Abstract
The main goal of this study was the evaluation of physical–chemical, as well as radiological properties of residual materials used for geopolymer synthesis and those final products as a possible application as new materials in a civil engineering industry. Concentration of 40K and radionuclides from the 238U and 232Th decay series in waste precursors, their metaphases and geopolymer samples synthetized by alkali activation were determined together with corresponding absorbed dose rate (\(\dot{D}\)) and the annual effective dose rate. Natural activity concentrations in the alkali-activated material (geopolymer) were found to be lower than that of both residual materials and calcined ones.
Similar content being viewed by others
References
O’Brien RS, Cooper MB (1998) Technologically enhanced naturally occurring radioactive material (NORM): pathway analysis and radiological impact. Appl Radiat Isot 49:227–239
Ivanović M, Lj Kljajević, Nenadović M, Bundaleski N, Vukanac I, Todorović B, Nenadović S (2018) Physicochemical and radiological characterization of kaolin and its polzmerization products. Mater Construct 68:330
Beretka J, Mathew PJ (1985) Natural radioactivity of Australian building materials, industrial wastes and by-products. Health Phys 48:87–95
UNSCEAR (2000) Sources and effects of ionizing radiation—United Nations Scientific Committe on the effects of Atomic Radiation, UNSCEAR 2000 Report to the General Assembly with Scientific Annexes. United Nations, New York
Merdanoglu B, Altinsoy N (2006) Radioactivity concentration and dose assessment for soil samples from Kestanbol granite area. Turkey, Radiat Prot Dosim. 121:399–405
Nuccetelli C, Risica S (2008) Thorium series radionuclides in the environment: measurement, dose assessment and regulation. Appl Radiat Isot 66:1657–1660
Riise G (1990) A study of radionuclide association with soil components using a sequential extraction procedure. J Radioanal Nucl Chem 142:531–538
Schmidt U (2003) Enhancing phytoextraction: the effect of chemical soil manipulation on mobility, plant accumulation, and leaching of heavy metals. J Environ Qual 32:1939–1954
Nenadović S, Nenadović M, Lj Kljajević, Vukanac I, Poznanović M, Radosavljević AM, Pavlović V (2012) Vertical distribution of natural radionuclides in soil: assessment of external exposure of population in cultivated and undisturbed areas. Sci Total Environ 429:309–316
Cooper MB (2005) Naturally occurring radioactive materials (NORM) in Australian industries-review of current inventories and future generation. A Report prepared for the Radiation Health and Safety Advisory Council, Australia
International Commission on Radiological Protection (2006) Low-dose extrapolation of radiation- related cancer risk. Publication 99. Amsterdam, the Netherlands: Elsevier
Ramli AT, Wahab MA, Hussein A, Wood K (2005) Environmental 238U and 232Th concentration measurements in an area of high level natural background radiation at Palong, Johor. Malaysia. J Environ Radioact. 80:287–304
Mkandawire M, Taubert B, Gert Dudel G (2005) Resource manipulation in uranium and arsenic attenuation by Lemnagibba L. (duckweed) in tailing water of a former uranium mine. Water Air Soil Pollut 166:83–101
Directive 2013/59/EURATOM 5—December 2013, Official European Union 17/01/2014, 2013
Nenadović S, Lj Kljajević, Nešić M, Petković M, Trivunac K, Pavlović V (2017) Structure analysis of geopolymers synthesized from clay originated from Serbia. Environmen Earth Sci 76(2):76–79
Nenadovic SS, Nenadovic MT, Vukanac IS, Djordjevic AR, Dragicevic SS, Ljesevic MA (2010) Vertical distribution of 137 Cs in cultivated and undistrurbed areas. Nucl Technol Radioat Prot 25:30–36
Nenadovic SS, Musci G, LjM Kljajevic, Mirkovic MM, Nenadovic MT, Kristaly F, Vukanac IS (2017) Physicochemical, mineralogical and radiological properties of red mud samples as secondary raw materials. Nucl Technol Radioat Prot 32(3):261–266
Nenadovic S, Lj Kljajevic, Markovic S, Omerasevic M, Jovanovic U, Andric V, Vukanac I (2015) Natural diatomite (Rudovci, Serbia) as adsorbet for removal Cs from radioactive waste liquids. Sci Sinter 47(3):299–309
