (renders, finishing coats), used in the construction and restoration of the Forum Traiani thermal baths (Central Sardinia, Italy), a significant example of the Roman-style architecture in Sardinia. The archaeological site is located in a high hydrogeological risk area, due to the cyclical flooding of nearby Tirso river. Moreover, the presence of thermal saline (NaCl-bearing) water spring directly in contact with mortars and building stones, also contributed to structure degradation. An analytical approach, comprising mineralogical-petrographic characterization, physical analysis and particle-size distribution of aggregate, was used for mortars characterization. In addition, pXRD analysis on mortars defined the presence of alteration minerals while the thermal characterization (TGA) gave information about binder hydraulicity degree. Further μ-XRD-associated μ-Raman spectroscopy and μ-FTIR were utilized for pigments identification on frescos. Interesting results came from two wall stratigraphic series of mortars, highlighting construction stages, ancient restoring interventions and waterproofing methods. The main pigments used on red, yellow and black frescoes were red ochre, goethite and wood charcoal respectively.
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References
Aliatis I, Bersani D, Campani E, Casoli A, Lottici PP, Mantovan S, Marino IG (2010) Pigments used in Roman wall paintings in the Vesuvian area. J Raman Spectrosc 41:1537–1542. https://doi.org/10.1002/jrs.2701
Angelini I, Asscher Y, Secco M, Parisatto M, Artioli G (2019) The pigments of the frigidarium in the Sarno Baths, Pompeii: identification, stratigraphy and weathering. J Cult Herit 40:309–316. https://doi.org/10.1016/j.culher.2019.04.021
Angiolillo S (1998) L’arte della Sardegna romana. Milano, Jaca Book
Antonelli F, Columbu S, De Vos RM, Andreoli M (2014) An archaeometric contribution to the study of ancient millstones from the Mulargia area (Sardinia, Italy) through new analytical data on volcanic raw material and archaeological items from Hellenistic and Roman North Africa. J Archaeol Sci 50:243–261
Argiolas S (2006) Caratterizzazione tecnologica e durevolezza di alcune piroclastiti Sarde: riflessi sui loro possibili impieghi in edilizia. Tesi di Dottorato di Ricerca in Ingegneria del Territorio, Università di Cagliari
Baraldi P, Baraldi C, Curina R, Tassi L, Zannini P (2007) A micro-Raman archaeometric approach to Roman wall paintings. Vib Spectrosc 43:420–426. https://doi.org/10.1016/j.vibspec.2006.04.029
Cagnana A (2000) Archeologia dei materiali da costruzione. SAP Società Archeologica S.r.l, Mantova
Cardoso I, Macedo MF, Vermeulen F, Corsi C, Santos Silva A, Rosado L, Candeias A, Mirao J (2014) A multidisciplinary approach to the study of archaeological mortars from the town of Ammaia in the Roman Province of Lusitania (Portugal). Archaeometry. 56:1–24. https://doi.org/10.1111/arcm.12020
Cennini C (1859) Il libro dell'arte. Le Monnier, Firenze
CNR–ICR (1980) Raccomandazione Nor.Ma.L 3/80: Materiali lapidei: campionamento, Rome
Columbu S (2017) Provenance and alteration of pyroclastic rocks from the Romanesque Churches of Logudoro (North Sardinia, Italy) using a petrographic and geochemical statistical approach. Appl Phys A Mater Sci Process. https://doi.org/10.1007/s00339-017-0790-z
Columbu S (2018) Petrographic and geochemical investigations on the volcanic rocks used in the Punic-Roman archaeological site of Nora (Sardinia, Italy). Environ Earth Sci 77. https://doi.org/10.1007/s12665-018-7744-4
Columbu S, Garau AM (2017) Mineralogical, petrographic and chemical analysis of geomaterials used in the mortars of Roman Nora theatre (South Sardinia, Italy). Ital J Geosci 136:238–262. https://doi.org/10.3301/IJG.2017.05
