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Perfluorinated Proton-Conducting Membrane Composites with Functionalized Nanodiamonds

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Abstract

Composite proton-conducting membranes based on perfluorinated short side chain polymers modified with nanodiamonds having a hydrophilic surface owing to grafted carboxyl groups have been produced. Membrane films are prepared by precipitating the polymer from a dimethylformamide solution with introduced nanodiamonds. The proposed method for synthesizing the composites provides a high mechanical strength and an increase in the proton conductivity of the material with an increase in temperature in a 20–50°С range at rather low diamond concentrations (0.25–1 wt %). These features are important for using the composites in fuel cells at high temperatures.

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Funding

This work was supported by the Russian Foundation for Basic Research (project no. 19-03-00249).

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, 199004, St. Petersburg, Russia

    O. N. Primachenko, E. A. Marinenko, I. V. Gofman & S. S. Ivanchev

  2. Petersburg Nuclear Physics Institute named by B.P. Konstantinov of National Research Centre “Kurchatov Institute, 188300, Gatchina, Leningrad oblast, Russia

    Yu. V. Kulvelis, V. T. Lebedev & V. Yu. Bayramukov

  3. Russian Research Center of Applied Chemistry, 193232, St. Petersburg, Russia

    A. S. Odinokov

  4. Ioffe Institute, 194021, St. Petersburg, Russia

    A. V. Shvidchenko & A. Ya. Vul

Authors
  1. O. N. Primachenko
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  2. Yu. V. Kulvelis
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  3. V. T. Lebedev
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  4. A. S. Odinokov
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  5. V. Yu. Bayramukov
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  6. E. A. Marinenko
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  7. I. V. Gofman
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  8. A. V. Shvidchenko
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  9. A. Ya. Vul
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  10. S. S. Ivanchev
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Corresponding author

Correspondence to Yu. V. Kulvelis.

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Translated by M. Timoshinina

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Primachenko, O.N., Kulvelis, Y.V., Lebedev, V.T. et al. Perfluorinated Proton-Conducting Membrane Composites with Functionalized Nanodiamonds. Membr. Membr. Technol. 2, 1–9 (2020). https://doi.org/10.1134/S2517751620010060

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  • DOI: https://doi.org/10.1134/S2517751620010060

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