Skip to main content
SpringerLink
Log in

New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands

  • Published:
Russian Journal of Coordination Chemistry Aims and scope Submit manuscript

Abstract

Heating of a solution of [(Dpp-bian)GaH2] (I) (Dpp-bian = 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene) in pyridine leads to elimination of a hydrogen atom and reduction of the diimine ligand to dianion, resulting in the complex [(Dpp-bian)GaH(Py)] (II). The reaction of I with 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene (i-Pr2ImMe) is accompanied by a similar process, with the reaction product being identified as [(Dpp-bian)GaH(i-Pr2ImMe)] (III). Diamagnetic derivatives II and III were characterized by 1H NMR spectroscopy. The molecular structure of compound II was established by X-ray diffraction (CIF file CCDC no. 1973549).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.

Similar content being viewed by others

REFERENCES

  1. Downs, A.J. and Pulham, C.R., Chem. Soc. Rev., 1994, vol. 23, no. 3, p. 175.

    Article  CAS  Google Scholar 

  2. Jegier, J.A. and Gladfelter, W.L., Coord. Chem. Rev., 2000, vols. 206–207, p. 631.

    Article  Google Scholar 

  3. Aldridge, S. and Downs, A.J., Chem. Rev., 2001, vol. 101, no. 11, p. 3305.

    Article  CAS  PubMed  Google Scholar 

  4. Uhl, W., Coord. Chem. Rev., 2008, vol. 252, nos. 15–17, p. 1540.

    Article  CAS  Google Scholar 

  5. Luo, B. and Gladfelter, W.L., Chem. Commun., 2000, no. 10, p. 825.

  6. Luo, B., Young, V.G., and Gladfelter, W.L., Inorg. Chem., 2000, vol. 39, no. 8, p. 1705.

    Article  CAS  PubMed  Google Scholar 

  7. Cowley, A.R., Downs, A.J., Himmel, H.J., et al., Dalton Trans., 2005, no. 9, p. 1591.

  8. Luo, B., Kucera, B.E., and Gladfelter, W.L., Chem. Commun., 2005, no. 27, p. 3463.

  9. Schmidbaur, H., Findeiss, W., and Gast, E., Angew. Chem., Int. Ed. Engl., 1965, vol. 4, no. 2, p. 152.

    Google Scholar 

  10. Ohshita, J. and Schmidbaur, H., J. Organomet. Chem., 1993, vol. 453, no. 1, p. 7.

    Article  CAS  Google Scholar 

  11. Nogai, S. and Schmidbaur, H., Inorg. Chem., 2002, vol. 41, no. 18, p. 4770.

    Article  CAS  PubMed  Google Scholar 

  12. Eisch, J.J., J. Am. Chem. Soc., 1962, vol. 84, no. 20, p. 3830.

    Article  Google Scholar 

  13. Uhl, W., Cuypers, L., Graupner, R., et al., Z. Anorg. Allg. Chem., 2001, vol. 627, no. 4, p. 607.

    Article  CAS  Google Scholar 

  14. Uhl, W., Cuypers, L., Geiseler, G., et al., Z. Anorg. Allg. Chem., 2002, vol. 628, no. 5, p. 1001.

    Article  CAS  Google Scholar 

  15. Schmidbaur, H. and Klein, H.F., Angew. Chem., Int. Ed. Engl., 1966, vol. 5, no. 3, p. 312.

    Google Scholar 

  16. Schumann, H., Hartmann, U., and Wassermann, W., Polyhedron, 1990, vol. 9, nos. 2–3, p. 353.

    Article  CAS  Google Scholar 

  17. Takami, K., Mikami, S., Yorimitsu, H., et al., Org. Chem., 2003, vol. 68, no. 17, p. 6627.

    Article  CAS  Google Scholar 

  18. Uhl, W., Breher, W., Haddadpour, S., et al., Organometallics, 2005, vol. 24, no. 9, p. 2210.

    Article  CAS  Google Scholar 

  19. Uhl, W., Haddadpour, S., and Matar, M., Organometallics, 2006, vol. 25, no. 1, p. 159.

    Article  CAS  Google Scholar 

  20. Uhl, W., Bock, H.R., Breher, F., et al., Organometallics, 2007, vol. 26, no. 9, p. 2363.

    Article  CAS  Google Scholar 

  21. Uhl, W., Claesener, M., Haddadpour, S., et al., Dalton Trans., 2007, no. 4, p. 417.

  22. Uhl, W. and Claesener, M., Inorg. Chem., 2008, vol. 47, no. 11, p. 4463.

    Article  CAS  PubMed  Google Scholar 

  23. Uhl, W., Claesener, M., Haddadpour, S., et al., Z. Anorg. Allg. Chem., 2008, vol. 634, no. 15, p. 2889.

    Article  CAS  Google Scholar 

  24. Uhl, W. and Claesener, M., Inorg. Chem., 2008, vol. 47, no. 2, p. 729.

    Article  CAS  PubMed  Google Scholar 

  25. Uhl, W., Claesener, M., Hepp, A., et al., Dalton Trans., 2009, no. 47, p. 10550.

  26. Uhl, W., Hepp, A., Westenberg, H., et al., Organometallics, 2010, vol. 29, no. 6, p. 1406.

    Article  CAS  Google Scholar 

  27. Uhl, W., Claesener, M., Kovert, D., et al., Organometallics, 2011, vol. 30, no. 11, p. 3075.

    Article  CAS  Google Scholar 

  28. Uhl, W., Kovert, D., Zemke, S., et al., Organometallics, 2011, vol. 30, no. 17, p. 4736.

    Article  CAS  Google Scholar 

  29. Uhl, W., Layh, M., Rhotert, I., et al., Z. Naturforsch., 2013, vol. 68, nos. 5–6, p. 503.

    Article  CAS  Google Scholar 

  30. Schmidt, E.S., Jockisch, A., and Schmidbaur, H., Dalton Trans., 2000, no. 7, p. 1039.

  31. Cole, M.L., Jones, C., Junk, P.C., et al., Chem.-Eur. J., 2005, vol. 11, no. 15, p. 4482.

    Article  CAS  PubMed  Google Scholar 

  32. Jones, C., Mills, D.P., and Rose, R.P., J. Organomet. Chem., 2006, vol. 691, no. 13, p. 3060.

    Article  CAS  Google Scholar 

  33. Bonello, O., Jones, C., Stasch, A., et al., Organometallics, 2010, vol. 29, no. 21, p. 4914.

    Article  CAS  Google Scholar 

  34. Singh, S., Ahn, H.J., Stasch, A., et al., Inorg. Chem., 2006, vol. 45, no. 4, p. 1853.

    Article  CAS  PubMed  Google Scholar 

  35. Seifert, A., Scheid, D., Linti, G., et al., Chem.-Eur. J., 2009, vol. 15, no. 44, p. 12114.

    Article  CAS  PubMed  Google Scholar 

  36. Turner, J., Abdalla, J.A.B., Bates, J.I., et al., Chem. Sci., 2013, vol. 4, no. 11, p. 4245.

    Article  CAS  Google Scholar 

  37. Abdalla, J.A.B., Riddlestone, I.M., Tirfoin, R., et al., Angew. Chem., Int. Ed. Engl., 2015, vol. 54, no. 17, p. 5098.