Columbu S, Sitzia F, Verdiani G (2015) Contribution of petrophysical analysis and 3D digital survey in the archaeometric investigations of the Emperor Hadrian’s Baths (Tivoli, Italy). Rend Lincei 26:455–474. https://doi.org/10.1007/s12210-015-0469-3
Columbu S, Sitzia F, Ennas G (2016) The ancient pozzolanic mortars and concretes of Heliocaminus baths in Hadrian’s Villa (Tivoli, Italy). Archaeol Anthropol Sci 9:523–553. https://doi.org/10.1007/s12520-016-0385-1
Columbu S, Lisci C, Sitzia F, Buccellato G (2017) Physical-mechanical consolidation and protection of Miocenic limestone used on Mediterranean historical monuments: the case study of Pietra Cantone (Southern Sardinia, Italy). Environ Earth Sci 76. https://doi.org/10.1007/s12665-017-6455-6
Columbu S, Lisci C, Sitzia F, Lorenzetti G, Lezzerini M, Pagnotta S, Raneri S, Legnaioli S, Palleschi V, Gallello G, Adembri B (2018a) Mineralogical, petrographic and physical-mechanical study of Roman construction materials from the Maritime Theatre of Hadrian’s Villa (Rome, Italy). Meas J Int Meas Confed 127:264–276. https://doi.org/10.1016/j.measurement.2018.05.103
Columbu S, Piras G, Sitzia F, Pagnotta S, Raneri S, Legnaioli S, Palleschi V, Lezzerini M, Giamello M (2018b) Petrographic and mineralogical characterization of volcanic rocks and surface-depositions on Romanesque monuments. Mediter Archaeol Archaeom. https://doi.org/10.5281/zenodo.1256051
Columbu S, Palomba M, Sitzia F, Murgia MR (2018c) Geochemical, mineral-petrographic and physical-mechanical characterization of stones and mortars from the Romanesque Saccargia Basilica (Sardinia, Italy) to define their origin and alteration. Ital J Geosci 137:369–695. https://doi.org/10.3301/IJG.2018.04
Columbu S, Antonelli F, Sitzia F (2018d) Origin of Roman worked stones from St. Saturno Christian Basilica (South Sardinia, Italy). Mediterranean Archaeology and Archaeometry. https://doi.org/10.5281/zenodo.1256047
Columbu S, Carboni S, Pagnotta S, Lezzerini M, Raneri S, Legnaioli S, Palleschi V, Usai A (2018e) Laser-induced breakdown spectroscopy analysis of the limestone Nuragic statues from Mont’e Prama site (Sardinia, Italy). Spectrochim Acta B At Spectrosc 149:62–70. https://doi.org/10.1016/j.sab.2018.07.011
Columbu S, Garau AM, Lugliè C (2019a) Geochemical characterisation of pozzolanic obsidian glasses used in the ancient mortars of Nora Roman theatre (Sardinia, Italy): provenance of raw materials and historical–archaeological implications. Archaeol Anthropol Sci 11:2121–2150. https://doi.org/10.1007/s12520-018-0658-y
Columbu S, Gioncada A, Lezzerini M, Sitzia F (2019b) Mineralogical-chemical alteration and origin of Ignimbritic stones used in the Old Cathedral of Nostra Signora di Castro (Sardinia, Italy). Stud Conserv 64:397–422. https://doi.org/10.1080/00393630.2018.1565016
Dettori B, Zanzari RA, Zuddas P (1982) Le acque termali della Sardegna. PFE Sottoprogetto Energia Geotermica. Relazione finale sul tema della ricerca: Studi geologici e geofisici finalizzati alla ricerca di fluidi caldi nel sottosuolo. Istituto di Geopedologia – Geologia applicata, Univeristà di Sassari
Franklin JA (1985) Suggested method for determining point load strength. Int J Rock Mech Min Sci 22:51–60. https://doi.org/10.1016/0148-9062(85)92327-7
Gutman M, Zanier K, Lux J, Kramar S (2016) Pigment analysis of roman wall paintings from two villae rusticae in Slovenia. Mediter Archaeol Archaeom. https://doi.org/10.5281/zenodo.160970
Il territorio in epoca romana
