Issue 9, 2020

Advances in design engineering and merits of electron transporting layers in perovskite solar cells

Abstract

The emerging photovoltaic technology, namely perovskite photovoltaics, follows a style to the blooming flower with superficial prosperity described by the ancient poet Yuxi Liu. Metal-halide perovskite has become one of the most promising photovoltaic materials for thin-film solar-cell applications, mainly due to its exellent visible light capture capability, large diffusion coefficients and long diffusion lengths of charge carriers (both electrons and holes). The reported power conversion efficiency of laboratory produced perovskite solar cells (PSCs) has exceeded 25%. However, this value was only achieved for devices of less than 0.1 cm2 dimensions, and decreases significantly with the increase in area (for example, down to 11.6% for a device area of ∼800 cm2, showing the issues with the scalability). In PSCs, the electron transport layer (ETL) has to perform two essential functions, which are related: (i) to collect and transfer charges after the injection of electrons from the perovskite light harvester; and (ii) to block the backflow of holes, thus realizing effective charge separation and suppressing charge carrier recombination. However, there are several critical issues associated with the ETLs which limit the further development of the PSCs. For example, the experimentally obtained open-circuit voltages in PSCs are typically much lower compared to the theoretical voltage limit with their optical bandgaps between 1.59 and 1.63 eV. This is mainly attributed to inefficient charge transport in the PSCs due to inhomogeneous charge accumulation and serious interfacial recombination at the interfaces between the ETL and the perovskite active layer. We scan recent developments of ETLs in PSCs, and discuss design methodologies, mechanisms, processing and characterization of new types of ETLs. High power conversion efficiency with large open-circuit voltages/photo-currents could be achieved through designing materials and microstructures for high-quality ETLs with a high electron mobility, high electrical conductivity and pinhole-free film morphology. It is crucial to balance the charge diffusion processes in the respective charge collective layers of PSCs as the interfaces between the ETLs and perovskites along with their interfacial structures play key roles in achieving new solid-state mesoscopic solar cells optimized open circuit voltages and output photocurrents.

Graphical abstract: Advances in design engineering and merits of electron transporting layers in perovskite solar cells

Article information

Article type
Review Article
Submitted
08 Apr 2020
Accepted
22 Jun 2020
First published
22 Jun 2020
This article is Open Access
Creative Commons BY-NC license

Mater. Horiz., 2020,7, 2276-2291

Advances in design engineering and merits of electron transporting layers in perovskite solar cells

H. Pan, X. Zhao, X. Gong, H. Li, N. H. Ladi, X. L. Zhang, W. Huang, S. Ahmad, L. Ding, Y. Shen, M. Wang and Y. Fu, Mater. Horiz., 2020, 7, 2276 DOI: 10.1039/D0MH00586J

This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. You can use material from this article in other publications, without requesting further permission from the RSC, provided that the correct acknowledgement is given and it is not used for commercial purposes.

To request permission to reproduce material from this article in a commercial publication, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party commercial publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements