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Zinc substituted Keggin-type polyoxometalate on Dowex: a green heterogeneous catalyst for oxidation of alcohols in water

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Abstract

In this work, homogeneous and heterogeneous oxidation of alcohols by H2O2 in the presence of [(n-C4H9)4 N]5[PW11ZnO39].3H2O and [PW11ZnO39]5− supported on Dowex 22 as catalysts have been investigated. Using water as a green solvent, different alcohols were converted into the corresponding aldehydes and ketones in high to excellent yields. Dowex 22 supported polyoxometalate, PW11Zn@Dowex, was also catalyzed highly robust and selective oxidation of unsaturated alcohols. Leaching and recycling experiments on supported catalyst revealed the excellent stability and reusability of this catalytic system.

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References

  1. S. Higashimoto, R. Shirai, Y. Osano, M. Azuma, H. Ohue, Y. Sakata, H. Kobayashi, J. Catal. 311, 137 (2014)

    Article  CAS  Google Scholar 

  2. L. Özcan, S. Yurdakal, V. Augugliaro, V. Loddo, S. Palmas, G. Palmisano, L. Palmisano, Appl. Catal. B 132–133, 535 (2013)

    Article  Google Scholar 

  3. R. Sheldon, I. Arends, A. Dijksman, Catal. Today 57, 157 (2000)

    Article  CAS  Google Scholar 

  4. H. Kargar, Transit. Met. Chem. 39, 811 (2014)

    Article  CAS  Google Scholar 

  5. H. Wang, W. Fan, Y. He, J. Wang, J.N. Kondo, T. Tatsumi, J. Catal. 299, 10 (2013)

    Article  CAS  Google Scholar 

  6. K. Kamata, K. Yonehara, Y. Sumida, K. Yamaguchi, S. Hikichi, N. Mizuno, Science 300, 964 (2003)

    Article  CAS  Google Scholar 

  7. J. Tan, X.B. Liu, W.F. Chen, Y.L. Hu, Chem. Select. 4, 8477 (2019)

    CAS  Google Scholar 

  8. I. Kozhevnikov, Catalysts for fine chemical synthesis, catalysis by polyoxometalates (Wiley, Hoboken, 2002)

    Google Scholar 

  9. R. Tan, C. Liu, N. Feng, J. Xiao, W. Zheng, A. Zheng, D. Yin, Micropor. Mesopor. Mater. 158, 77 (2012)

    Article  CAS  Google Scholar 

  10. T.J. Wilke, M.A. Barteau, J. Catal. 371, 357 (2019)

    Article  CAS  Google Scholar 

  11. V. Panchenko, I. Borbáth, M. Timofeeva, S. Gőbölös, J. Mol. Catal. A 319, 119 (2010)

    Article  CAS  Google Scholar 

  12. M.R. Farsani, B. Yadollahi, J. Mol. Catal. A Chem. 392, 8 (2014)

    Article  CAS  Google Scholar 

  13. B.J. Johnson, A. Stein, Inorg. Chem. 40, 801 (2001)

    Article  CAS  Google Scholar 

  14. W. Kaleta, K. Nowińska, Chem. Commun. 535 (2001).

  15. H.-L. Li, N. Perkas, Q.-L. Li, Y. Gofer, Y. Koltypin, A. Gedanken, Langmuir 19, 10409 (2003)

    Article  CAS  Google Scholar 

  16. X. Qu, Y. Guo, C. Hu, J. Mol. Catal. A 262, 128 (2007)

    Article  CAS  Google Scholar 

  17. C. Shi, R. Wang, G. Zhu, S. Qiu, J. Long, Eur. J. Inorg. Chem. 4801 (2005).

  18. P. Barbaro, Chem. Eur. J. 12, 5666 (2006)

    Article  CAS  Google Scholar 

  19. P. Barbaro, F. Liguori, Chem. Rev. 109, 515 (2008)

    Article  Google Scholar 

  20. T. J. R. Weakley, J. Chem. Soc. Dalton Trans. 341 (1973).

  21. I. Kozhevnikov, A. Sinnema, R. Jansen, K. Pamin, H. Van Bekkum, Catal. Lett. 30, 241 (1994)

    Article  CAS  Google Scholar 

  22. A. Kukovecz, Z. Balogi, Z. Konya, M. Toba, P. Lentz, S.-I. Niwa, F. Mizukami, A. Molnar, J. Nagy, I. Kiricsi, Appl. Catal. A 228, 83 (2002)

    Article  CAS  Google Scholar 

  23. M.R. Farsani, F. Jalilian, B. Yadollahi, H.A. Rudbari, Polyhedron 76, 102 (2014)

    Article  CAS  Google Scholar 

  24. E. Assady, B. Yadollahi, M.R. Farsani, M. Moghadam, Appl. Organomet. Chem. 29, 561 (2015)

    Article  CAS  Google Scholar 

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Acknowledgements

Support for this research by the University of Isfahan and Institute for Advanced Studies in Basic Sciences (IASBS) is acknowledged.

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Authors and Affiliations

  1. Institute for Advanced Studies in Basic Sciences (IASBS), Gavazang, 45195-1159, Zanjan, Iran

    Mehdi Aghayi

  2. Department of Chemistry, University of Isfahan, 81746-73441, Isfahan, Iran

    Bahram Yadollahi

  3. Department of Chemistry, Islamic Azad University, Shahrekord Branch, Shahrekord, Iran

    Mostafa Riahi Farsani

Authors
  1. Mehdi Aghayi
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  2. Bahram Yadollahi
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  3. Mostafa Riahi Farsani
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Correspondence to Bahram Yadollahi.

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Aghayi, M., Yadollahi, B. & Farsani, M.R. Zinc substituted Keggin-type polyoxometalate on Dowex: a green heterogeneous catalyst for oxidation of alcohols in water. J IRAN CHEM SOC 17, 2895–2900 (2020). https://doi.org/10.1007/s13738-020-01963-6

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  • DOI: https://doi.org/10.1007/s13738-020-01963-6

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