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Syntheses, Crystal Structure, and Magnetic Property of a New Mn(II) Complex with an Aromatic N-heterocyclic Tetracarboxylic Acid Ligand

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Abstract

A new 2D Mn(II) complex named as [Mn3(HL)2(H2O)6]n (I) (H4L = 3-(2,4-dicarboxyphenyl)-2,6-dicarboxypyridine) was synthesized and characterized by IR, elemental analysis, and single-crystal X-ray diffraction method (CIF file CCDC no. 1915189). The complex crystallizes in the monoclinic space group C2/c with Z = 4, a = 20.6597(11), b = 9.0949(5), c = 20.6041(12) Å, β = 110.056(6)°. The crystal consists of trinuclear Mn(II) ion clusters {Mn3} which are linked by four independent HL3– ligands and these trimeric units are connected into 2D structure by pentadentate HL3– ligand in alternate bis(bridging) and chelated coordination modes. Thermogravimetry, powder X-ray diffraction, and magnetic measurement experiments are also carried out to determinethe thermal stability, phase purity and magnetism. The results show that weak antiferromagnetic interactions occur between the Mn(II) centers within bridging trinuclear {Mn3} cluster.

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REFERENCES

  1. Zhao, Y., Yang, X.G., Lu, X.M., et al., Inorg. Chem., 2019, vol. 58, p. 6215.

    Article  CAS  Google Scholar 

  2. Wang, Y.F., Sun, Y.C., Zhao, J.S., et al., CrystEngComm, 2013, vol. 15, no. 46, p. 9980.

    Article  CAS  Google Scholar 

  3. Mu, Y.Q., Zhu, B.F., Li, D.S., et al., Inorg. Chem. Commun., 2013, vol. 33, p. 86.

    Article  CAS  Google Scholar 

  4. Fu, H.R., Wang, N., Qin, J.H., et al., Chem. Commun., 2018, vol. 54, p. 11645.

    Article  CAS  Google Scholar 

  5. Wen, G., Han, M.L., Wu, X.Q., et al., Dalton Trans., 2016, vol. 45, p. 15492.

    Article  CAS  Google Scholar 

  6. Liu, X.F., Li, R.F., Feng, X., et al., New. J. Chem., 2016, vol. 40, no. 1, p. 619.

    Article  CAS  Google Scholar 

  7. Bai, L., Wang, H.B., Li, D.S., et al., Inorg. Chem. Commun., 2014, vol. 44, p. 188.

    Article  CAS  Google Scholar 

  8. Han, M.L., Duan, Y.P., Li, D.S., et al., Dalton Trans., 2014, vol. 43, p. 17519.

    Article  CAS  Google Scholar 

  9. Zhou, Z., Han, M.L., Fu, H.R., et al., Dalton Trans., 2018, vol. 47, no. 15, p. 5359.

    Article  CAS  Google Scholar 

  10. Yang, X.G., Ma, L.F., and Yan, D.P., J. Mater. Chem., A, 2016, vol. 4, no. 11, p. 3991.

    Article  Google Scholar 

  11. Ma, L.F., Qin, J.H., Wang, L.Y., et al., RSC Adv., 2011, vol. 1, no. 2, p. 180.

    Article  CAS  Google Scholar 

  12. Wang, Y.F., Chen, J.Q., and Geng, J.L., Z. Anorg. Allg. Chem., 2014, vol. 640, no. 10, p. 2086.

    Article  CAS  Google Scholar 

  13. Liu, X.F., Li, R.F., and Zhang, X.Y., Russ. J. Coord. Chem., 2013, vol. 39, no. 8, p. 593. https://doi.org/10.1134/S1070328413080058