Jackson MD, Chae SR, Mulcahy SR, Meral C, Taylor R, Li P, Emwas AH, Moon J, Yoon S, Vola G, Wenk HR, Monteiro PJM (2013) Unlocking the secrets of Al-tobermorite in Roman seawater concrete. Am Mineral 98:1669–1687. https://doi.org/10.2138/am.2013.4484
Klein C (2004) Mineralogia. Zanichelli, Bologna
Krumbein WC (1941) Measurement and geological significance of shape and roundness of sedimentary particles. J Sediment Res 11(2):64–72
Lafuente B, Downs RT, Yang H, Stone N (2016) The power of databases: the RRUFF project. Highlights in Mineralogical Crystallography. https://doi.org/10.1515/9783110417104-003
Lezzerini M, Antonelli F, Columbu S, Gadducci R, Marradi A, Miriello D, Parodi L, Secchiari L, Lazzeri A (2016, 2014) Cultural heritage documentation and conservation: three-dimensional (3D) laser scanning and geographical information system (GIS) techniques for thematic mapping of facade stonework of St. Nicholas Church (Pisa, Italy). International Journal of Architectural Heritage. https://doi.org/10.1080/15583058.2014.924605
Lezzerini M, Raneri S, Pagnotta S, Columbu S, Gallello G (2018) Archaeometric study of mortars from the Pisa’s Cathedral Square (Italy). https://doi.org/10.1016/j.measurement.05.057
Mackenzie WS, Guilford C (1980) Atlas of rock-forming minerals in thin section. Mineral Mag
Mastino A (2005) La storia della Sardegna antica, Nuoro. Il Maestrale, Nuoro
Meloni P (1990) La provincia di Oristano, l'orma della storia. Pizzi, Milano
Miguel C, Lopes JA, Clarke M, Melo MJ (2012) Combining infrared spectroscopy with chemometric analysis for the characterization of proteinaceous binders in medieval paints. Chemom Intell Lab Syst 119:32–38. https://doi.org/10.1016/j.chemolab.2012.09.003
Miriello D, Antonelli F, Apollaro C, Bloise A, Bruno N, Catalano M, Columbu S, Crisci G. M, De Luca R, Lezzerini M, Mancuso S, La Marca A (2015) A petro-chemical study of ancient mortars from the archaeological site of Kyme (Turkey). Periodico di Mineralogia https://doi.org/10.2451/2015PM0028
Miriello D, Antonelli F, Bloise A, Ceci M, Columbu S, De Luca R, Lezzerini M, Pecci A, Mollo BS, Brocato P (2019) Archaeometric approach for studying architectural earthenwares from the archaeological site of St. Omobono (Rome-Italy) 9. https://doi.org/10.3390/min9050266
Moropoulou A, Bakolas A, Bisbikou K (1995) Characterization of ancient, byzantine and later historic mortars by thermal and X-ray diffraction techniques. Thermochim Acta 269-270:779–795. https://doi.org/10.1016/0040-6031(95)02571-5
Moropoulou A, Cakmak A, Labropoulos KC, Van Grieken R, Torfs K (2004) Accelerated microstructural evolution of a calcium-silicate-hydrate (C-S-H) phase in pozzolanic pastes using fine siliceous sources: comparison with historic pozzolanic mortars. Cem Concr Res 34:1–6. https://doi.org/10.1016/S0008-8846(03)00187-X
Moropoulou A, Bakolas A, Anagnostopoulou S (2005) Composite materials in ancient structures. Cem Concr Compos 27:295–300. https://doi.org/10.1016/j.cemconcomp.2004.02.018
Oliver RP, Cennini A, Val d’Elsa C, Thompson DV (2006) Il Libro dell’Arte. Italica. 11:114. https://doi.org/10.2307/476627
PAI (2006) Piano di assetto idrogeologico regione Sardegna. http://www.sardegnageoportale.it
Palmström A (1995) RMi – a rock mass characterization system for rock engineering purposes. Sci. York
Piovesan R, Siddall R, Mazzoli C, Nodari L (2011) The Temple of Venus (Pompeii): a study of the pigments and painting techniques. J Archaeol Sci 38:2633–2643. https://doi.org/10.1016/j.jas.2011.05.021
Piovesan R, Dalconi MC, Maritan L, Mazzoli C (2013) X-ray powder diffraction clustering and quantitative phase analysis on historic mortars. Eur J Mineral 25:165–175. https://doi.org/10.1127/0935-1221/2013/0025-2263
