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Enthalpy of Formation of Erbium-Doped Bismuth Niobate

  • THERMODYNAMICS OF INORGANIC COMPOUNDS
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Abstract

The thermodynamic characteristics of bismuth niobate doped with erbium Bi3Nb0.2Er0.8O6.2 have been determined. This compound is a representative of a promising class of ionic conductors. The solution enthalpies of bismuth oxide, erbium oxide, niobium chloride, and Bi3Nb0.2Er0.8O6.2 have been measured in 4 M HCl using solution calorimetry. Based on the experimental and reported data, we have calculated the standard formation enthalpy ΔfH°(Bi3Nb0.2Er0.8O6.2, 298.15 K) = −1787.5 ± 8.9 kJ/mol and the lattice enthalpy ΔlatH°(Bi3Nb0.2Er0.8O6.2, 298.15 K) = −28 540 kJ/mol. The obtained thermodynamic characteristics can be used to develop recommendations for optimizing the synthesis of materials based on bismuth oxides.

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Funding

This work was supported by the Russian Science Foundation (project no. 19-19-00095).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Science, 630090, Novosibirsk, Russia

    N. I. Matskevich, A. N. Semerikova, N. V. Gelfond, M. Yu. Matskevich, E. N. Tkachev, O. I. Anufrieva & V. G. Martynetz

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  1. N. I. Matskevich
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  2. A. N. Semerikova
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  3. N. V. Gelfond
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  4. M. Yu. Matskevich
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  5. E. N. Tkachev
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  6. O. I. Anufrieva
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  7. V. G. Martynetz
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Correspondence to N. I. Matskevich.

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Translated by V. Avdeeva

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Matskevich, N.I., Semerikova, A.N., Gelfond, N.V. et al. Enthalpy of Formation of Erbium-Doped Bismuth Niobate. Russ. J. Inorg. Chem. 65, 743–746 (2020). https://doi.org/10.1134/S0036023620050162

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