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Pressure-induced phase transition of 1,4-dioxane: From twisted-boat- to chair conformer

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Abstract

1,4-dioxane presents promising application in the field of organic synthesis. To discover the structural and phase information of 1,4-dioxane under pressure, in-situ high-pressure Raman measurement of 1,4-dioxane is carried out up to 15 GPa. At around 0.5 GPa, 1,4-dioxane undergoes a liquid–solid phase transition from liquid phase to a new high-pressure phase I. The evolution of Raman spectra in the region of 350–650 cm−1 suggests that 1,4-dioxane is transformed from twisted-boat conformer to chair conformer. When the pressure increases to about 8 GPa, 1,4-dioxane undergoes a solid–solid phase transition to another new high-pressure phase II. This study, for the first time, comprehensively analyzes the conformational transformation of 1,4-dioxane in the solid phase and provides a new experimental strategy to identify conformational isomers.

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Authors and Affiliations

  1. College of Physics, Jilin University, Changchun, 130012, P.R. China

    Yixin Chen, Aijun Li, Yue Zhao, Jingkai Bi, Mengying Zheng, Mi Zhou & Hongbo Wang

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  1. Yixin Chen
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  2. Aijun Li
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  3. Yue Zhao
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  4. Jingkai Bi
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  5. Mengying Zheng
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  6. Mi Zhou
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  7. Hongbo Wang
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Correspondence to Mi Zhou or Hongbo Wang.

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Chen, Y., Li, A., Zhao, Y. et al. Pressure-induced phase transition of 1,4-dioxane: From twisted-boat- to chair conformer. Eur. Phys. J. D 74, 121 (2020). https://doi.org/10.1140/epjd/e2020-100651-3

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