Pollione MV (n.d.15 BC) De Architecture. Vol. II. In: Cesariano C, De Architectura Libri Dece, 1521, Como
Quattrocchi L (2018) The tomb mosaic of Fl (avius) Rogatianus at Forum Traiani (Oristano, Sardinia). SAGVNTVM Papeles del Lab Arqueol Val 49:161. https://doi.org/10.7203/sagvntvm.49.9980
Ramacciotti M, Rubio S, Gallello G, Lezzerini M, Raneri S, Hernandez E, Calvo M, Columbu S, Morales A, Pastor A, De la Guardia M (2019) Chemical and mineralogical analyses on stones from Sagunto Castle (Spain). J Archaeol Sci Rep 24:931–938. https://doi.org/10.1016/j.jasrep.2019.03.017
Raneri S, Pagnotta S, Lezzerini M, Legnaioli S, Palleschi V, Columbu S, Neri NF, Mazzoleni P (2018) Examining the reactivity of volcanic ash in ancient mortars by using a micro-chemical approach. Mediter Archaeol Archaeom. https://doi.org/10.5281/zenodo.1285897
Saǧin EU, Böke H, Aras N, Yalçin Ş (2012) Determination of CaCO3 and SiO2 content in the binders of historic lime mortars. Mater Struct Constr 45:841–849. https://doi.org/10.1617/s11527-011-9802-1
Secco M, Dilaria S, Addis A, Bonetto J, Artioli G, Salvadori M (2018) The evolution of the Vitruvian recipes over 500 years of floor making techniques: the case studies of the Domus delle Bestie Ferite and the Domus di Tito Macro (Aquileia, Italy). Archaeometry. 60:185–206. https://doi.org/10.1111/arcm.12305
Secco M, Previato C, Addis A, Zago G, Kamsteeg A, Dilaria S, Canovaro C, Artioli G, Bonetto J (2019) Mineralogical clustering of the structural mortars from the Sarno Baths, Pompeii: a tool to interpret construction techniques and relative chronologies. J Cult Herit 40:265–273. https://doi.org/10.1016/j.culher.2019.04.016
Serra PB, Bacco P (1998) Forum Traiani: il contesto termale e l’indagine archeologica di scavo. L’Africa Romana 7:1213–1255
Serra PB, Bacco P (2014) Aquae Ypsitanae – Forum Traiani: Mostra archeologico grafica, fotografica. Soprintendenza per i beni archeologici delle provincie di Cagliari ed Oristano
Siedel H (2018) Salt efflorescence as indicator for sources of damaging salts on historic buildings and monuments: a statistical approach. Environ Earth Sci 77. https://doi.org/10.1007/s12665-018-7752-4
Sitzia F (2019) Decay monitoring and conservation of Sardinia monumental heritage through geochemical, petro-physical and micro-photogrammetric characterization of stone surfaces. PhD thesis in Earth and Environmental Sciences and Technologies. University of Cagliari
Verdiani G, Columbu S (2010) E. Stone, an archive for the Sardinia monumental witnesses. Lecture notes in computer science. https://doi.org/10.1007/978-3-642-16873-4_27
Vola G, Gotti E, Brandon C, Oleson JP, Hohlfelder RL (2011) Chemical, mineralogical and petrographic characterization of Roman ancient hydraulic concretes cores from Santa Liberata, Italy, and Caesarea Palestinae. Israel Period di Mineral. https://doi.org/10.2451/2011PM0023
Wentworth CK (1922) A scale of grade and class terms for clastic sediments. J Geol 30:377–392. https://doi.org/10.1086/622910
Wetmore MN, Vitruvius Morgan MH (2010) Vitruvius: the ten books on architecture. Class Wkly 9:116. https://doi.org/10.2307/4387224
Zucca R (1986) Fordongianus, Sassari
Zucca R (2004) Viaggio nell’archeologia della provincia di Oristano. E.P.T, Oristano, Oristano
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Fabio, S., Massimo, B., Stefano, C. et al. Ancient restoration and production technologies of Roman mortars from monuments placed in hydrogeological risk areas: a case study. Archaeol Anthropol Sci 12, 147 (2020). https://doi.org/10.1007/s12520-020-01080-8
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DOI: https://doi.org/10.1007/s12520-020-01080-8