Skip to main content
SpringerLink
Log in

Morphological, Structural, and Catalytic Properties of Pd–CeO2/Al2O3 Compositions and Thereof Coatings in the Oxidation of Methane

  • CATALYSIS AND ENVIRONMENTAL PROTECTION
  • Published:
Catalysis in Industry Aims and scope Submit manuscript

Abstract

The morphological and structural properties of Pd–CeO2/Al2O3 catalytic compositions annealed at 100, 500, and 1000°С are studied, along with thereof coatings deposited on metallic foil via cold gas dynamic spraying. The influence of the preparation technique of the initial catalytic composition and introducing active component into a coating on their phase states, particle sizes, and activitites is elucidated. It is shown that introducing active components via impregnation into preliminarily sprayed alumina layer ensures the uniform distribution of Pd and Ce in the support profile, the formation of nanosized PdO particles, and the phase of interaction between the components of the catalyst and support. The impregnated catalyst shows the highest activity in the reaction of methane oxidation. The technique for preparing coatings has no limitations when scaled up and can find application in manufacturing full-size catalysts on metallic foil for different types of power engineering devices.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.
Fig. 8.
Fig. 9.

Similar content being viewed by others

REFERENCES

  1. Parmon, V.N., Ismagilov, Z.R., Favorskii, O.N., Belokon’, A.A., and Zakharov, V.M., Vestn. Ross. Akad. Nauk, 2007, vol. 77, no. 9, pp. 819–830.

    CAS  Google Scholar 

  2. Chen, J., Arandiyan, H., Gao, X., and Li, J., Catal. Surv. Asia, 2015, vol. 19, no. 3, pp. 140–171.

    Article  CAS  Google Scholar 

  3. Schwartz, W.R., Ciuparu, D., and Pfefferle, L.D., J. Phys. Chem. C, 2012, vol. 116, no. 15, pp. 8587–8593.

    Article  CAS  Google Scholar 

  4. Banerjee, A.C., McGuire, J.M., Lawnick, O., and Bozack, M.J., Catalysts, 2018, vol. 8, no. 7, p. 266.

    Article  Google Scholar 

  5. Dalla Betta, R.A. and Rostrup-Nielsen, T., Catal. Today, 1999, vol. 47, nos. 1–4, pp. 369–375.

  6. Choi, J.-S. and Kočí, P., Catalysts, 2016, vol. 6, no. 10, p. 155.

    Article  Google Scholar 

  7. Heck, R.M., Farrauto, R.J., and Gulati, S.T., Catalytic Air Pollution Control. Commercial Technology, Hoboken, NJ: Wiley, 2009.

    Book  Google Scholar 

  8. Ciuparu, D., Lyubovsky, M.R., Altman, E., Pfefferle, L.D., and Datye, A., Catal. Rev., 2003, vol. 44, no. 4, pp. 593–649.

    Article  Google Scholar 

  9. Vatcha, S.R., Energy Convers. Manage., 1997, vol. 38, nos. 10–13, pp. 1327–1334.

  10. Pfefferle, W.C., J. Energy, 1978, vol. 2, no. 3, pp. 142–146.

    Article  CAS  Google Scholar 

  11. Ismagilov, Z.R., Shikina, N.V., Yashnik, S.A., Zagoruiko, A.N., Kerzhentsev, M.A., Ushakov, V.A., Sazonov, V.A., Parmon, V.N., Zakharov, V.M., Braynin, B.I., and Favorskii, O.N., Catal. Today, 2010, vol. 155, nos. 1–2, pp. 35–44.

  12. Kuper, W.J., Blaauw, M., van der Berg, F., and Graaf, G.H., Catal. Today, 1999, vol. 47, nos. 1–4, pp. 377–389.

  13. Ismagilov, Z.R., React. Kinet. Catal. Lett., 1997, vol. 60, no. 2, pp. 215–218.

    Article  CAS  Google Scholar 

  14. Isupova, L.A., Sadykov, V.A., Tikhov, S.F., Kimkhai, O.N., Kovalenko, O.N., Kustova, G.N., Ovsyannikova, I.A., Dovbii, Z.A., Kryukova, G.N., Rozovskii, A.Ya., Tretyakov, V.F., and Lunin, V.V., Catal. Today, 1996, vol. 27, nos. 1–2, pp. 249–256.

  15. Matsumoto, S., Catal. Today, 2004, vol. 90, nos. 3–4, pp. 183–190.

  16. Ismagilov, Z.R., Yashnik, S.A., Matveev, A.A., Koptyug, I.V., and Moulijn, J.A., Catal. Today, 2005, vol. 105, nos. 3–4, pp. 484–491.

  17. Yashnik, S.A., Andrievskaya, I.P., Pashke, O.V., Ismagilov, Z.R., and Mulyain, Ya.A., Katal. Prom-sti, 2007, no. 1, pp. 35–46.

  18. Bal’zhinimaev, B.S., Suknev, A.P., Gulyaeva, Yu.K., and Kovalyov, E.V., Catal. Ind., 2015, vol. 7, no. 4, pp. 267–274.

