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Oligomerization of 1-Pentene on Zeolite Catalysts

  • CATALYSIS IN CHEMICAL AND PETROCHEMICAL INDUSTRY
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Abstract

The oligomerization of 1-pentene is an efficient process for producing environmentally friendly high-quality fuel components. The catalytic properties of FAU, OFF, MOR, BEA, MTW, and MFI zeolites in the H form are studied in the synthesis of pentene oligomers in an autoclave at 110–200°C. It is established that the high activity of H-Y and H-Beta(18) zeolites in the reaction of oligomerization, where the yield of oligomers reaches 97–100%, is determined by their wide-pore structure and high concentration of acid sites. The oligomers prepared on these catalysts are 30–73% dimers, 25–50% trimers, and 2–14% oligomers, with number n > 3 of monomer units. Narrow-pore zeolites (H-ZSM-5) or zeolites with one- and two-dimensional channel systems (H-OFF, H-MOR, and H-ZSM-12) are less active in the oligomerization of 1-pentene, with decenes as the main products of the reaction.

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Funding

This work was performed within state task no. AAAA-A19-119022290006-2, “Zeolite Materials of Different Structural Types with High Degrees of Crystallinity and Hierarchical Porous Structures: A New Generation of Catalysts for the Synthesis of Petrochemical Products of Practical Importance.” and supported by the RF Presidential Grant for Young Scientists and Graduate Students, project no. SP-2137.2018.1.

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, 450075, Ufa, Russia

    N. G. Grigor’eva, D. V. Serebrennikov, S. V. Bubennov & B. I. Kutepov

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  1. N. G. Grigor’eva
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  2. D. V. Serebrennikov
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  3. S. V. Bubennov
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  4. B. I. Kutepov
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Correspondence to N. G. Grigor’eva.

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Translated by O. Kadkin

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Grigor’eva, N.G., Serebrennikov, D.V., Bubennov, S.V. et al. Oligomerization of 1-Pentene on Zeolite Catalysts. Catal. Ind. 12, 47–55 (2020). https://doi.org/10.1134/S2070050420010079

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  • DOI: https://doi.org/10.1134/S2070050420010079

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