Short communicationLuminescent 3D homochiral coordination polymers of europium(III) and terbium(III) based on amino acid-functionalized isophthalic acid
Graphical abstract
The use of purely chiral fluorescent tricarboxylic ligand (S)-5-(((1-carboxy-2-phenylethyl)amino)methyl)isophthalic acid led to two luminescent novel 3D homochiral coordination polymers of europium(III) and terbium(III).
Section snippets
Declaration of Competing Interest
The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Acknowledgements
We gratefully acknowledge financial support from the National Natural Science Foundation of China (21271157), the Key Scientific Research Projects of Colleges and Universities in Henan Province (20A150007), and the Key R & D and Promotion Projects in Henan Province (202102210008).
References (42)
- et al.
A unique (4,12)-connected lanthanide metal-organic framework based on tetranuclear building blocks: topological analysis, fluorescence and magnetism properties
Inorg. Chem. Commun.
(2013) - et al.
Synthesis, crystallographic and spectral studies of homochiral cobalt(II) and nickel(II) complexes of a new terpyridylaminoacid ligand
J. Mol. Struct.
(2018) - et al.
A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties
Chem. Commun.
(2011) - et al.
1,4-Phenylenediacetate-based Ln MOFs–synthesis, structures, luminescence, and catalytic Activity
Eur. J. Inorg. Chem.
(2011) - et al.
Two polymeric 36-metal pure lanthanide nanosize clusters
Chem. Sci.
(2013) - et al.
Constraining and tuning the coordination geometry of a lanthanide ion in metal-organic frameworks: approach toward a single-molecule magnet
Inorg. Chem.
(2015) - et al.
A series of lanthanide-organic polymers incorporating nitrogen-heterocyclic and aliphatic carboxylate mixed-ligands: structures, luminescent and magnetic properties
Dalton Trans.
(2010) - et al.
Bin Zhao, 3d–4f Heterometal-organic frameworks for efficient capture and conversion of CO2
Cryst. Growth Des.
(2017) - et al.
Metal-organic frameworks as playgrounds for reticulate single-molecule magnets
Inorg. Chem.
(2019) - et al.
2D and 3D Lanthanide coordination polymers constructed from benzimidazole-5,6-dicarboxylic acid and sulfate bridged secondary building units
CrystEngComm
(2010)
Synthesis, crystal structure and magnetic characterization of a series of CuII–LnIII heterometallic [Ln = La, Ce, Pr, Nd and Sm) metal-organic compounds with an unusual single crystal to single crystal phase transition
Cryst. Growth Des.
A series of heterometallic three-dimensional frameworks constructed from imidazole-dicarboxylate: structures, luminescence, and magnetic properties
Cryst. Growth Des.
New lanthanide hybrid as clustered Infinite nanotunnel with 3D Ln–O–Ln framework and (3,4)-connected net
Inorg. Chem.
Luminescence modulation, white light emission, and energy transfer in a family of lanthanide metal-organic frameworks based on a planar π-conjugated ligand
Cryst. Growth Des.
Single component lanthanide hybrids based on metal-organic framework for near-ultraviolet white light LED
ACS Appl. Mater. Interfaces
Tunable luminescence and white light emission of mixed lanthanide-organic frameworks based on polycarboxylate ligands
J. Mater. Chem. C
Syntheses, structures, tunable emission and white light emitting Eu3+ and Tb3+ doped lanthanide metal-organic framework materials
Dalton Trans.
Highly anisotropic and water molecule-dependent proton conductivity in a 2D homochiral copper(II) metal-organic framework
Chem. Mater.
Homochiral metal-organic frameworks with tunable nanoscale channel array and their enantioseparation performance against chiral diols
Inorg. Chem.
Enantioselective catalysis with homochiral metal-organic frameworks
Chem. Soc. Rev.
Surface-mounted MOF templated fabrication of homochiral polymer thin film for enantioselective adsorption of drugs
Chem. Commun.
Cited by (7)
Formation of homochiral 3D frameworks using zinc (II) and rigid achiral ligands
2022, Inorganic Chemistry CommunicationsCitation Excerpt :Therefore, rational design and synthesis of HMOFs has become a hot spot in the past several years, and many spectacular HMOFs have been reported [6–8]. Several prime methodologies, including the usage of chiral ligand, asymmetrical inductive crystallization from achiral precursors in the presence of enantiopure reagents and post-synthetic modification of achiral frameworks with chiral blocks have been developed to construct HMOFs through year's efforts [9–13]. But all these methods involve enantiopure agents, which bring about some downsides such as high cost, limited avail ability and possibility of in situ ligand racemization[14–15].
3D Tb(III) and Eu(III) coordination polymers with mixed dicarboxylate ligands: Synthesis, structure and luminescence properties
2021, PolyhedronCitation Excerpt :Among these peaks, the emission at 546 nm (5D4→7F5) is the strongest, indicating intense green luminescence. It is worth noting that the greater “5D4→7F5 to 5D4→7F6” intensity ratio indicates that the Tb(III) ions located in low symmetric coordination environment have no inversion centre [54,55]. When the excitation wavelength is 300 nm, coordination polymer 2 exhibits three emission peaks at 593, 617, and 695 nm, assignable to 5D0→7Fj (j = 1, 2, 4) transitions of Eu(III) ion, respectively [7,41,56–58].
Three-dimensional homochiral coordination polymers of Eu(III) and Tb(III): Synthesis, structure determination, and optical properties
2020, Journal of Solid State ChemistryCitation Excerpt :Currently, more and more attention has been paid to homochiral metal-organic frameworks (HMOFs) due to their diverse structural topologies, unique chirality, and wide applications in asymmetric catalysis, chiral separation and recognition, nonlinear optics, and so on [18–31]. In contrast, the use of enantiopure aromatic polycarboxylate ligands to construct lanthanide-based homochiral metal-organic frameworks (Ln-HMOFs) as multicolor luminescent materials remains quite limited, although the incorporation of lanthanide ions and chiral ligands in Ln-HMOFs will be coupled with unique chiroptical properties, such as nonlinear optics, circular dichroism and chiral polarized photoemission, which could further expand their applications in optical materials [32–34]. Very recently, we have intentionally designed and synthesized purely chiral aromatic tricarboxylic ligands through using an effective strategy of binding natural chiral amino acids to 5-methyl-isophthalic acid, and reported a series of interesting transition-metal HMOFs containing those ligands [35,36].
Highly improved photoluminescence properties of novel ternary Eu(cpioa)phen metal-organic frameworks
2022, Functional Materials LettersA new two-dimensional homochiral cadmium(II) coordination polymer: synthesis, structure determination, optical properties, and fluorescent sensing
2022, Journal of Coordination Chemistry