    Article  Google Scholar 

  19. Pinaeva, L.G., Dovlitova, L.S., and Isupova, L.A., Kinet. Catal., 2017, vol. 58, no. 2, pp. 167–178.

    Article  CAS  Google Scholar 

  20. Qu, Z., Wang, Z., Quan, X., Wang, H., and Shu, Y., Chem. Eng. J., 2013, vol. 233, pp. 233–241.

    Article  CAS  Google Scholar 

  21. Zhu, A., Zhou, Y., Wang, Y., Zhu, Q., Liu, H., Zhang, Z., and Lu, H., J. Rare Earths, 2018, vol. 36, no. 12, pp. 1272–1277.

    Article  CAS  Google Scholar 

  22. Forzatti, P., Ballardini, D., and Sighicelli, L., Catal. Today, 1998, vol. 41, nos. 1–3, pp. 87–94.

  23. Pratt, A.S. and Cairns, J.A., Platinum Met. Rev., 1977, vol. 21, no. 3, pp. 74–83.

    CAS  Google Scholar 

  24. Smith, R.W. and Mutasim, Z.Z., J. Therm. Spray Technol., 1992, vol. 1, no. 1, pp. 57–63.

    Article  CAS  Google Scholar 

  25. Ismagilov, Z.R., Podyacheva, O.Yu., Solonenko, O.P., Pushkarev, V.V., Kuz’min, V.I., Ushakov, V.A., and Rudina, N.A., Catal. Today, 1999, vol. 51, nos. 3–4, pp. 411–417.

  26. US Patent 5 302 414, 1994.

  27. Shikina, N., Podyacheva, O., Kosarev, V., and Ismagilov, Z., Mater. Manuf. Processes, 2016, vol. 31, no. 11, pp. 1521–1526.

    Article  CAS  Google Scholar 

  28. Alkhimov, A.P., Kosarev, V.F., and Papyrin, A.N., Dokl. Akad. Nauk, 1990, vol. 315, no. 4, pp. 1062–1065.

    CAS  Google Scholar 

  29. Mayernick, A.D. and Janik, M.J., J. Catal., 2011, vol. 278, no. 1, pp. 16–25.

    Article  CAS  Google Scholar 

  30. Xiao, L-H., Sun, K-P., Xu, X.-L., and Li, X.-N., Catal. Commun., 2005, vol. 6, no. 12, pp. 796–801.

    Article  CAS  Google Scholar 

  31. Colussi, S., Gayen, A., Camellone, M.F., Boaro, M., Llorca, J., Fabris, S., and Trovarelli, A., Angew. Chem., Int. Ed. Engl., 2009, vol. 48, no. 45, pp. 8481–8484.

    Article  CAS  Google Scholar 

  32. Gulyaev, R.V., Kardash, T.Yu., Malykhin, S.E., Stonkus, O.A., Ivanova, A.S., and Boronin, A.I., Phys. Chem. Chem. Phys., 2014, vol. 16, no. 26, pp. 13523–13539.

    Article  CAS  Google Scholar 

  33. Wang, N., Li, S., Zong, Y., and Yao, Q., J. Aerosol Sci., 2017, vol. 105, pp. 64–72.

    Article  CAS  Google Scholar 

  34. Lei, Y., Li, W., Liu, Q., Lin, Q., Zheng, X., Huang, Q., Guan, S., Wang, X., Wang, C., and Li, F., Fuel, 2018, vol. 233, pp. 10–20.

    Article  CAS  Google Scholar 

  35. Tsud, N., Veltruská, K., and Matolín, V., Surf. Sci., 2002, vols. 507–510, pp. 808–812.

  36. Sun, K., Liu, J., Nag, N., and Browning, N.D., Catal. Lett., 2002, vol. 84, nos. 3–4, pp. 193–199.

Download references

ACKNOWLEDGMENTS

The authors thank V.F. Kosarev and V.V. Lavrushin at the Institute of Theoretical and Applied Mechanics SB RAS for performing cold gas spraying experiments.

Funding

This work was supported by the Russian Foundation for Basic Research, project no. 18-43-54 0015.

Author information

Authors and Affiliations

  1. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, 630090, Novosibirsk, Russia

    N. V. Shikina, O. Yu. Podyacheva, A. V. Ishchenko, S. R. Khairulin & Z. R. Ismagilov

  2. Institute of Coal Chemistry and Chemical Materials Science, Federal Science Center, Siberian Branch, Russian Academy of Sciences, 650000, Kemerovo, Russia

    N. V. Shikina, A. A. Moroz & Z. R. Ismagilov

  3. Kemerovo State University, 650000, Kemerovo, Russia

    T. B. Tkachenko

Authors
  1. N. V. Shikina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. O. Yu. Podyacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Ishchenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. S. R. Khairulin
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. T. B. Tkachenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. A. A. Moroz
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Z. R. Ismagilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to N. V. Shikina, O. Yu. Podyacheva, A. V. Ishchenko, S. R. Khairulin, T. B. Tkachenko, A. A. Moroz or Z. R. Ismagilov.

Additional information

Translated by A. Bannov

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shikina, N.V., Podyacheva, O.Y., Ishchenko, A.V. et al. Morphological, Structural, and Catalytic Properties of Pd–CeO2/Al2O3 Compositions and Thereof Coatings in the Oxidation of Methane. Catal. Ind. 11, 323–334 (2019). https://doi.org/10.1134/S2070050419040081

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S2070050419040081

Keywords:

Search

Navigation