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A Kinetic Model for Chelating Extraction of Metals from Spent Hydrodesulphurization Catalyst by Complexing Agent

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Abstract

In this present paper, chelating extraction of metals from spent hydrodesulphurization catalyst was carried out using ethylene diamine tetraacetic acid as complexing agent. Mo, Ni and Co metals were precipitated in ammonium molybdate, nickel dimethylglyoxime and cobalt hydroxide forms at pH:2, pH:6 and pH:10, respectively. The highest metal extraction yields (90.22% Mo, 96.71% Co, 95.31% Ni and 19.98% Al) were achieved under optimum process conditions. The activation energy values (Ea) of Co, Mo and Ni were calculated as 14.36 kJ/mol, 16.85 kJ/mol and 15.93 kJ/mol, respectively. It was determined that leaching kinetics fitted to the pseudo-first homogenous model and the chelating process was controlled by diffusion mechanism. In the light of the kinetic data, the kinetic equation including the process parameters was obtained as follows: \(\ln \left( {1 - x} \right) = 1.217 \times 10^{ - 4} [(C_{A} )^{1.068} \left( D \right)^{ - 0.929} (K/S)^{ - 0.850} (R)^{0.185} \exp ( - 6462.6/T)] t\). The results provided a new approach both for reducing the solid waste load of the petrochemical industry and for efficient recovery of metals from the spent hydrodesulphurization catalyst using EDTA.

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Acknowledgements

This paper was produced from Orhon ALPASLAN’s master thesis.

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Authors and Affiliations

  1. Institute of Science and Technology, Bartin University, Bartin, 74100, Turkey

    Orhon Alpaslan

  2. Department of Metallurgy and Materials Engineering, Bartin University, Bartin, 74100, Turkey

    Ali Yaras

  3. Department of Chemical and Process Engineering, Ahi Evran University, Kırsehir, 40100, Turkey

    Hasan Arslanoğlu

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  1. Orhon Alpaslan
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  2. Ali Yaras
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Correspondence to Ali Yaras.

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Alpaslan, O., Yaras, A. & Arslanoğlu, H. A Kinetic Model for Chelating Extraction of Metals from Spent Hydrodesulphurization Catalyst by Complexing Agent. Trans Indian Inst Met 73, 1925–1937 (2020). https://doi.org/10.1007/s12666-020-02007-6

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