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Facile Synthesis of Fluorescence/Temperature Multisensitive Hybrid Hydrogels

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Abstract

Hybrid hydrogels based on poly(N-isopropylacrylamide) and poly(acrylamide) containing CdTe quantum dots with UV sensitive response and including NaYF4:Yb/Er nanoparticles have been prepared through glow discharge electrolysis plasma. The fluorescence characteristic and temperature sensitivity of the prepared hydrogels have been most extensively studied. In addition, scanning electron microscopy, X-ray diffraction, differential scanning calorimetry were determined to characterize the morphology, degree of crystallinity and the phase transformations of the hydrogels. The results suggested that the phase transition temperature of the hydrogels was 32.5°C and the hydrogels had good up-conversion and down-conversion fluorescence properties. Moreover, hybrid hydrogels had a reversible temperature response performance.

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Funding

We gratefully acknowledge the financial support from the following sources: National Natural Science Foundation of China (NSFC) (Grants 51607054), Young Talent of Hebei Province (nos. 70280011808, 70280016160250), Hebei Province Outstanding Youth Fund (A2018201019, A2017201082), Hebei Province Natural Science Fund (A2015201050).

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Authors and Affiliations

  1. College of Chemistry and Environmental Science, Hebei University, 071000, Baoding, China

    Wenshan Gao

  2. College of Physics Science and Technology, Hebei University, 071002, Baoding, China

    Yu Zhang, Xinyu Zhang, Siqi Gu, Xiaojun Zhang & Wenming Zhang

  3. Department of Digestive Medicine, Affiliated Hospital of Hebei University, 071000, Baoding, China

    Jie Meng

  4. Department of Breast Surgery, Affiliated Hospital of Hebei University, 071000, Baoding, China

    Lvzhu Li

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  1. Wenshan Gao
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  2. Yu Zhang
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Correspondence to Jie Meng, Lvzhu Li, Xiaojun Zhang or Wenming Zhang.

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Wenshan Gao, Zhang, Y., Zhang, X. et al. Facile Synthesis of Fluorescence/Temperature Multisensitive Hybrid Hydrogels. Polym. Sci. Ser. A 62, 240–248 (2020). https://doi.org/10.1134/S0965545X20030074

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  • DOI: https://doi.org/10.1134/S0965545X20030074

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