Davidovits J (2013) Geopolymer cement, a review, Institute Geopolymer
Davidovits J (2008) Geopolymer Chemistry and Applications, 2nd ed. 3rd ed. 2011, 4th ed. 2015, Geopolymer Institute, ISBN 4th ed. 9782951482098
Provis JL, van Deventer JSJ (eds) (2009) Geopolymers. Structure, processing, properties and industrial applications. Woodhead Publishing Limited
Messina F, Ferone C, Colangelo F, Roviello G, Cioffi R (2018) Alkali activated waste fly ash as sustainable composite: influence of curing and pozzolanic admixtures on the early-age physico-mechanical properties and residual strength after exposure at elevated temperature. Compos B 132:161–169
Messina F, Ferone C, Molino A, Roviello G, Colangelo F, Molino B, Cioffi R (2017) Synergistic recycling of calcined clay sediments and water potabilization sludge as geopolymer precursors: upscaling from binders to precast paving cement-free bricks. Constr Build Mater 133:14–26
Lirer S, Liguori B, Capasso I, Flora A, Caputo D (2017) Mechanical and chemical properties of composite materials made of dredged sediments in a fly-ash based geopolymer. J Environ Manage 191:1–7
International Crystallographical Database (ICDD). ICDD PDF-2/4 Release 2012. In: 12
IAEA (1989) Measurement of radionuclides in food and the environment, technical report Series No 295, Vienna, Austria
Tchakouté HK, Henning Rüscher C, Hinsch M, Yankwa Djobo JN, Kamseu E, Leonelli C (2017) Utilization of sodium waterglass from sugar cane bagasse ash as a new alternative hardener for producing metakaolin-based geopolymer cement. Geochemistry 77:257–266
Ferone C, Colangelo F, Messina F, Iucolano F, Liguori B, Cioffi R (2013) Coal combustion wastes reuse in low energy artificial aggregates manufacturing. Materials 6:5000–5015
Komnitsas K, Zaharaki D (2007) Geopolymerisation: a review and prospects for the minerals industry. Miner Eng 20:1261–1277
Ferone C, Capasso I, Bonati A, Roviello G, Montagnaro F, Santoro L, Turco R, Cioffi R (2019) Sustainable management of water potabilization sludge by means of geopolymers production. J Clean Product. 229:1–9
Vidmar T (2005) EFFTRAN—a monte carlo efficiency transfer code for gamma-ray spectrometry. Nucl Instrum Methods Phys Res Sect A 550:603–608
Villieras F, YvoN J, Cases JM, De Donato P, Lhote F, Baeza R (1994) Development of microporosity in clinochlore upon heating. Clays Clay Miner 42:679–688
Lj Kljajević, Melichova Z, Kisić D, Nenadović M, Todorović B, Pavlović V, Nenadović S (2018) The influence of alumino-silicate matrix composition on surface hydrophobic properties. Sci Sinter 5:163–173
Theo Kloprogge J, Komarneni S, Amonette JE (1999) Synthesis of smectite clay minerals: a critical review. Clays Clay Miner 47:529–554
Tyagi B, Chudasama CD, Jasra RV (2006) Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy. Spectrochim Acta, Part A 64A:273–278
Shahraki BK, Mehrabi B, Gholizadeh K, Mohammadinasab M (2011) Thermal behavior of calcite as expansive agent. J Min Metall. Sect B 47B(1):89–97
Taylor WR (1990) Proceedings of application of infrared spectroscopy to studies of silicate glass structure: examples from the melilite glasses and the systems Na2O–SiO2and Al2O3–SiO2. Indian Acad Sci. (Earth and Planetary Science) 99:99–117
Gervais F, Blin A, Massiot D, Coutures JP, Chopinet MH, Naudin F (1987) Infrared reflectivity spectroscopy of silicate glasses. J Non-Cryst Solids 89:384–401
Leonelli C, Romagnoli M (2011) Geopolimeri: polimeri inorganici chimicamente attivati, ed I.Cer.s., Bologna
Chen L, Wang Z, Wang Y, Feng J (2016) Preparation and properties of alkali activated metakaolin-based geopolymer. Materials 9:1–12
Acknowledgements
The research was funded by the Ministry of Education, Science and Technological Development of the Republic of Serbia.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The authors declare that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Nenadović, S.S., Ferone, C., Nenadović, M.T. et al. Chemical, physical and radiological evaluation of raw materials and geopolymers for building applications. J Radioanal Nucl Chem 325, 435–445 (2020). https://doi.org/10.1007/s10967-020-07250-1
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10967-020-07250-1