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Influence of Precursor Concentration on the Formation of Silver Nanoparticles with Oligostyrylmonocarboxylate Ligands in ED-20 Epoxy Oligomer

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Abstract

Using transmission electron microscopy and UV–Vis spectroscopy, the effect of the concentration of the silver oligostyrylmonocarboxylate precursor in the range of 0.3–3.2 wt % in the reaction with the ED-20 epoxy resin on the formation of silver nanoparticles at a temperature of 75°C is studied. At the initial carboxylate concentration ≤0.3 wt %, silver nanoparticles with oligostyrylmonocarboxylate ligands having a spherical shape, small size, and narrow dispersion are produced. With an increase in the initial concentration of silver oligostyrylcarboxylate ≥0.3 wt %, the accumulation of nanoparticles is accompanied by the appearance of aggregates of arbitrary shape due to the van der Waals interaction of carboxylate ligands. The presence of aggregates leads to the broadening, splitting, and redshift of surface plasmon resonance peaks. Silver nanoparticles in aggregates are separated by ligand shells that reduce the probability of coalescence.

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ACKNOWLEDGMENTS

We are grateful to A.N. Grishchuk for the synthesis of the initial oligo(styrylcarboxylic acid), a precursor for the synthesis of OS–COOAg.

This study was carried out using the equipment of the Analytical Shared Research Center of the Institute of Problems of Chemical Physics, Russian Academy of Sciences.

Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-53-15016) and was performed within the framework of State Task no. 0089-2019-0012 (no. AAA-A19-119032690060-9).

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Authors and Affiliations

  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    L. I. Kuzub, L. L. Gurieva & E. R. Badamshina

  2. Institute of Microelectronics Technology and High-Purity Materials, Russian Academy of Sciences, 142432, Chernogolovka, Moscow oblast, Russia

    I. I. Khodos

Authors
  1. L. I. Kuzub
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  2. L. L. Gurieva
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  3. I. I. Khodos
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  4. E. R. Badamshina
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Correspondence to L. L. Gurieva.

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Kuzub, L.I., Gurieva, L.L., Khodos, I.I. et al. Influence of Precursor Concentration on the Formation of Silver Nanoparticles with Oligostyrylmonocarboxylate Ligands in ED-20 Epoxy Oligomer. Polym. Sci. Ser. B 62, 299–305 (2020). https://doi.org/10.1134/S1560090420030094

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  • DOI: https://doi.org/10.1134/S1560090420030094

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