    Article  CAS  Google Scholar 

  14. Wang, H., Huang, C., Han, Y., et al., Dalton Trans., 2016, vol. 45, p. 7776.

    Article  CAS  Google Scholar 

  15. Li, X.L., Liu, G.Z., Xin, L.Y., et al., CrystEngComm, 2012, vol. 14, no. 5, p. 1729.

    Article  CAS  Google Scholar 

  16. Kai, S., Sakuma, Y., Mashiko, T., et al., Inorg. Chem., 2017, vol. 56, no. 20, p. 12652.

    Article  CAS  Google Scholar 

  17. Dong, W.W., Li, D.S., Zhao, J., et al., CrystEngComm, 2013, vol. 15, no. 27, p. 5412.

    Article  CAS  Google Scholar 

  18. Mahapatra, P., Drew, M.G., and Ghosh, A., Inorg. Chem., 2018, vol. 57, no. 14, p. 8338.

    Article  CAS  Google Scholar 

  19. Du, L., Yu, S., and Liu, X., New J. Chem., 2018, vol. 42, no. 6, p. 4553.

    Article  CAS  Google Scholar 

  20. Qin, J.H., Wang, H.R., Pan, Q., et al., Dalton Trans., 2015, vol. 44, p. 17639.

    Article  CAS  Google Scholar 

  21. Khannam, M., Weyhermuller, T., Goswami, U., et al., Dalton Trans., 2017, vol. 46, no. 31, p. 10426.

    Article  CAS  Google Scholar 

  22. Li, X.L., Liu, G.Z., Xin, L.Y., et al., J. Solid State Chem., 2017, vol. 246, p. 252.

    Article  CAS  Google Scholar 

  23. Chang, X.H., Qin, J.H., Han, M.L., et al., CrystEngComm, 2014, vol. 16, no. 5, p. 870.

    Article  CAS  Google Scholar 

  24. Li, G.L., Yin, W.D., Li, X.L., et al., Syn. React. Inorg. Met. Org. Chem., 2015, vol. 45, no. 6, p. 869.

    Article  CAS  Google Scholar 

  25. Chakraborty, P., Majumder, I., Banu, K.S., et al., Dalton Trans., 2016, vol. 45, no. 2, p. 742.

    Article  CAS  Google Scholar 

  26. Ma, L.F., Han, M.L., Qin, J.H., et al., Inorg.Chem., 2012, vol. 51, no. 17, p. 9431.

    Article  CAS  Google Scholar 

  27. Zhao, Y., Chang, X.H., Liu, G.Z., et al., Cryst. Growth. Des., 2015, vol. 15, no. 2, p. 966.

    Article  CAS  Google Scholar 

  28. Dolomanov, O.V., Bourhis, L.J., Gildea, R.J., et al., J. Appl. Cryst., 2009, vol. 42, p. 339.

    Article  CAS  Google Scholar 

  29. Sheldrick, G.M., Acta Crystallogr., Sect. A: Found. Adv., 2015, vol. 71, p. 3.

    Article  Google Scholar 

  30. Sheldrick, G.M., Acta Crystallogr., Sect. C:,Struct. Chem., 2015, vol. 71, p. 3.

    Google Scholar 

  31. Lim, K.S., Song, J.H., Kang, D.W., et al., Dalton Trans., 2018, vol. 47, no. 3, p. 845.

    Article  CAS  Google Scholar 

  32. Berezin, A.S., Vinogradova, K.A., Nadolinny, V.A., et al., Dalton Trans., 2018, vol. 47, no. 5, p. 1657.

    Article  CAS  Google Scholar 

  33. Kang, H.X., Fu, Y.Q., Ju, F.Y., et al., Russ. J. Coord. Chem., 2018, vol. 44, p. 340. https://doi.org/10.1134/S1070328418050020

    Article  CAS  Google Scholar 

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Funding

The authors are grateful for the financial support from the National Natural Science Foundation of China (nos. U1604143 and U1804131), Training Program for Young Cadre Teachers of Higher Education Institutions in Henan Province (no. 2018GGJS128), and Science and Technology Development Project in Henan Province (no. 172101410037).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-Oriented Porous Materials, Luoyang Normal University, 471934, Luoyang, P.R. China

    X. F. Liu, N. N. Ma, F. Feng, M. D. You & X. Feng

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  1. X. F. Liu
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  2. N. N. Ma
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  3. F. Feng
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  4. M. D. You
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  5. X. Feng
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Correspondence to X. F. Liu or X. Feng.

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Liu, X.F., Ma, N.N., Feng, F. et al. Syntheses, Crystal Structure, and Magnetic Property of a New Mn(II) Complex with an Aromatic N-heterocyclic Tetracarboxylic Acid Ligand. Russ J Coord Chem 46, 365–370 (2020). https://doi.org/10.1134/S1070328420050036

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  • DOI: https://doi.org/10.1134/S1070328420050036

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