    Article  CAS  Google Scholar 

  38. Herappe-Mejía, E., Trujillo-Hernández, K., Garduño-Jiménez, J., et al., Dalton Trans., 2015, no. 44, p. 16894.

  39. Fedushkin, I.L., Nikipelov, A.S., Lyssenko, K.A., et al., J. Am. Chem. Soc., 2010, vol. 132, no. 23, p. 7874.

    Article  CAS  PubMed  Google Scholar 

  40. Fedushkin, I.L., Moskalev, M.V., Lukoyanov, A.N., et al., Chem.-Eur. J., 2012, vol. 18, no. 36, p. 11264.

    Article  CAS  PubMed  Google Scholar 

  41. Fedushkin, I.L., Moskalev, M.V., Baranov, E.V., et al., J. Organomet. Chem., 2013, vol. 747, p. 235.

    Article  CAS  Google Scholar 

  42. Fedushkin, I.L., Skatova, A.A., Dodonov, V.A., et al., Inorg. Chem., 2014, vol. 53, no. 10, p. 5159.

    Article  CAS  PubMed  Google Scholar 

  43. Fedushkin, I.L., Nikipelov, A.S., Skatova, A.A., et al., Eur. J. Inorg. Chem., 2009, no. 25, p. 3742.

  44. Fedushkin, I.L., Kazarina, O.V., Lukoyanov, A.N., et al., Organometallics, 2015, vol. 34, no. 8, p. 1498.

    Article  CAS  Google Scholar 

  45. Moskalev, M.V., Lukoyanov, A.N., Baranov, E.V., et al., Dalton Trans., 2016, no. 40, p. 15872.

  46. Dodonov, V.A., Skatova, A.A., Cherkasov, A.V., et al., Russ. Chem. Bull.,Int. Ed., 2016, vol. 65, no. 5, p. 1171.

    CAS  Google Scholar 

  47. Fedushkin, I.L., Dodonov, V.A., Skatova, A.A., et al., Chem.-Eur. J., 2018, vol. 24, no. 8, p. 1877.

    Article  CAS  PubMed  Google Scholar 

  48. Fedushkin, I.L., Nikipelov, A.S., Morozov, A.G., et al., Chem.-Eur. J., 2012, vol. 18, no. 1, p. 255.

    Article  CAS  PubMed  Google Scholar 

  49. Sokolov, V.G., Koptseva, T.S., Moskalev, M.V., et al., Inorg. Chem., 2017, vol. 56, no. 21, p. 13401.

    Article  CAS  PubMed  Google Scholar 

  50. SAINT. Version 8.38A. Data Reduction and Correction Program, Madison: Bruker AXS, 2017.

  51. Sheldrick, G.M. SADABS. Version 2016/2. Bruker/Siemens Area Detector Absorption Correction Program, Madison: Bruker AXS, 2016.

    Google Scholar 

  52. Sheldrick, G.M., Acta Crystallogr., Sect. A:,Found. Adv., 2015, vol. 71, p. 3.

    Article  CAS  Google Scholar 

  53. Sheldrick, G.M., SHELXTL. Version 6.14. Structure Determination Software Suite, Madison: Bruker AXS, 2003.

    Google Scholar 

  54. Sokolov, V.G., Koptseva, T.S., Moskalev, M.V., et al., Russ. Chem. Bull.,Int. Ed., 2017, vol. 66, no. 9, p. 1569.

    CAS  Google Scholar 

  55. Sokolov, V.G., Koptseva, T.S., Dodonov, V.A., et al., Russ. Chem. Bull.,Int. Ed., 2018, vol. 67, no. 12, p. 2164.

    CAS  Google Scholar 

  56. Sokolov, V.G., Koptseva, T.S., Moskalev, M.V., et al., Russ. J. Coord. Chem., 2019, vol. 45, no. 9, p. 637. https://doi.org/10.1134/S1070328419090070

    Article  CAS  Google Scholar 

  57. Fedushkin, I.L., Lukoyanov, A.N., Tishkina, A.N., et al., Chem.-Eur. J., 2010, vol. 16, no. 25, p. 7563.

    Article  CAS  PubMed  Google Scholar 

  58. Fedushkin, I.L., Lukoyanov, A.N., Ketkov, S.Y., et al., Chem.-Eur. J., 2007, vol. 13, no. 25, p. 7050.

    Article  CAS  PubMed  Google Scholar 

  59. Sokolov, V.G., Koptseva, T.S., Rumyantcev, R.V., et al., Organometallics, 2020, vol. 39, no. 1, p. 66.

    Article  CAS  Google Scholar 

Download references

Funding

This work was carried out within the state assignment using the research equipment of the Center for Collective Use “Analytical Center of the of the Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences.”

Author information

Authors and Affiliations

  1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

    T. S. Koptseva, V. G. Sokolov, E. V. Baranov & I. L. Fedushkin

Authors
  1. T. S. Koptseva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. G. Sokolov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E. V. Baranov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. L. Fedushkin
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. S. Koptseva.

Ethics declarations

The authors declare that they have no conflicts of interest.

Additional information

The authors congratulate Academician I.L. Eremenko with a 70th birthday

Translated by Z. Svitanko

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Koptseva, T.S., Sokolov, V.G., Baranov, E.V. et al. New Gallium Hydrides with Dianionic Acenaphthene-1,2-Diimine Ligands. Russ J Coord Chem 46, 379–385 (2020). https://doi.org/10.1134/S1070328420060020

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S1070328420060020

Keywords:

Search

Navigation