Abstract
In this study, the continued investigation of a copper (II) complex that yields an extended hydrogen-bonded bilayer framework and it’s ability to include guest molecules, particularly pyridine molecules. Our previous study has shown the ability of this framework to include long-chanined alkyl alcohol molecules and now the copper-based framework has the ability to include pyridine molecules, via non-coordinative and coordinative inclusion. The description of three guest included hydrogen-bonded frameworks that will be discussed: (1) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(pyridine), (2) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(4-methylpyridine), (3) [α-methylbenzylammonium]2Cu(PDCA)2(H2O)·(4-tert-butylpyridine). The guest included frameworks will be discussed based on X-ray crystallography structures and thermogravimetric analysis data.
Graphic Abstract
The creation of a hydrogen-bonded metal-organic bilayer framework that allows for coordinative and non-coordinative guest inclusion of pyridine and pyridine derivatives.
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Acknowledgements
The authors will would like to express their sincere appreciation to Dr. Joseph Reibenspies from the Department of Chemistry at Texas A&M University for assistance with the x-ray crystallography and Dr. Tan Zhang from the Polymer Technology Center at Texas A&M University for assistance with the thermogravimetric analysis.
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Nguyen, H.H., Hogan, C.E. & Hogan, G.A. Guest Inclusion of Pyridine Molecules into a Copper (II)-Bilayer Hydrogen-Bonded Metal–Organic Framework. J Chem Crystallogr 51, 82–87 (2021). https://doi.org/10.1007/s10870-020-00838-1
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DOI: https://doi.org/10.1007/s10870-020-00838-1