Issue 15, 2020
From the journal:

Organic Chemistry Frontiers

Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters†

Xianli Shu,a   Ruting Xu,a   Qiang Maa  and  Saihu Liao ORCID logo *a  

* Corresponding authors

a Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University, Fuzhou 350108, China
E-mail: shliao@fzu.edu.cn

Abstract

A general and facile approach for the synthesis of alkyl boronic esters via visible light-mediated decarboxylative radical addition of redox-active esters to vinyl boronic ester is presented. The reaction features mild, metal-free reaction conditions and broad substrate scope covering primary, secondary, and tertiary acids, as well as amino acids and drugs.

Graphical abstract: Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

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Article information

DOI
https://doi.org/10.1039/D0QO00440E
Article type
Research Article
Submitted
13 Apr 2020
Accepted
13 Jun 2020
First published
17 Jun 2020

Org. Chem. Front., 2020,7, 2003-2007

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Accessing alkyl boronic esters via visible light-mediated decarboxylative addition reactions of redox-active esters

X. Shu, R. Xu, Q. Ma and S. Liao, Org. Chem. Front., 2020, 7, 2003 DOI: 10.1039/D0QO00440E

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