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Crystal structures and magnetic properties of two isomorphic nickel(II) and cobalt(II) coordination polymers-based nitrogen-heterocyclic tricarbolylate ligands

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Abstract

5-(3,4-Dicarboxylphenyl) picolinic acid (H3dppa) was applied as a new building block for the synthesis of two isomorphic coordination polymers, namely [Ni1.5dppa(H2O)3]n·nH2O (1), [Co1.5dppa(H2O)3]n·nH2O (2). Two compounds were generated by a hydrothermal self-assembly method using the corresponding metal(II) acetates and H3cppa ligand. Structure analysis reveals that compounds 1 and 2 are isomorphic both featuring a two-dimensional wave structure and are finally extended into the three-dimensional supramolecular architecture though hydrogen bonding interactions. Magnetic susceptibility measurements indicate that domain a weak ferromagnetic exchange coupling between the adjacent Ni(II) centers in 1, and a weak antiferromagnetic coupling between Co(II) ions in for 2.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (no. 21671114).

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Correspondence to Yufang Wang or Liya Wang.

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Wang, Y., Li, S. & Wang, L. Crystal structures and magnetic properties of two isomorphic nickel(II) and cobalt(II) coordination polymers-based nitrogen-heterocyclic tricarbolylate ligands. Transit Met Chem 45, 561–568 (2020). https://doi.org/10.1007/s11243-020-00408-6

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  • DOI: https://doi.org/10.1007/s11243-020-00408-6

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