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Synthesis and Structure of New Rare Earth Cadmium Tellurite Halides

  • SYNTHESIS AND PROPERTIES OF INORGANIC COMPOUNDS
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Abstract

Single crystals of novel rare earth–cadmium tellurite halides, [Ln12(TeO3)12][Cd6X24] (Ln = La, X = Cl (1); Ln = La, X= Br (2), and Ln = Pr, X = Br (3)), were obtained from melts. All three compounds are isostructural to layered tellurite halides [Ln12(TeO3)12][Cd6Cl24] (Ln = Sm, Eu), described earlier, and crystallize in space group P4/nbm with unit cell parameters a ~ 16 Å and c ~ 13 Å. Their crystal structures have been refined to Robs = 0.052, 0.047, and 0.049, respectively. Bromides adopting this structure have been synthesized for the first time. Crystal-chemical features and prospects for development are discussed for the family of rare earth chalcogenite halides containing [Ln11Mx(ChO3)12] rare earth–chalcogenite slabs.

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ACKNOWLEDGMENTS

We thank Dr. F.M. Spiridonov and Dr. V.Yu. Verchenko for the PXRD and EDX studies.

Funding

This study was supported by the Russian Foundation for Basic Research (project no. 17-03-01168).

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Authors and Affiliations

  1. Moscow State University, 119991, Moscow, Russia

    D. O. Charkin, V. Yu. Grishaev & V. A. Dolgikh

  2. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, 119034, St. Petersburg, Russia

    S. N. Volkov

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  1. D. O. Charkin
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  2. V. Yu. Grishaev
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  3. S. N. Volkov
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  4. V. A. Dolgikh
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Correspondence to D. O. Charkin.

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Charkin, D.O., Grishaev, V.Y., Volkov, S.N. et al. Synthesis and Structure of New Rare Earth Cadmium Tellurite Halides. Russ. J. Inorg. Chem. 65, 466–471 (2020). https://doi.org/10.1134/S0036023620040038

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