Skip to main content
Log in

Effect of Doping of Plant Raw-Based Activated Carbons with Iron Nanoparticles on Their Catalytic Activity in the Reaction of Propane Dehydrogenation

  • Published:
Petroleum Chemistry Aims and scope Submit manuscript

Abstract

A method is developed for creating highly active and selective catalysts for associated petroleum gas cracking which is based on use of activated carbons derived from renewable sources of plant raw materials (Jerusalem artichoke, false flax, rape, wheat) modified with nanosized iron particles obtained in reverse-micellar solutions. It is shown that carbon matrices modified with iron nanoparticles possess а high catalytic activity with the maximum conversion attained at 900 К and a high selectivity for olefin formation (about 95%).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. S. N. Khadzhiev, Pet. Chem. 56 (6), 465 (2016). https://doi.org/10.1134/S2414215816010056

    Article  CAS  Google Scholar 

  2. A. A. Revina, N. L. Voropaeva, V. M. Mukhin, S. A. Busev, D. Chekmar’, and V. V. Karpachev, Abstracts of Papers, I International Scientific and Practical Conference on Graphene and Related Structures: Synthesis, Production, and Application (Tambov, 2015), pp. 164–165 [in Russian].

  3. D. V. Chekmar’, D. A. Tanasyuk, N. L. Voropaeva, and A. A. Revina, in Proceedings of II All-Union Conference with International Participation and Symposium on Topical Problems of the Theory of Adsorption, Porosity, and Adsorption Selectivity (Klyaz’ma, Moscow, 2015), p. 62 [in Russian].

  4. N. L. Voropaeva, V. M. Mukhin, A. A. Revina, C. A. Busev, and V. V. Karpachev, GeoScience Eng. LXI (3), 247 (2015).

    Google Scholar 

  5. Y. S. Pavlov, A. A. Revina, O. V. Souvorova, N. L. Voropaeva, D. V. Chekmar, E. V. Abkhalimov, M. A. Zavyalov, and V. P. Filippovich, J. Phys.: Conf. Ser. 941 (2017). https://doi.org/10.1088/1742-6596/941/1/012098

    Google Scholar 

  6. A. A. Revina, RF Patent No. 2 322 327, Byull. Izobret., 2008, no. 11.

  7. E. A. Yagol’nik, B. B. Makhmutov, Yu. S. Tarakhovskii, E. N. Muzafarov, O. M. Alekseeva, and Yu. A. Kim, Izv. Tul’sk. Gos. Univ., Est. Nauki, No. 2, 289 (2010).

    Google Scholar 

  8. A. A. Revina, O. V. Suvorova, Yu. S. Pavlov, and D. L. Tytik, Prot. Met. Phys. Chem. Surf. 55 (5), 531 (2019). https://doi.org/10.1134/S0044185619040168

    Article  Google Scholar 

  9. E. M. Egorova, A. A. Revina, T. P. Rostovshchikova, and O. I. Kiseleva, Vest. Mosk. Univ., Ser. 2: Khim. 42 (5), 332 (2001).

    CAS  Google Scholar 

  10. A. A. Revina, L. D. Belyakova, S. A. Parkaeva, O. V. Suvorova, M. O. Sergeev, and V. I. Zolotarevskii, Port. Met. Phys. Chem. Surf. 46 (6), 578 (2010).

    Article  Google Scholar 

  11. A. Tomita, T. Miki, and Yu. Tai, Appl. Catal., A 522, 138 (2016).https://doi.org/10.1016/j.apcata.2016.04.033

    Article  CAS  Google Scholar 

Download references

Funding

Preparation of the publication was supported by the Ministry of Higher Education and Science of the Russian Federation (project 4.1154.2017/4.6). Elemental analysis studies were supported by the Program 5-100 of the Peoples’ Friendship University of Russia.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to E. B. Markova.

Ethics declarations

CONFLICT OF INTEREST

The authors declare that there is no conflict of interest to be disclosed in this paper.

ADDITIONAL INFORMATION

A.A. Revina, ORCID: https://orcid.org/0000-0002-4197-2565

E.B. Markova, ORCID: https://orcid.org/0000-0003-2735-2893

O.V. Suvorova, ORCID https://orcid.org/0000-0003-3713-8161

T.A. Tereshina, ORCID https://orcid.org/0000-0002-2009-2358

A.G. Cherednichenko, ORCID: https://orcid.org/ 0000-0002-4709-5313

Additional information

Translated by T. Soboleva

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Revina, A.A., Markova, E.B., Suvorova, O.V. et al. Effect of Doping of Plant Raw-Based Activated Carbons with Iron Nanoparticles on Their Catalytic Activity in the Reaction of Propane Dehydrogenation. Pet. Chem. 60, 585–591 (2020). https://doi.org/10.1134/S0965544120050096

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0965544120050096

Keywords:

Navigation