Issue 14, 2020

Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

Abstract

Trifluoromethylthiolation-peroxidation of alkenes using AgSCF3 and tert-butyl hydroperoxide has been developed in the presence of a copper catalyst. The method exhibits a broad alkene scope with excellent regio- and chemo-selectivities, providing a variety of β-trifluoromethylthio peroxides from readily available materials. In addition, allenes can be applied to deliver the trifluoromethylthiolation-peroxidation products containing a vinyl-SCF3 moiety.

Graphical abstract: Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

Supplementary files

Article information

Article type
Research Article
Submitted
04 May 2020
Accepted
31 May 2020
First published
02 Jun 2020

Org. Chem. Front., 2020,7, 1837-1844

Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes

Y. Chen, Y. Ma, L. Li, M. Cui and Z. Li, Org. Chem. Front., 2020, 7, 1837 DOI: 10.1039/D0QO00533A

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